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International audience; This paper empirically investigates the asymptotic behaviour of the flood probability distribution and more precisely the possible occurrence of heavy tail distributions, generally predicted by multiplicative cascades. Since heavy tails considerably increase the frequency of extremes, they have many practical and societal consequences. A French database of 173 daily discharge time series is analyzed. These series correspond to various climatic and hydrological conditions, drainage areas ranging from 10 to 10(5) km(2), and are from 22 to 95 years long. The peaks-over-threshold method has been used with a set of semi-parametric estimators (Hill and Generalized Hill estimators), and parametric estimators (maximum likelihood and L-moments). We discuss the respective interest of the estimators and compare their respective estimates of the shape parameter of the probability distribution of the peaks. We emphasize the influence of the selected number of the highest observations that are used in the estimation procedure and in this respect the particular interest of the semi-parametric estimators. Nevertheless, the various estimators agree on the prevalence of heavy tails and we point out some links between their presence and hydrological and climatic conditions.

International audience; A rapid and direct spectrofluorimetric method was tested in order to monitor the bioaccumulation of PAHs in Daphnia magna in a control media. After exposure to Water containing benzo[a]pyrene or fluoranthene, daphnids were put in solvent, sonicated, and filtered. The fluorescence spectrum observed in the filtrate was recorded. Results were compared to HPLC measurements of the same pools of organisms. In fluoranthene experiments, the fluorescence peak of the daphnid extract spectrum was linearly related to the PAH content as measured with HPLC. In benzo[a]pyrene experiments, other fluorescent compounds progressively appeared in the sample. They were assumed to be metabolites. A linear regression involving fluorescence intensities at two different wavelengths was necessary for a satisfactory correlation with HPLC measurements, A water extraction was performed to isolate metabolites, None or very few fluoranthene metabolites were isolated in the aqueous phase, whereas increasing ben:a[a]pyrene metabolites were observed while the exposure time increased.