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Wet-strength paper production is of great significance due to its prominent importance in everyday consumer activities. Recently, market demands for paper with specific properties and purposes are increasing. Production of these paper types is very challenging for the manufacturer since they have to meet very specific demands. Wet-strength paper products include bags that come in contact with moisture and wet products, hygienic and kitchen towels, paper towels, packaging products (packages for liquids, aseptic dishes, and a variety of packaging for food), and other special purposes items (tea bags, coffee filters, paper money, etc.) Throughout this research, the focus was on the effects a wetstrength agent has on the tensile strength of paper. The wet strength property of paper is the ratio between the strength of paper in the wet and dry state. The strength in the dry state comes from the hydrogen bonds present in natural cellulose, while the strength of paper in the wet state requires waterproof (covalent) bonds created by the use of a wet strength agent. The wet strength agent used is a cationic PAE resin. The aim of the work is to determine the optimal amount of agent needed in relation to the required value of the tensile strength property of the paper. The investigation of these influences was carried out on Semi Extensible Standard Kraft type of paper in Natron-Hayat. [ABSTRACT FROM AUTHOR]

Abstract Temperature and humidity are the main factors that cause the decomposition of Nomex paper widely used as turn‐to‐turn insulation material of mining dry‐type transformers. In this study, for understanding the effect of ambient humidity and thermal aging on the properties of Nomex paper, specimens with the initial moisture content of 7% were aged in the oven for 168, 504, 672 h at 180°C, respectively. After thermal aging, corona discharge experiments of unaged and aged specimens with different aging degrees were carried out at different relative humidity (RH) levels from 10 to 70%. The characteristic parameters of corona discharge, such as the average discharge amplitude and the number of discharges, were measured. Then, the surface conductivity and the surface potential decay rate were measured. The morphology and attenuated total internal reflectance Fourier transform infrared spectroscopy were also analysed for explaining the difference of properties between unaged and aged specimens. The experiment results indicate that the average discharge amplitude decreases with the increase of RH or the deepening of the aging degree of specimens, but the number of discharges shows the reversal tendency. The changes in the physical structure and chemical composition, which is induced by the hydrolysis reaction of Nomex paper, accelerate the surface potential decay and increase the surface conductivity.

Moisture absorption in the cell wall structure of wood is well known to induce considerable swelling of the wood exerting high expansion forces. This swelling is mainly induced by the sorptive action of the hydroxyl groups of the carbohydrate wood polymers; cellulose and hemicelluloses. On the ultrastructural level, there are, however, still questions with regard to the detailed deformations induced by this moisture absorption. Here, FTIR spectroscopy and synchrotron-radiation-based X-ray diffraction were used on paper samples to study the deformation of the cellulose crystals as a consequence of moisture absorption and desorption. Both techniques revealed that the moisture absorption resulted in a transverse contraction of the cellulose crystals accompanied by a somewhat smaller elongation in the cellulose chain direction. The deformations were found to be a direct response to the increased moisture content and were also found to be reversible during moisture desorption. It is hypothesised that these deformations are a consequence of the swelling forces created by the combined longitudinal and lateral expansions of the non-crystalline cellulose molecules and the glucomannan hemicellulose aligned along the cellulose crystals. These forces will impose a lateral contraction of the cellulose crystals, as well as a longitudinal extension of it. [ABSTRACT FROM AUTHOR]

The condition assessment of oil–paper insulation is a vital issue in transformer management. To investigate the effect of moisture content on the accuracy of the prediction model, accelerated ageing experiments were performed with different initial moisture content (IMC) in laboratory condition. Two types of multi-parameter lifetime prediction models, e.g. with and without consideration of IMC, were presented for comparison purpose. The authors found that a better accuracy for its prediction results could be achieved by establishing the prediction models with the consideration of IMC. Besides, models considering IMC have better economic feasibility than that without considering IMC(non-IMC) as its total cost is cheaper according to life cycle cost (LCC) calculations. In addition, failure probability based on the proposed prediction models was also calculated as a direct indicator for evaluating the oil–paper insulation status. [ABSTRACT FROM AUTHOR]

A computationally efficient method to study the in-plane and out-of-plane dimensional instability of thin paper sheets under the influence of moisture changes is presented. The method explicitly resolves the bonded and the free segments of fibers in the sheet, capturing the effect of anisotropic hygroexpansion at the fiber level. The method is verified against a volumetric model. The importance of longitudinal fiber hygroexpansion is demonstrated in spite of the absolute value of longitudinal hygroexpansion being an order of magnitude lower than the transverse hygroexpansion component. Finally, the method is used to demonstrate the formation of macroscopic sheet curl due to a moisture gradient in structurally uniform sheets in the absence of viscoelastic or plastic constitutive behavior and through-thickness residual stress profiles. [ABSTRACT FROM AUTHOR]

The dielectric properties of oil-paper insulation degrade due to moisture ingression and ageing. This degradation significantly impacts the space charge accumulation and charge trapping behaviour in the insulation, which are vital parameters for insulation health under the high-voltage direct current environment. In this work, an improved model based on the isothermal relaxation current (IRC) has been developed to study the charge trapping behaviour of an oil pressboard under the influence of moisture and ageing. The conventional IRC model considers the total relaxation current because of charge de-trapping only. However, in the case of a composite dielectric like oil pressboard, dipolar relaxation also affects the relaxation current. In this work, a methodology has been proposed to investigate charge de-trapping behaviour of oil-pressboard insulation considering the dipole relaxation process from IRC measurements. For this purpose, frequency domain spectroscopy measurements and IRC measurements have been performed on oil-impregnated pressboard specimens carefully prepared in the laboratory having different ageing conditions and moisture contents. Results presented in this work depict that charge trapping parameters, i.e. the trap depth and trapped charge distribution are highly affected both by ageing and moisture. It was observed that ageing leads to the generation of deeper traps, while moisture mainly enhances the density of shallow traps.

