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An 11 hours survey was performed on the 17th of September 2014 in the Rhine Region Of Freshwater Influence (Rhine-ROFI) about 10 km downstream of the mouth of the Rotterdam Waterway during calm weather conditions. Suspended Particle Matter (SPM) measurements were performed during a full tidal cycle, near the seabed, at neap tide, and samples were taken at 0.6 meter above bed for on-board analysis. The measurements were performed with (a) LISST 100X, a submersible particle size analyzer, (b) LISST-HOLO, a submersible digital holographic camera, (c) a home-made underwater camera and (d) an on-board LabSFLOC2 video microscopy equipment that used in-situ collected samples. The first aim of the present study was to compare the results obtained from the different monitoring techniques and to characterize the different types of suspended particles found in-situ. It was found that that the highly anisotropic particles present in the water column lead to multiple peaks in the Particle Size Distributions (PSD) found using the LISST 100X. Using the LISST-HOLO, underwater camera and LabSFLOC2 camera these particles could properly be imaged and meaningful PSD’s were obtained using these techniques in the size range > 20 μm. LabSFLOC2, LISST-HOLO and the underwater camera moreover provide information on the size and aspect ratio of particles. On the other hand, LISST 100X can be used to detect the fine fraction (μm), a size range that is not accessible for the other techniques. From the analysis of the data on the survey day, three classes of particles were identified, based on composition rather than size (the sizes given here are purely indicative): (1) mineral (inorganic) sediment particles in the range size 5 - 20 μm, (2) organic/inorganic aggregates in the size range 20 - 200 μm and (3) organic particles in the size range > 200 μm. A large range of settling velocities (0.1 - 10 mm/s) and aspect ratios between 1 and 10 were recorded by video microscopy (LabSFLOC2). This spreading in settling velocities and aspect ratio was due to the different properties (shape, effective density and size) of the particles in the water column. The second aim of the study was to reproduce the flocs found in-situ in the lab and investigate the kinetics of flocculation between inorganic and living organic matter. Laboratory experiments were conducted with grab samples obtained from Port of Rotterdam harbour and living microalgae (Skeletonema costatum). The results of these experiments showed a shift in effective density upon addition of living algae to the sediment, which confirmed the flocculation ability between sediment and microalgae. The flocculation occured on a timescale of minutes and lead to flocs having a large spread in density for a given size, due to the heteregeous inorganic/organic composition of the flocs. This spread in density was at the origin of the large range of settling velocities for a given floc size observed in-situ, which leads to conclude that organic matter should be an important input parameter in sediment transport models.

Sediment is found throughout the world’s alluvial plain rivers, estuarine coasts and adjacent seas and is thereby a key factor in major ecosystems. Suspended mineral sediment can affect the biological activity of microorganisms and plants, by reducing light penetration in the water column or by binding to organic matter. Biological processes can, in turn, affect the physical and chemical properties of the sediment particles and influence the adhesion between particles. They can facilitate the sediment aggregation (flocculation) through bridging, patching and sweep, while biological decay will mainly help to disintegrate organic matter rich flocs. Biological activity also affects the properties of flocs (structure, density, sedimentation rate and composition). This activity is itself influenced by environmental conditions (like temperature, light and nutrient fluxes). Sediment flocculation thus involves complex relationships between several physical, chemical and biological factors. The role of biology in particular needs to be better integrated in sediment transport models, through the interaction between mineral clay particles, microorganisms and their excreted polymers (Extra Polymeric Substances, i.e., EPS). In this article, a summary of the state-of-the-art research regarding sediment flocculation is given. In particular, the action of organic matter on fine-grained sediment flocculation is discussed. The aim of the article is to provide a more comprehensive understanding of bio-sediment dynamics and give an outlook on remaining research questions.

