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Resonant Inelastic soft X-ray Scattering (RIXS) is an ideal tool for the study of intermediate- and low-energy excitations in correlated materials based on 3d transition metals because the L2,3 absorption is strongly resonant and involves directly the 3d valence states. Scattering intensity and energy resolution have been limiting the use of RIXS for several years. Since 2007 at the Swiss Light Source, the SAXES instrument, jointly designed and built by the Paul Scherrer Institut and the Politecnico di Milano together with its host beamline called ADRESS, has marked the field of high-resolution RIXS by reaching a combined resolution of the order of 60–130 meV, a value approximately three times better than any previous apparatus. With such a leap in performance, RIXS has been used for the first time to measure orbital and spin excitations in a variety of 3d transition metal oxides. In particular magnetic excitations in cuprates (2D antiferromagnets, 1D systems, high Tc superconductors) have been the most fruitful research field of RIXS in the last three years, demonstrating that X-rays can be a valid alternative to neutron scattering for the detection of spin, orbital, and charge excitations in transition metal oxides. [ABSTRACT FROM AUTHOR]

Epitaxial films of high critical temperature ( T c ) cuprate superconductors preserve their transport properties even when their thickness is reduced to a few nanometers. However, when approaching the single crystalline unit cell (u.c.) of thickness, T c decreases and eventually, superconductivity is lost. Strain originating from the mismatch with the substrate, electronic reconstruction at the interface and alteration of the chemical composition and of doping can be the cause of such changes. Here, we use resonant inelastic x-ray scattering at the Cu L 3 edge to study the crystal field and spin excitations of NdBa 2 Cu 3 O 7 − x ultrathin films grown on SrTiO 3 , comparing 1, 2 and 80 u.c.-thick samples. We find that even at extremely low thicknesses, the strength of the in-plane superexchange interaction is mostly preserved, with just a slight decrease in the 1 u.c. with respect to the 80 u.c.-thick sample. We also observe spectroscopic signatures for a decrease of the hole-doping at low thickness, consistent with the expansion of the c-axis lattice parameter and oxygen deficiency in the chains of the first unit cell, determined by high-resolution transmission microscopy and x-ray diffraction. [ABSTRACT FROM AUTHOR]

The authors present novel results on the interface between silicon and the high-κ oxides Al2O3 and HfO2 grown by atomic layer deposition. The determination of the thickness of the interfacial layer between oxide and Si(100) is crucial to the evaluation of the performances of devices based on high-κ dielectrics. They find through hard x-ray photoemission spectroscopy (HaXPES) that no interfacial layer forms between Al2O3 and Si(100) whereas almost one monolayer forms between HfO2 and Si(100). HaXPES does not involve any destructive procedure nor any sample preparation. High-energy photoemission could therefore be widely employed for the characterization of real devices. [ABSTRACT FROM AUTHOR]

Taking spinon excitations in the quantum antiferromagnet CaCu2O3 as an example, we demonstrate that femtosecond dynamics of magnetic electronic excitations can be probed by direct resonant inelastic x-ray scattering (RIXS). To this end, we isolate the contributions of single and double spin-flip excitations in experimental RIXS spectra, identify the physical mechanisms that cause them, and determine their respective time scales. By comparing theory and experiment, we find that double spin flips need a finite amount of time to be generated, rendering them sensitive to the core-hole lifetime, whereas single spin flips are, to a very good approximation, independent of it. This shows that RIXS can grant access to time-domain dynamics of excitations and illustrates how RIXS experiments can distinguish between excitations in correlated electron systems based on their different time dependence. [ABSTRACT FROM AUTHOR]

Despite its simple structure and low degree of electronic correlation, SrTiO3 (STO) features collective phenomena linked to charge transport and, ultimately, superconductivity, that are not yet fully explained. Thus, a better insight into the nature of the quasiparticles shaping the electronic and conduction properties of STO is needed. We studied the low-energy excitations of bulk STO and of the LaAlO3/SrTiO3 two-dimensional electron gas (2DEG) by Ti L3 edge resonant inelastic x-ray scattering. In all samples, we find the hallmark of polarons in the form of intense dd+phonon excitations, and a decrease of the LO3-mode electron-phonon coupling when going from insulating to highly conducting STO single crystals and heterostructures. Both results are attributed to the dynamic screening of the large polaron self-induced polarization, showing that the low-temperature physics of STO and STO-based 2DEGs is dominated by large polaron quasiparticles. [ABSTRACT FROM AUTHOR]

We provide a novel experimental method to quantitatively estimate the electron-phonon coupling and its momentum dependence from resonant inelastic x-ray scattering (RIXS) spectra based on the detuning of the incident photon energy away from an absorption resonance. We apply it to the cuprate parent compound NdBa2Cu3O6 and find that the electronic coupling to the oxygen half-breathing phonon branch is strongest at the Brillouin zone boundary, where it amounts to ∼0.17  eV, in agreement with previous studies. In principle, this method is applicable to any absorption resonance suitable for RIXS measurements and will help to define the contribution of lattice vibrations to the peculiar properties of quantum materials. [ABSTRACT FROM AUTHOR]

We have investigated the 3d orbital excitations in CaCuO_{2} (CCO), Nd_{2}CuO_{4} (NCO), and La_{2}CuO_{4} (LCO) using high-resolution resonant inelastic x-ray scattering. In LCO they behave as well-localized excitations, similarly to several other cuprates. On the contrary, in CCO and NCO the d_{xy} orbital clearly disperses, pointing to a collective character of this excitation (orbiton) in compounds without apical oxygen. We ascribe the origin of the dispersion as stemming from a substantial next-nearest-neighbor (NNN) orbital superexchange. Such an exchange leads to the liberation of the orbiton from its coupling to magnons, which is associated with the orbiton hopping between nearest neighbor copper sites. Finally, we show that the exceptionally large NNN orbital superexchange can be traced back to the absence of apical oxygens suppressing the charge transfer energy.