Epoxy resin impregnated paper (RIP) bushings are widely used as transformer bushings and wall bushings, but this type of bushing is easy to be dampened. In order to study the effect of moisture on the bushings' insulation performance, a test device was established to simulate the moisture absorption process in the air or N(2) gas. Based on the frequency-domain dielectric spectroscopy (FDS) method, FDS curves that indicate the dielectric loss factor (tan δ) and capacitance (C) under different frequencies were tested and analysed. The results demonstrated that the FDS curve moves to the high frequency direction with the increase of the moisture content, and there exist minus tan δ and a negative peak in low-frequency band. Since the moisture content is much lower than in the air, tan δ and C under power frequency of the bushing almost unchanged in the N(2) gas. However, the tan δ under 0.1 Hz increases sharply with the increase of trace moisture, and the higher moisture content, the greater increase rate. A damp diagnosis method for RIP bushings is proposed based on the FDS curves' frequency translation characteristics and tan δ variation law. Also the results can give references for RIP bushings' insulation diagnosis.

The measurement of water inside a transformer is essential to maintain its reliable operation, as the water content can increase as the transformer ages. This measurement is frequently performed by a utility as a part of its periodic maintenance activities. In this paper, the application of optical fiber sensors as an online method to measure water content of paper inside an operating transformer is presented. There are several advantages of using these sensors, including their size, lightweight, flexibility, multiplexing, no-electromagnetic interference, etc. A unique benefit of fiber optic technology is that sensors can be embedded into the winding structure and operate in areas of high electric field strength. For this work, fiber optic water and temperature sensors are investigated by comparing their measurements to a commercial water activity probe immersed in oil. The study found that the determination of water content by fiber optic sensors compared closely with other techniques, which lead to the conclusion that they can be an effective technology for water measurement in an operational transformer. [ABSTRACT FROM AUTHOR]

The performance of oil-impregnated paper significantly affects the safety and reliability of transformers. Previous studies on water reducing the breakdown strength of oil-impregnated paper have been mainly due to increasing charge carriers and conductivity. However, the influence of water on the cellulose crystal structure of oil-impregnated paper is still not clear; in particular, its role on breakdown strength remains ambiguous. In this study, the AC breakdown strength and crystal structure of vegetable and mineral oil-impregnated paper with different moisture contents were investigated. The results show that with increasing moisture content, the cellulose crystallinity and crystal size increases linearly, while the breakdown strength decreases. The breakdown strength of vegetable oil-impregnated paper is higher than that of mineral oil-impregnated paper and is less affected by moisture. Herein, a model is proposed on the effects of water on the crystal structure of oil-impregnated paper and the correlation of breakdown strength with crystal structure is reported. [ABSTRACT FROM AUTHOR]

Abstract A number of problems associated with dimensional stability of paper products have to do with hygroexpansion in response to changes in humidity or moisture content. The main underlying mechanism of hygroexpansion in paper is the effect of the change of fiber cross-sections transferred through fiber bonds. In fact, the transverse expansion of fibers can be an order of magnitude greater than the longitudinal expansion. Addressing such problems using modeling on the microscale is associated with large computational costs since both the bonds and the fibers need to be resolved. We present a method for modeling the hygro or thermal expansion of interconnected fiber networks modeled with beam elements and connected through beam-to-beam contact. Being a line structure, beams can only support pointwise contact, which poses a challenge for modeling the force transfer induced by the deformation of the cross-sections at the contact point. The idea of implementing the stress transfer is to use a concurrent multiscale approach in which the bond level is resolved in detail using the configuration of the fibers and the computed strains are passed over to the beam elements. We verify and prove the applicability of this approach by comparing it with continuum models. We demonstrate the advantage of using this approach in terms of its tremendous saving in time. The use of beam models for modeling the hygro- or thermal expansion of fiber networks enables considering relevant sizes in the problems involving dimensional stability, in particular those associated with embedded inhomogeneities. We will show the applicability of the model by providing insights into published experimental observations on the hygroexpansion properties of paper products. Finally, we will demonstrate that the use of a 2D model to simulate the inter-fiber bonds in a network, not only leads to underestimation of out-of-plane deformations, but also to overestimation of the contribution of the transverse deformation of fibers to the in-plane dimensional change of the network. [ABSTRACT FROM AUTHOR]

