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This study investigates the rejuvenation mechanism of asphalt binders at the microscopic level and compares the rejuvenation effects of rejuvenators. A model of rejuvenated asphalt was established on the basis of molecular simulation by adding different doses of two rejuvenators to the aged asphalt. This model was validated in terms of density and surface free energy. The diffusion ability of the rejuvenator was investigated by using a diffusion model and mean square displacement. The deagglomeration ability of rejuvenators on asphaltene was explored by using a radial distribution function. The microscopic mechanism of asphalt rejuvenation was explained. Results show that small molecule structures are more diffusible than long-chain structures, and aromatic ring structures are more attracted than polar functional groups. The rejuvenating effect of the rejuvenator was evaluated in terms of viscosity and cohesive energy density. Results show that the long-chain structure reduces the viscosity value more than the small molecule structure. The aromatic ring structure in the aged asphalt helps to restore the compatibility between the fractions. This study serves as a guide for the selection and development of future rejuvenators. [ABSTRACT FROM AUTHOR]

Debris flows are among the most frequent and hazardous disasters worldwide. Debris flow hazard prediction is an important and effective means of engineering disaster mitigation, and rainfall threshold is the core issue in debris flow prediction. This study selected the Laomao Mountain debris flow in Dalian as the research object and explored the relationship among the percentage of coarse sand content of soil, rainfall conditions and the critical rainfall values that induce debris flows on the basis of field investigation data, combined with the results of a flume test, soil suction measurement and geomechanical analysis. The new multi-parameter debris flow initiation warning models were obtained through the mathematical regression analysis method. The critical rainfall values of debris flows in this area were calculated by the previous research on the mechanism of hydraulic debris flow initiation (HIMM). Lastly, the multi-parameter debris flow initiation warning models were compared and analyzed with the critical rainfall values obtained using the HIMM method and the rainfall information available in historical rainfall data, and the reliability of the models was verified. The comparison results showed that the new multi-parameter debris flow initiation warning models can effectively modify the traditional intensity–duration model and have certain reliability and practical values. They can provide an effectual scientific basis for future work on the monitoring and prediction of debris flow disasters. [ABSTRACT FROM AUTHOR]

[Display omitted] • FTCs weakened the shear strength and disintegration resistance of the soil. • Increase of water and salt content exacerbated soil erosion due to FTCs. • The effect of FTCs on soil microstructure was investigated. • The underlying micro-mechanism of the change in soil erodibility was explored. Soda-saline loessal soils are distributed extensively in the Songnen Plain of Northeast China. Freeze-thaw effects on soil structure and mechanical properties are becoming more frequent and intense with global warming, which further affects soil erosion in cold regions. Quantifying the effects of freeze-thaw cycles (FTCs) on the erodibility of saline soils is challenging because of the abundant soluble salt content and complex soil mechanical responses. In this study, direct shear tests, disintegration tests, and scanning electron microscopy were conducted to investigate the effects of freeze-thaw action on the erodibility indicators (shear strength and disintegration velocity) of soda-saline loessal soils and their microscopic deterioration mechanisms. Four initial moisture contents (IMCs: 8%, 13%, 18%, 23%), three soluble salt contents (SSCs: 0.5%, 1.0%, 1.5%), and six FTCs (0, 1, 3, 6, 10, 15) were considered. The results showed that successive FTCs continued to degrade the erosion resistance of the soil until it stabilized after approximately 10 FTCs. After 15 FTCs, the shear strength and cohesion decreased by 8.6–19.8% and 24.1–59.2%, respectively, while the angle of internal friction was relatively unaffected. Meanwhile, the soil disintegration velocity increased by 52.3–208.8%. During the freeze-thaw process, the water-ice phase change and the crystallization of soluble salts both led to the continuous adjustment of the microstructure of soda-saline loessal soils. It was found that microcracks within the soil structural units increased significantly, cementation between the structural units weakened continuously, pore connectivity was enhanced, and pore size homogenization increased. Correlation analysis showed that IMC was the fundamental factor affecting the soil mechanical properties, whereas SSC mainly affected the soil's resistance to disintegration. The increase in IMC and SSC exacerbated the deterioration of the soil by freeze-thaw action. This paper presents a new understanding of the erosion characteristics and micromechanisms of soda-saline loessal soils in seasonally frozen regions under freeze-thaw action. [ABSTRACT FROM AUTHOR]