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Environment effects in plasticity and fracture of metals, well studied for several decades, still pose many unanswered questions. A micro-mechanics explanation of how dislocation activity is influenced by the material surface state, that can answer these questions, has been elusive. We build on a recently discovered effect in metal cutting – organic monolayer embrittlement (OME) – wherein metal surfaces are rendered brittle by long-chain organic adsorbates, to explore how material state variables influence surface plasticity and fracture. In particular, cutting experiments with Al containing Self Assembled Monolayers (SAMs), show that the OME is controlled by surface stress (f) induced by the adsorbates. This is contrary to many instances of environment-assisted fracture which are usually attributed to surface energy changes, and wherein f is largely ignored. Other contributions include (a) a cantilever technique to measure surface stress, (b) demonstration of strong effect of SAM molecule chain length on f, (c) characterization of how dislocation activity at crack-tips is affected by adsorbate-induced f, and (d) large improvements in machining processes enabled by controlled environment-assisted fracture. We make the case that surface stress, due to adsorbates, likely influences all environmentally assisted cracking (EAC) phenomena, warranting a revisit of extant models of EAC. [ABSTRACT FROM AUTHOR]

Next‐generation, high‐efficiency energy storage and conversion systems require development of lithium metal batteries. But the high cost of production and constraints on thickness of lithium (anode) foils continue to limit adoption for integration into battery cell architectures. Here, a novel lithium anode manufacturing solution is demonstrated – single‐step production of ultrathin gauge foil formats directly from solid ingot. Hybrid cutting‐based deformation processes, involving large plastic strains and strain rates, produce foil to sub‐10 µm thickness, with surface quality even superior to present Li anode processing routes. Energy analysis shows the single‐stage processing is ≈50% more efficient than conventional processing by extrusion‐rolling. Through in situ force measurements and high‐speed imaging of the cutting it also characterize – for the first time – the flow stress of Li to strain rates of 800 sec−1, revealing a power‐law relationship. The results present a paradigm shift in manufacturing and integration of solid lithium anodes for energy applications. [ABSTRACT FROM AUTHOR]

The question of how soft polymers slide against hard surfaces is of significant scientific interest, given its practical implications. Specifically, such systems commonly show interesting stick–slip dynamics, wherein the interface moves intermittently despite uniform remote loading. The year 2021 marked the 50th anniversary of the publication of a seminal paper by Adolf Schallamach (Wear, 1971), which first revealed an intimate link between stick–slip and moving detachment waves, now called Schallamach waves. We place Schallamach's results in a broader context and review subsequent investigations of stick–slip, before discussing recent observations of solitary Schallamach waves. This variant is not observable in standard contacts so that a special cylindrical contact must be used to quantify its properties. The latter configuration also reveals the occurrence of a dual wave—the so-called separation pulse—that propagates in a direction opposite to Schallamach waves. We show how the dual wave and other, more general, Schallamach-type waves can be described using continuum theory and provide pointers for future research. In the process, fundamental analogues of Schallamach-type waves emerge in nanoscale mechanics and interface fracture. The result is an ongoing application of lessons learnt from Schallamach-type waves to better understand these latter phenomena. This article is part of the theme issue 'Nanocracks in nature and industry'. [ABSTRACT FROM AUTHOR]

The dislocation-indenter interaction is described using contact mechanics in linear, isotropic elasticity. The size dependent behavior is expected to be important during incipient plasticity wherein, dislocation-indenter interactions are expected to play a role in determining plastic flow.

A study has been made of the effect of an externally imposed, low-frequency modulation ([less than or equal to] 100 Hz) on the action of a fluid in machining. It is shown that in conventional machining, fluid action in terms of lubrication is essentially confined to the edges of the chip-tool contact along the tool rake face, with little or no change in the friction condition over much of this face. However, the effectiveness of the lubricating action is significantly enhanced when a controlled low-frequency modulation of sufficient amplitude, such as to break the chip-tool contact, is imposed in the direction of cutting. Measurements show that the friction coefficient between tool and chip is reduced by a factor of up to three in the presence of such a modulation. The extent of the secondary deformation zone in the chip material close to the rake face is also significantly reduced. Direct observations of the tool rake face show that when the modulation is applied, the fluid penetrates into much of the intimate contact region between chip and tool. Keywords: Machining, Modulation, Friction, Lubrication

Taylor's theory of crystal plasticity is reformulated for dislocations in a couple stress medium. The divergence between Taylor's approach and an approach that includes the effects of couple stresses on dislocation interactions is demonstrated. It is shown that dislocations separated by a distance that is comparable to a characteristic material length scale, have mutual interaction somewhat weaker than that predicted by classical elasticity.