Epoxy resin impregnated paper (RIP) bushings are widely used as transformer bushings and wall bushings, but this type of bushing is easy to be dampened. In order to study the effect of moisture on the bushings' insulation performance, a test device was established to simulate the moisture absorption process in the air or N2 gas. Based on the frequency-domain dielectric spectroscopy (FDS) method, FDS curves that indicate the dielectric loss factor (tan δ) and capacitance (C) under different frequencies were tested and analysed. The results demonstrated that the FDS curve moves to the high frequency direction with the increase of the moisture content, and there exist minus tan δ and a negative peak in low-frequency band. Since the moisture content is much lower than in the air, tan δ and C under power frequency of the bushing almost unchanged in the N2 gas. However, the tan δ under 0.1 Hz increases sharply with the increase of trace moisture, and the higher moisture content, the greater increase rate. A damp diagnosis method for RIP bushings is proposed based on the FDS curves' frequency translation characteristics and tan δ variation law. Also the results can give references for RIP bushings' insulation diagnosis. [ABSTRACT FROM AUTHOR]

Study of alternate fluids for transformer and their combination with traditional ones is an interesting area of research. The intent of this work is to investigate the thermal ageing performance of ester oils (synthetic and natural), and mixed oil vis‐à‐vis mineral oil. All the samples were thermally stressed at 110, 140, 160, and 185°C for 2 weeks each. Dissolved decay contents in oil and linear thermal expansion coefficients of solid insulation have been studied using ultraviolet visible infrared spectroscopy and dilatometry analysis, respectively, as per ASTM standards. Change in functional groups of the insulation oils with ageing have been understood by Fourier transform infrared spectroscopy analysis. Additionally, diffusion of oil–moisture mixture into paper with ageing and the corresponding effect on dielectric strength of paper has been also examined using ASTM standards. It is observed that the use of synthetic ester (SE) and addition of SE to mineral insulating oil lead to improved performance of oil–paper insulation system with retarding the rate of degradation of the insulation system. [ABSTRACT FROM AUTHOR]

The moisture-induced degradations during the use of paper are of growing concern for the existing paper materials stored in libraries, archives and museums. Knowing the moisture profiles is therefore a primary step in order to understand paper deterioration and give an assessment of degradation rate of library collections in their preservation. In this paper, the theoretical models based on 2-D scanning electron microscope real image microstructure were established for describing moisture transport in paper sheet in response with external humidity and the moisture diffusion profiles. The acid-catalyzed hydrolysis kinetic in combination with moisture diffusion theory gave the complementary explanation for the time-dependent natural aging process of a paper sheet and book stacks. The differential equations were solved by a numerical approach based on the finite element method implemented in commercial COMSOL Multiphysics. The 2-D simulation results, with a mesh based directly on SEM characterization of microstructure, could show the equilibrium moisture contents and the degradation rates as a function of relative humidity in cellulose pores and cellulose fibers across the transverse section of paper. For the stacks composed of books, the air gaps between the books provided convenient channels for diffusion and transport, accelerating the moisture transport process in the book stacks. [ABSTRACT FROM AUTHOR]

Nowadays, reliability of power system is of great importance. Therefore, the condition of transformers as the expensive and critical components of a power system should be monitored and assessed. The dominant factor that causes limitation in transformers lifetime is the paper insulation. This paper aims to investigate the conspicuous influence of moisture content, especially in low oxygen and temperature on lifetime estimation under constant conditions, based on the results of previous experiments. Degree of polymerization (DP) is employed to quantify the effects of detrimental parameters with respect to their time-varying nature. This paper proposes a novel lifetime estimation-approach considering a yearly moisture growth for transformers. The results indicate different trend of DP profiles, which lead to an accurate lifetime estimation in comparison with DP obtained through ideal conditions. Furthermore, oscillations in the hot-spot temperature of transformers are demonstrated to have a negative effect on the lifetime. [ABSTRACT FROM AUTHOR]

This article introduces a method to validate heat of sorption measurements from isotherms by comparing them to direct measurements using reaction calorimetry. We have evaluated some frequently used single-temperature isotherm models (BET, GAB) as well as two multi-temperature isotherm equations (Anderson, Heikkilä). It turned out that the isotherm models with better isotherm curve fitting characteristics did not deliver the best results for the heat of sorption. Multi-temperature isotherm models such as the Heikkilä equation are able to deliver good results in terms of modelling the isotherm data and determining the heat of sorption. Single-temperature models fit the isotherm data better than multi-temperature models, but failed to deliver correct values for the heat of sorption. We specifically investigated the heat of sorption at very low moisture content, which is most relevant for paper drying. The resulting heat of sorption curves were analyzed with respect to their saturation behavior, which is expected to occur below BET monolayer moisture. The heat of sorption from the Heikkilä’s model was the only one to show the expected saturation at very low moisture content. [ABSTRACT FROM PUBLISHER]

A moisture-dependent and temperature-dependent constitutive model for paper materials was proposed and implemented into a finite element model of the paper hydroforming process. Experimental hydroforming was conducted at temperatures of 23°C and 110 °C and moisture contents of 6.9 and 10.6 (respectively corresponding to 50 and 80% relative humidity). The proposed model, which also included the effects of drying, captured the extent of forming of all experimental results within reasonable accuracy. For the moisture content and temperature conditions in this study, the phenomenon of drying was found to be the reason why the application of temperature had a much greater effect on the degree of forming than hydroforming at various moisture contents. A simulation-based parametric study was conducted in order to identify the importance of various process and material parameters. This parametric study confirmed many previous empirical findings and was capable of quantifying the extent to which these process and material parameters affect the three-dimensional formability of paper. The coefficient of friction was identified as one of the most important factors when determining the extent of forming. Copyright © 2016 John Wiley & Sons, Ltd. [ABSTRACT FROM AUTHOR]