The normal state of optimally doped cuprates is dominated by the “strange metal” phase that shows a linear temperature ( T ) dependence of the resistivity persisting down to the lowest T. For underdoped cuprates, this behavior is lost below the pseudogap temperature T *, where charge density waves (CDWs), together with other intertwined local orders, characterize the ground state. We found that the T -linear resistivity of highly strained, ultrathin, underdoped YBa 2 Cu 3 O 7–δ films is restored when the CDW amplitude, detected by resonant inelastic x-ray scattering, is suppressed. This observation suggests an intimate connection between the onset of CDWs and the departure from T -linear resistivity in underdoped cuprates. Our results illustrate the potential of using strain control to manipulate the ground state of quantum materials.

Despite its simple structure and low degree of electronic correlation, SrTiO_{3} (STO) features collective phenomena linked to charge transport and, ultimately, superconductivity, that are not yet fully explained. Thus, a better insight into the nature of the quasiparticles shaping the electronic and conduction properties of STO is needed. We studied the low-energy excitations of bulk STO and of the LaAlO_{3}/SrTiO_{3} two-dimensional electron gas (2DEG) by Ti L_{3} edge resonant inelastic x-ray scattering. In all samples, we find the hallmark of polarons in the form of intense dd+phonon excitations, and a decrease of the LO3-mode electron-phonon coupling when going from insulating to highly conducting STO single crystals and heterostructures. Both results are attributed to the dynamic screening of the large polaron self-induced polarization, showing that the low-temperature physics of STO and STO-based 2DEGs is dominated by large polaron quasiparticles.

Epitaxial films of high critical temperature ( T c ) cuprate superconductors preserve their transport properties even when their thickness is reduced to a few nanometers. However, when approaching the single crystalline unit cell (u.c.) of thickness, T c decreases and eventually, superconductivity is lost. Strain originating from the mismatch with the substrate, electronic reconstruction at the interface and alteration of the chemical composition and of doping can be the cause of such changes. Here, we use resonant inelastic x-ray scattering at the Cu L 3 edge to study the crystal field and spin excitations of NdBa 2 Cu 3 O 7 - x ultrathin films grown on SrTiO 3 , comparing 1, 2 and 80 u.c.-thick samples. We find that even at extremely low thicknesses, the strength of the in-plane superexchange interaction is mostly preserved, with just a slight decrease in the 1 u.c. with respect to the 80 u.c.-thick sample. We also observe spectroscopic signatures for a decrease of the hole-doping at low thickness, consistent with the expansion of the c -axis lattice parameter and oxygen deficiency in the chains of the first unit cell, determined by high-resolution transmission microscopy and x-ray diffraction.

Cobalt ferrite nanoparticles have been attracting considerable interest in the recent years because of the large number of potential applications, including magnetic storage, magnetic fluid hyperthermia and as contrast agents for magnetic resonance imaging. Physical properties of this class of materials depend critically on a number of parameters, including crystallinity, stoichiometry and cation distribution. In this work we have performed a Resonant Inelastic soft X-ray Scattering (RIXS) study on a series of 5 nm cobalt-doped maghemite nanoparticles to obtain direct quantitative information on cation distribution as a function of cobalt doping. We found that the distribution of divalent cobalt is stable in the investigated doping range and slightly different from that of bulk, stoichiometric cobalt ferrite. These results confirm that cobalt doping can be used to finely tune the magnetic properties of nanostructured ferrites without modifying their structural integrity.

Taking spinon excitations in the quantum antiferromagnet CaCu2O3 as an example, we demonstrate that femtosecond dynamics of magnetic electronic excitations can be probed by direct resonant inelastic x-ray scattering (RIXS). To this end, we isolate the contributions of single and double spin-flip excitations in experimental RIXS spectra, identify the physical mechanisms that cause them, and determine their respective time scales. By comparing theory and experiment, we find that double spin flips need a finite amount of time to be generated, rendering them sensitive to the core-hole lifetime, whereas single spin flips are, to a very good approximation, independent of it. This shows that RIXS can grant access to time-domain dynamics of excitations and illustrates how RIXS experiments can distinguish between excitations in correlated electron systems based on their different time dependence.

We show that in resonant inelastic x-ray scattering (RIXS) at the copper L and M edge direct spin-flip scattering is in principle allowed. We demonstrate how this possibility can be exploited to probe the dispersion of magnetic excitations, for instance magnons, of cuprates such as the high T(c) superconductors. We compute the relevant local and momentum dependent magnetic scattering amplitudes, which we compare to the elastic and dd-excitation scattering intensities. For cuprates these theoretical results put RIXS as a technique on the same footing as neutron scattering.