301. Polyphenol-metal manipulated nanohybridization of CNT membranes with FeOOH nanorods for high-flux, antifouling and self-cleaning oil/water separation.
- Author
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Zhao, Xueting, Cheng, Lijuan, Jia, Ning, Wang, Ruoxi, Liu, Lifen, and Gao, Congjie
- Subjects
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NANORODS , *PETROLEUM , *WATER efficiency , *WASTEWATER treatment , *WATER , *MULTIWALLED carbon nanotubes , *CARBON nanotubes - Abstract
Carbon nanotube (CNT) membranes with nano-enhanced superwettability show great potential in high-efficient oil/water separation. In this study, we present a novel polyphenol-metal manipulated nanohybridization strategy to prepare CNT nanohybrid membranes embedded with FeOOH nanorods (NRs). The polyphenol-metal manipulated nanohybridization strategy lies in the assembly of polyphenol-metal (chitosan/tannic acid-Fe3+) complex primer on the CNT membranes followed by in situ FeOOH NRs mineralizating. The polyphenol-metal complex modulates the uniform distribution of in situ mineralized FeOOH NRs in the as-prepared CNT@CS/TA-FeOOH nanohybrid membrane, which endows the CNT nanohybrid membrane with both superhydrophilicity and underwater superoleophobicity. By integrating the high permeability of CNT membranes and the hydrophilicity and photo-degradation activity of FeOOH NRs, the CNT@CS/TA-FeOOH nanohybrid membrane possesses achieved a high water permeability above 8000 Lm-2h-1bar-1 and greatly elevated flux recovery ratio above 97% for oil/water separation. Both hydration-induced antifouling property and photo-induced self-cleaning capability contributed to the robust flux recovery for highly efficient oil/water separation. The CNT@CS/TA-FeOOH nanohybrid membrane is promising for oily wastewater treatment applications, and the proposed polyphenol-metal manipulated nanohybridization strategy shows great potential for engineering various multifunctional nanohybrid membranes. Image 1 • The nanohybrid membrane is prepared via polyphenol-metal manipulated nanohybridization. • FeOOH nanorods are in situ mineralized and evenly distributed on the nanohybrid membrane. • The nanohybrid membrane shows robust superhydrophilicity and underwater superoleophobicity. • The nanohybrid membrane possesses superior water flux and high oil/water separation efficiency. • The nanohybrid membrane integrates both antifouling and self-cleaning mechanisms. [ABSTRACT FROM AUTHOR]
- Published
- 2020
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