This paper studied the impact of moisture on the correlated characteristics of the condenser bushings oil-paper insulation system. The oil-impregnated paper samples underwent accelerated thermal aging at 130 °C after preparation at different initial moisture contents (1%, 3%, 5% and 7%). All the samples were extracted periodically for the measurement of the moisture content, the degree of polymerization (DP) and frequency domain dielectric spectroscopy (FDS). Next, the measurement results of samples were compared to the related research results of transformer oil-paper insulation, offering a theoretical basis of the parameter analysis. The obtained results show that the moisture fluctuation amplitude can reflect the different initial moisture contents of insulating paper and the mass ratio of oil and paper has little impact on the moisture content fluctuation pattern in oil-paper but has a great impact on moisture fluctuation amplitude; reduction of DP presents an accelerating trend with the increase of initial moisture content, and the aging rate of test samples is higher under low moisture content but lower under high moisture content compared to the insulation paper in transformers. Two obvious "deceleration zones" appeared in the dielectric spectrum with the decrease of frequency, and not only does the integral value of dielectric dissipation factor (tan δ) reflect the aging degree, but it reflects the moisture content in solid insulation. These types of research in this paper can be applied to evaluate the condition of humidified insulation and the aging state of solid insulation for condenser bushings. [ABSTRACT FROM AUTHOR]

Significant dimensional variations may occur in paper-based materials when subjected to changes in moisture content. Moisture induced deformations are governed by the swelling of individual fibres, which is transferred through inter-fibre bonds to the entire fibrous network. Complex interactions between mechanical and hygro-expansive properties take place in the bonding areas, affecting the overall material response. In most network models, the role of these inter-fibre bonds is not explicitly incorporated. This work presents a periodic meso-structural model for the discrete fibrous network, which considers the free-standing fibre segments and inter-fibre bonds. Despite its simplicity, the reference unit-cell enables the incorporation of relevant micro- and meso-structural features such as network structure, fibres and bond geometry and hygro-elastic properties. The proposed model is solved analytically through a proper homogenization strategy, allowing to recover the paper’s anisotropic hygro-mechanical response in terms of effective elastic constants and effective hygro-expansive coefficients, exploiting the coupling at the meso-structural level between hygroscopic and mechanical behavior. A comparison with experimental results obtained from the literature shows that the presented approach is quite accurate in predicting the overall paper response, thereby revealing the influence of several meso-scale parameters (e.g. fibre orientation, dimensions, mechanical strength). [ABSTRACT FROM AUTHOR]

To model advanced 3-D forming strategies for paper materials, the effects of environmental conditions on the mechanical behavior must be quantitatively and qualitatively understood. A tensile test method has been created, verified, and implemented to test paper at various moisture content and temperature levels. Testing results for one type of paper for moisture contents from 6.9 to 13.8 percent and temperatures from 23 to 168 degrees Celsius are presented and discussed. Coupled moisture and temperature effects have been discovered for maximum stress. Uncoupled effects have been discovered for elastic modulus, tangent modulus, hardening modulus, strain at break, tensile energy absorption (TEA), and approximate plastic strain. A hyperbolic tangent function is also utilized which captures the entire one-dimensional stress-strain response of paper. The effects of moisture and temperature on the three coefficients in the hyperbolic tangent function may be assumed to be uncoupled, which may simplify the development of moisture- and temperature-dependent constitutive models. All parameters were affected by both moisture and temperature with the exception of TEA, which was found to only be significantly dependent on temperature. [ABSTRACT FROM AUTHOR]

This paper aims to investigate the impact of moisture on mechanical properties of insulation paper. According to the molecular modeling approach proposed by Theodorou, the amorphous cellulose models of insulation paper with different moisture contents were built up to calculate mechanical parameters and hydrogen bond networks. And relevant conclusions could be drawn through further analysis on these calculation results: water molecules can destroy hydrogen bond network between the neighboring cellulose molecules, which might be responsible for the significant decrease of Young's modulus and other mechanical parameters, while no appreciable effect of intramolecular hydrogen bonds on mechanical properties was detected. Thus tensile tests were also carried out to study the moisture influence on the Young's modulus, by which the result of the simulation was approved. [ABSTRACT FROM AUTHOR]

The in-service evaluation of moisture in transformer insulation is a very important aspect in the condition assessment of power transformers because moisture in cellulosic materials leads to significant reductions in both dielectric and mechanical strengths by one-half for each doubling of water content [1]. Moisture equilibrium charts provide a quick way of estimating the in-service moisture content of transformer insulations. Knowledge of the moisture distribution within the various materials, which are dependent on diffusion and absorption? desorption processes, are valuable in insulation diagnostics and dry-out processes. [ABSTRACT FROM PUBLISHER]

