Regarding the three objectives of European Union (EU) energy policy (secure supply, competitiveness and environmental protection) the EU Commission published the Communication entitled ‘White Paper: Energy for the Future Renewable Sources of Energy’ (EU Commission, 1997; Mourelatou & Smith, 2004). This document, which was the starting point for the European promotion and development of renewable energy, stated the objective that 12% of energy production in 2010 would come from renewable sources. In Spain, this objective was recognized by the government in 1999 in the Plan to the Promotion of Renewable Energies (PPRE). To achieve this objective, the PPRE focused on increasing the use of biomass, identifying forest residues as one of the biomass sources. Specifically, this document established an increase in the use of forest residual biomass to 450 000 tonnes of petroleum equivalent per year (TPE/year) (IDAE, 1999). Among the different sources of renewable energy, this chapter focuses on forest residual biomass (FRB). This term refers to branches, foliage, and unmerchantable stem tops that are commercially unsuitable in terms of the timber obtained from regular operations in forest management or in timber exploitation (Esteban et al., 2004; IDAE, 1999; Velazquez, 2006). Following the ‘complete-tree concept,’ the term ‘branches’ include the wood and bark of live and dead branches; ‘foliage’ refers to all leaves-needles, new shoots and reproductive organs; and the ‘unmerchantable stem top’ is the upper section of the stem that is left unutilized in logging operations due to its small diameter and high degree of branching (the bottom stem diameter of this unmerchantable top usually ranges from 5 to 10 cm) (Hakkila & Parikka, 2002). The treatments commonly applied to these residues in Spain include controlled burning, stacking within the forest and, less commonly, splintering to improve their incorporation into the soil (IDAE, 2005a, 2007; Velazquez, 2006). However, this biomass segment can also be used as a source of energy in heating applications (fuel for domestic or industrial stoves and boilers) and in the generation of electricity (replacing fossil fuels in power stations) (Asikainen et al., 2002; IDAE, 2005b), with the majority of the residue currently being utilized for the latter in Spain (IDAE, 2007). The benefits associated with this energy-related use can be divided into two types: environmental and socio-economic. The first benefits are generated in the production phase, as the recovery and elimination of FRB reduces the risk of forest fires and their severity (IDAE, 2005a; Velazquez, 2006), and also because the implementation of silviculture can