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Pore structure impacts the capability of seepage pattern of subsurface fluid mineral and mineral exploitation efficiency. Because of the strong heterogeneity in carbonate reservoirs, the pore structure is nonlinearly varying and complex in reservoirs. It is necessary to establish a method for pore structure type (PST) prediction. Machine learning provides an efficient prediction method by finding the relationship between core test data and well‐logging data. In this paper, a reservoir identification method based on Gradient Boost Decision Trees (GBDT) is proposed for the pore structure characteristics of carbonate reservoirs integrating core test and logging data. Core testing data are utilized to form the training set for PST prediction. Then, we adopt the mutual information method to optimize the logging data as the input of the machine learning model. GBDT hyperparameters are optimized using the learning curve to make it have optimal performance. Finally, we compare the predicted result of GBDT with K‐Nearest Neighbor and support vector machines, demonstrating the superior performance of GBDT. The results indicate that the four PS are different in some properties, such as permeability, pore radius and shape of pore and throat. 20%, 10 and 0.15 are recommended as the optimal parameter values for Maximum feature, iteration number and Sub‐sample number to improve GBDT accuracy in carbonate reservoir PST prediction. Evaluation indicators of machine learning, including the Kappa coefficient, Heming distance, Jaccard similarity coefficient and Confusion matrices, indicate that GBDT has better performance. This research proves the high accuracy and applicability of machine learning technology in the carbonate reservoir and also provides a meaningful reference for the identification of the carbonate reservoirs in the central area of Iraq. [ABSTRACT FROM AUTHOR]