The surface quality of papers impregnated with a mimosa tannin resin and a MUF resin for application as surface coating on wood panels was compared. The impregnated papers were conditioned to 23% and 10% moisture contents and pressed on to beech plywood. Moisture content of the impregnated papers before pressing was found to influence the abrasion resistance for both mimosa tannin resin and MUF resin impregnated papers. Colour measurements were carried out to relate the different paper colours to the two different moisture contents at pressing. Mimosa tannin impregnated papers at 23% moisture content had a lighter shade compared to impregnated papers with mimosa tannin resins at 10% moisture content. Impregnated papers with mimosa tannin resin gave excellent results for water vapour resistance, cross-cut test and abrasion resistance compared to papers impregnated with MUF resin according to relevant standards. [ABSTRACT FROM AUTHOR]

Paper is a material exhibiting a complex microstructure that is composed of a network of fibres at the micro-level. When subjected to external loading or variations in moisture conditions over different time scales, changes in strain that are non-linear with respect to time are observed at the sheet level (macro-scale). In order to investigate this time-dependent behaviour of paper, a creep power law model is implemented within a finite element approach at the level of single fibres. This rate-dependent model is found to capture experimental results available in literature for single fibres with a good agreement (both quantitatively and qualitatively). Based on the identified model at the level of single fibres, the time-dependent hygro-mechanical response is upscaled towards the network scale. To this end, random model networks of ribbon shaped fibres are generated and their response is simulated. The network-scale response, emerging from the rate-dependent fibre model, demonstrates the ability to predict the response of networks subjected to relaxation at a constant moisture level. The developed numerical model predicts lower values of overall stress response in single fibres as compared to networks. Also, stress relaxation predicted by the rate-dependent model in the cross-direction of the networks is in agreement with the experimental observations by Johanson and Kubát (1967). Therefore, one of the remarkable findings of the present work is that the developed rate-dependent model is robust enough to capture the sheet scale response also qualitatively. Based on the study of these computational results, a better understanding is achieved regarding the influence of mechanical and rate-dependent properties of single fibres on the hygro-expansion of complete fibre networks, and in particular of paper sheets. • A rate-dependent non-linear model is developed to study creep in paper networks. • It is calibrated with experiments on the single paper fibres with a good match. • It also captures the experimental response of the networks qualitatively. • One of the remarkable achievement of our work is the robustness of the model. [ABSTRACT FROM AUTHOR]

Abstract: Cellulose fiber has been modified by mechanical and chemical means in order to improve paper properties, which respond to moisture and temperature. When the cellulose is first refined and then etherified using hydroxypropylation under dry conditions, the paper sheets prepared from the hydroxypropylated cellulose show improved elongation. When the level of hydroxypropylation is high enough, the paper sheets also become transparent. Additionally, the effect of cellulose activation using different mechanical methods has been compared by esterification reactions. It is shown that removal of water is the most crucial step for the esterification reactions while other methods have a lesser impact. The paper sheets prepared from the esterified cellulose fibers show an increase in contact angles and high hydrophobicity. [Copyright &y& Elsevier]

Abstract: In this work we present a mathematical model describing the coupled heat and moisture transport in paper. The model is solved numerically and the numerical solution is used to study the interdependency of the moisture and temperature distribution in paper. The results show that variation with temperature of the saturated water vapor concentration and the sorption isotherm parameters are both important for inducing moisture desorption. It is also found that for steep relative humidity ramps moisture sorption generates temperature increments that slow down the sorption process itself. The model is also used to study the moisture gradients in a paper sheet inside a printer from Océ Technologies, which contains a warm print surface. The results predict changes in moisture content of only 0.2%, which suggests that no deformations are induced on the printed sheet. [Copyright &y& Elsevier]

We present theory for the shrinkage on drying of the cross-sectional area of cellulosic fibres and show that this depends on their initial moisture content only. For the linear shrinkage of cross-sectional dimensions, an additional parameter is required, which we estimate from comparison of the theory with experimental data from the literature. We proceed to combine our model of fibre shrinkage with probabilistic theory for fibre contacts in random fibrous networks to obtain a model for the unrestrained shrinkage of isotropic paper sheets. The expression obtained depends only on the moisture content of fibres and the extent of inter-fibre contact and exhibits good agreement with experimental data for laboratory-formed paper sheets. The results have relevance to the commercial manufacture of paper and potential for application to the study of cellulose nano-composites. [ABSTRACT FROM AUTHOR]

Adhesion issues are present in many disciplines such as, for example, surface science, microrobotics or MEMS design. Within this framework, this paper presents a study on capillary forces due to capillary condensation. A simulation tool had already been presented using Surface Evolver and Matlab to compute the shape of a meniscus in accordance with the Kelvin equation and contact angles. The numerical results of this simulation complied well with literature results. One very important result is the ability to compute the evolution of the capillary force depending on the tilt angle of the gripper with respect to the object. The main contribution of this new paper is a test bench and the related experimental results which validate these numerical results. We present here new experimental results illustrating the role of humidity and tilt angle in capillary forces at the nanoscale. [ABSTRACT FROM AUTHOR]

Results of dielectric response measurements in frequency domain at various temperatures have been presented for oil impregnated paper samples unaged and thermally aged containing various amounts of moisture. The obtained results were used for defining respective master curves and activation energies. Discrepancies of the results for similar samples are also discussed. Finally, statistical spread of the data was presented and the influence of moisture content on the dielectric response of paper samples has been discussed. [ABSTRACT FROM AUTHOR]

Adsorption isotherms of 3 selected paper-based packaging materials, that is, vegetable parchment (VP) paper, Kraft paper, and solid-bleached-sulfate (SBS) paperboard, were determined at 3 different temperatures (25, 40, and 50 °C). The GAB isotherm model was found to fit adequately for describing experimental adsorption isotherm data for the paper samples. The monolayer moisture content of the paper samples decreased with increase in temperature, which is in the range of 0.0345 to 0.0246, 0.0301 to 0.0238, and 0.0318 to 0.0243 g water/g solid for the MG paper, the Kraft paper, and the SBS paperboard, respectively. The net isosteric heats of sorption ( qst) for the paper samples decreased exponentially with increase in moisture content after reaching the maximum values of 18.51, 27.39, and 26.80 kJ/mol for the VP paper, the Kraft paper, and the SBS paperboard, respectively, at low-moisture content. The differential enthalpy and entropy of 3 paper samples showed compensation phenomenon with the isokinetic temperature of 399.7 K indicating that water vapor had been adsorbed onto the paper samples with the same mechanism. Depending on the paper material, tensile strength of paper samples was affected by moisture content. [ABSTRACT FROM AUTHOR]

The extension of the Darcy law (the Forchheimer flow equation) relating second-order nonlinear pressure drop with flow velocity is studied during fast transient through air drying of sheets of porous biobased materials such as paper. A range of the paper materials with open structure consistent with tissue and towel products (basis weights 25 and 50 g/m2) made using different production processes are analyzed for the factor-specific influences with regard to changes in the fluid resistance from the removal of moisture from the material interstices. A characteristic dimension suitable for the drying process is applied from viscous and inertial momentum transport analysis. [ABSTRACT FROM AUTHOR]

Abstract: This paper presents a method to predict the through-thickness moisture content distribution and associated induced deformations of paper and cardboard sheets as they are subjected to relative humidity changes. The transient moisture diffusion problem is solved using a “natural” analytic approach that has previously been applied for solving transient heat conduction in multi-layer solids. The deformation behaviour of the sheet during the moisture diffusion process is predicted using a semi-analytical approach based on a Rayleigh–Ritz minimization of the total potential energy. Geometrically nonlinear effects are taken into account. Curvatures of the originally flat sheet are predicted as a function of time, as are the shapes of the sheet for steady-state condition. As multiple solutions exist, stability is studied. The developed model was used to study the deformation behaviour of one paper and two cardboard sheets. Comparisons with finite-element results demonstrate that the developed model provides accurate results. The displacements obtained for steady-state conditions are within +6%. Comparisons with previous steady-state analyses reveal important differences in the shape of one cardboard sheet. This suggests that the moisture diffusion process may influence the configuration assumed by the sheet at steady-state equilibrium. Hence, it may be necessary to take the moisture diffusion into account in the analysis to accurately predict the hygro-mechanical behaviour of paper or cardboard sheets. [Copyright &y& Elsevier]

The hygroexpansion of paper was significantly reduced, up to 28% lower amplitude of change when the paper was subjected to a change in relative humidity from 20 to 85% RH, by oxidation of the fibre wall. Never-dried bleached kraft fibres were oxidised with sodium periodate, which specifically oxidises the C2–C3 bond of 1,4-glucans so that the cellulose is partly converted into dialdehyde cellulose. Since both the dry and wet strength of laboratory sheets were significantly improved, the dry tensile strength increased from 24 kNm/kg up to 66 kNm/kg and the relative wet tensile strength increased from 1.5% up to 40%, it is suggested that the aldehydes form hemiacetal linkages within the fibre wall during the consolidation and drying of the sheets. The mechanical, hygroexpansive and moisture sorptive properties of the sheets made from the oxidised fibres were studied. The results showed that the main reason for the reduced hygroexpansion was a decrease in moisture sorptivity, i.e. when the sheets made of fibres with different degrees of cross-linking were subjected to the same change in relative humidity, the more cross-linked fibres showed a smaller change in moisture content. It was also shown that the hygroexpansion coefficient, i.e. the moisture-normalised dimensional change, was not significantly changed by the periodate oxidation, i.e. indicating that there are no improvement in dimensional stability if the paper is subjected to a specific amount of water. [ABSTRACT FROM AUTHOR]

Abstract: In this paper a simplified network model for mechano-sorptive creep is presented, which is a further development of an earlier paper [Strömbro, J., Gudmundson, P., 2008. Mechano-sorptive creep under compressive loading – a micromechanical model. International Journal of Solids and Structures 45 (9), 2420–2450.]. It is assumed that the anisotropic hygroexpansion of the fibres leads to large stresses at the fibre bonds when the moisture content changes. The resulting stress state will accelerate creep if the fibre material obeys a constitutive law that is non-linear. Fibre kinks are included in order to capture experimental observations of larger mechano-sorptive effects in compression than in tension. Moisture dependent material parameters and anisotropy in the fibre distribution have been introduced. Theoretical predictions based on the model are compared to experimental results for an anisotropic paper both under tensile and compressive loading at varying moisture content and it is found that the important features in the experiments are captured by the model. Different kinds of drying conditions have also been examined. [Copyright &y& Elsevier]

Abstract: Cockling of paper is a common problem occurring in the production, storage and end-use of paper. It is usually induced by a moisture content change. In many cases, cockling is an irreversible phenomenon; i.e. the initial shape is not obtained although the initial moisture content is restored. This kind of moisture content change occurs in copying machines and in the printing process, for example. In this paper, we present a continuum mechanical model, which is used to study the irreversible cockling of paper. In the model, paper is treated as an orthotropic elasto-plastic material and the model takes into account the small-scale variation of fibre orientation. The model is used to show the importance of the through-thickness moisture gradient on the cockling phenomenon during a cyclic moisture content change. The results suggest that the moisture gradient is a crucial factor for the irreversible cockling. [Copyright &y& Elsevier]

Abstract: The creep of paper is accelerated by moisture cycling, an effect known as mechano-sorptive creep. It has also been observed that the mechano-sorptive effects are larger in compression than in tension. In this paper a simplified network model for mechano-sorptive creep is presented. It is assumed that the anisotropic hygroexpansion of the fibres leads to large stresses at the fibre–fibre bonds when the moisture content changes. The resulting stress state will accelerate creep if the fibre material obeys constitutive laws that are non-linear in stress. Geometrical fibre effects are included in the model in order to capture experimental observations of the differences between paper loaded in tension and compression. Theoretical predictions based on the developed model are compared to experimental results for paper both under tensile and compressive loading at varying moisture content. The important features in the experiments are captured by the model, i.e. the creep is accelerated by the moisture cycling and the mechano-sorptive effects are larger in compression than in tension. [Copyright &y& Elsevier]

This study presents experimental analysis and numerical modeling of hygroscopic moisture buffering by paper and books. First, a literature review of moisture transport properties of paper is presented. Experimental work on two paper types includes SEM analysis of the paper structure, determination of sorption isotherms and water vapor permeability measurements. A hysteretic model for paper is presented, which is based on the measurement of the main adsorption and desorption curves. It is shown that the water vapor permeability in a hysteretic model is dependent on the moisture content and not on the relative humidity. Books consist of several paper sheets with air layers between the sheets. To take the air layers into account, a parallel transport model is proposed to determine the effective moisture transport properties of books taking into account the air layers. The dynamic hygroscopic behavior of small book samples was measured. It is shown that, although the water vapor permeability of different paper types can be quite different, the effusivity of a book highly depends on the presence of the air layers and can therefore remain comparable for different paper types. [ABSTRACT FROM AUTHOR]

There is interest in replacing inorganic fillers in paper, coatings and plastics with renewable organic fillers to improve the economics, performance and environmental aspects of such products. Starch microcellular foam (SMCF) particles are promising materials in this regard. This research was undertaken to produce SMCF particles and characterize their morphology, optical properties and interaction with water. SMCF particles were produced using corn starch; which was solubilized in water. The foam structure was created by precipitating the starch using ethanol in a solvent exchange technique. The starch was also reacted with alkyl ketene dimer (AKD) wax at different levels in order to understand if the AKD could impart water resistance to the particles. Two methods were used to incorporate AKD: (1) the AKD was coated onto foam particles after foam formation, and (2) the AKD was blended with the starch before foam particle formation. Hexane extraction was used to purify a portion of each of the samples to determine if unreacted AKD existed with the starch matrix. Particles with porous structure and high brightness were developed for all combinations of starch and AKD. The brightness of the particles was significantly higher than that of the uncooked starch, presumably due to the development of a porous structure. For the AKD coated particles a minimum amount of AKD charged was needed to develop a high contact angle, low solubility, and low water retention value, higher levels of AKD in AKD coated particles did not further alter these properties. This indicates that the changes in properties with AKD level with coated particles is a surface phenomena. Starch AKD blends did not show any increased resistance to water relative to the particles with no AKD blended. This is due to the ethanol used in the precipitation process extracting the AKD, which was confirmed by elemental analysis. The particles, even with the 10% AKD coated or blended, lost their porous structure upon rewetting. Further work needs to be performed to more effectively hydrophobize the starch foams with AKD. [Copyright &y& Elsevier]

The properties of recycled paper are strongly affected by shrinking during drying, which depends on the drying conditions. An experimental study of the shrinkage phenomenon during drying of paper is presented. Drying experiments were conducted in a drying oven with controlled temperature. The temperature influence on shrinkage extent, porosity, and apparent density of the paper was evaluated. Structural changes on the paper surface after drying were analyzed by scanning electronic microscopy. Thickness contraction, surface, and volumetric shrinkage were correlated as a function of the moisture content. Lower apparent density values and more porous paper samples were obtained for higher temperatures. [ABSTRACT FROM AUTHOR]

The influence of mixing process (in a two-roll mill, high-speed mixer, or twin-screw extruder) on the strength properties of polypropylene/wood fiber composites was studied. The best results were obtained for composites compounded in a twin-screw extruder. The water uptake and the influence of moisture on the flexural strength (σfl) and modulus (Efl) were studied by immersion of the composites in water at 20, 50, and 90°C. Most strongly the moisture affected the value of Efl, but the degree of water uptake and the change in σfl and Efl also depended on temperature and the presence of a modificator—maleated polypropylene (MAH). MAH improved the strength properties of the composites both in dry and wet states and also decreased the extent of water uptake and swelling in cyclic (soaking/drying) tests. [ABSTRACT FROM AUTHOR]

The transport rate of liquid water, i.e., the water penetration rate, into paper is one of the important physical properties in the printing, coating, and gluing processes. However, some kinds of paper are too thin to permit the measurement of the penetration rate in the direction of the thickness accurately. Thus, a novel method for measurement of the penetration rate has been developed. The large difference in electrostatic capacitance between soaked and dry paper and that in penetration rate between filter and thin paper were utilized as the foundation for this method. The time required for penetration through the whole sheet of thin paper was calculated from the measured penetration curve on the basis of theoretical analysis. As a result of the measurements in a relative humidity range of 40 to 70% it was concluded that this method could be useful in the characterization of thin paper materials with respect to penetration. [ABSTRACT FROM AUTHOR]

Multicylinder sections of paper dryers consume the most energy in an industrial plant. They are also responsible for the final characteristics of the paper produced. In this context, the modeling of the paper drying process is very important, and is normally done by phenomenological approaches. An interesting and promising alternative, due to the possibilities of its application, is through the identification of an operational standard behavior, obtained by the use of neural networks in the simulation of the final paper moisture content. This alternative was implemented in the drying section of the KIabin Paraná Papeis S.A. (Klabin-PR) MP-7 paper machine. For this study, we collected operational data related directly and indirectly to the drying process, composing a database with 110 preselected variables. These data were analyzed with the help of Statistica Neural Network software, which, besides its use for training and choosing the more capable neural networks to model the chosen variable, allows the selection of the group of variables of larger influence in the studied process. The results obtained by the use of the neural network modeling were quite satisfactory, with an average error of less than 2% in the prediction of the final paper moisture content Application: Neural networks may be useful to help control moisture content and increase dryer efficiency. [ABSTRACT FROM AUTHOR]

The effects of moisture, oxygen, and acidity upon the aging of Kraft and thermally upgraded ("Insuldur®") papers have been studied in detail. The results for Kraft are consistent with the kinetic model and parameters proposed earlier by Emsley et al., and with the principle that moisture promotes acid-hydrolysis by causing carboxylic acids to dissociate. Moisture is released during the aging of Kraft and, hence, its aging is auto-acceleratory. In contrast, Insuldur consumed moisture under the same conditions, aged more slowly, and its aging was less accelerated by added moisture. 2-Furfuraldehyde (2FAL), which is a dehydration product of pentosans and, hence, an index of moisture production, is also released from Kraft during aging, but not from Insuldur. Acids are, however, produced from both types of paper. Theoretical explanations for these findings are proposed, and their practical implications for transformer maintenance are discussed. [ABSTRACT FROM AUTHOR]

Moisture equilibrium isotherms are very important in drying and storage processes analysis. So, the DEQ/UEM process separation group is building a data bank for cellulose, paper, and textile isotherms and their fit with available literature equations. In this context, the experimental isotherms of a brazilian specific commercial paper, the KLABIN-PR KLAPAK commercial liquid package paper were obtained. The experimental equilibrium data were obtained by exposing the material to different ambient conditions of temperature and relative humidity controlled by the use of saline solutions. The samples were placed in glass flasks left inside an oven to provide a better adjust of temperature conditions, being periodically weighed until constant weight. KLAPAK moisture equilibrium isotherms were built from the obtained experimental results and temperature effects on its behavior were analyzed. Then, these results were fitted with the help of some models and equations available from literature. [ABSTRACT FROM AUTHOR]

Upon application of water based coating onto silicone-coated paper and during the subsequent drying process, the water permeates through the silicone layer into the paper substrate. At the same time, water evaporates from both the surface of the coated layer and throughout the paper layer. Initially, the evaporation rate from the wet coating surface may be dominant, but at longer times the bulk evaporation from the paper can dominate. Here a three-layer diffusion model for such a system is developed. Solutions obtained by Galerkin's method with finite element basis functions show that the hygroscopic nature of the paper leads to low drying rates at low moisture contents. Further, the model predicts that initially the coating dries to a moderately low residual moisture concentration faster than a coating applied on an impermeable substrate. However, at longer times, the predicted residual moisture of coatings applied on silicon-coated paper is higher than for a coating applied on an impermeable substrate. [ABSTRACT FROM AUTHOR]

Some current models for moisture diffusion in paper in the hygroscopic range are analyzed. In general, two types of diffusion models can be recognized. Models of the first type treat paper as a homogeneous medium with moisture flux that is proportional to the gradient in moisture content. Although useful in some instances this approach fails frequently because it homogenizes the internal dynamics and relaxation processes occurring within the paper material. Recent studies have shown that a subtler approach which treats paper as a composite of fibers and void spaces is more successful at describing moisture transport dynamics. A review of these studies along with a generalization of this approach to three dimensions is considered here. The parameters appearing in such models can be identified with the physical processes of diffusion through the void space and through the fiber matrix. Diffusivities in these individual phases are supplemented by a local kinetic coefficient representing moisture flux interchange between the void and fiber phases. When the local moisture exchange coefficient takes on large values, the fibers and the void spaces are at local equilibrium with no net exchange of moisture. Under such conditions, the model reduces to the simpler Fickian diffusion model with nonlinear moisture diffusivity equivalent to earlier models. [ABSTRACT FROM AUTHOR]