Mud, a cohesive material, consists of water, clay minerals, sand, silt and small quantities of organic matter (i.e., biopolymers). Amongst the different mud layers formed by human or natural activities, the fluid mud layer found on top of all the others is quite important from navigational point of view in ports and waterways. Rheological properties of fluid mud layers play an important role in navigation through fluid mud and in fluid mud transport. However, the rheological properties of mud are known to vary as a function of sampling location within a port, sampling depth and sampling location across the globe. Therefore, this variability in rheological fingerprint of mud requires a detailed and systematic analysis. This chapter presents two different sampling techniques and the measured rheological properties of mud, obtained from laboratory experiments. The six protocols used to measure the yield stresses are detailed and compared. Furthermore, the empirical or semi-empirical models that are commonly used to fit rheological experimental data of such systems are presented. The influence of different factors such as density and organic matter content on the rheological behavior of mud is discussed. The fluidic yield stress of mud samples was observed to vary from 0.2 Pa to 500 Pa as a function of density and organic matter content.

Many projects (Marker Wadden, Kleirijperij) have recently been initiated in the Netherlands that involve the reuse of dredged material from silted channels. This dredged material is deposited in large ponds, and left to consolidate. When its dewatering and strength development is found to be adequate, the consolidate slurry is used as building or filling material for dikes, roads and artificial islands. The consolidation of slurries is a complex process that depends on many physico-chemical aspects. Sediment particles in suspension are interacting and this interaction can lead to time-dependent flocculation and settling rates. Settled flocs will create a very open and fluffy bed that will consolidate over time, exhibiting large strains during the primary consolidation regime. At the same time, a substantial amount of fine particles can remain (unflocculated) in suspension due to Brownian motion. The aim of our research is to link the suspension phase to the consolidating phase in a single model. This model combines a traditional 1D large-strain consolidation model with 1D advection-diffusion model as derived in colloid science in the suspension phase. The model is subsequently tested on various samples from the aforementioned projects.

This paper gives an overview of the research that has been conducted to get a better understanding of the navigation in ports and waterways with fluid mud layers. In particular, the up-to-date review of reported full scale experiments that involve real vessels is provided. To study physical processes, thefull scale experiments are accompanied by scaled experiments and numerical modelling. This combination provides a valuable insight into ship behavior with respect to different navigation conditions and physical properties of fluid mud. Another aspect of this paper are the surveying methods that can localize the fluid mud layers and potentially provide information about the strengthof these layers. Some of these methods were tested on fluid mud produced by water injection dredging in the Port of Rotterdam. It was concluded that the new rheology-based method show a potential for understanding of strength development in fluid mud layers. Finally, some open research questions with respect to the applicability of the navigation through fluid mud are discussed.

We previously proposed (Gourdin-Bertin, S. and Chassagne, C. J. Chem. Phys. 2016, 144 (24)) a simple theoretical model to account for the evolution of conductivity with dielectric permittivity in nonpolar media. In this article, we validate the theory experimentally for the case of an ionogenic species kept at a constant chemical potential (i.e., in equilibrium with a nondissolved salt, in contrast to previously published conductivity measurements carried out as a function of various fully dissolved salt concentrations). To our knowledge, it is the first time that this type of experiment has been performed explicitly.

The flocculation process and modelling of suspended sediment transport in estuarine regions is a hot topic in estuarine science[Winterwerp, 1999]. The flocculation is greatly influenced by biochemical parameters[De Lucas Pardo, 2014]. In this paper, we analyse the impact of algae on the processes of flocculation in the Yangtze Estuary, and we identify the mechanisms which are responsible for their changes. The amount of algae (phytoplankton biomass) is linked to the chlorophyll α concentration which we measured[Uncles et al., 1998]. The measurements were performed in the maximum turbidity zone. The seasonal variations of phytoplankton lead to changes in the flocculation dynamics and the composition of suspended particle matter. We recorded the floc size changes in the Yangtze Estuary and we found that: (1) the flocs are significantly influenced by tidal dynamics, as the floc size during slack water is larger than ebb tide and flood tide, (2) there is a correlation between the Chlorophyll concentration and sediment concentration, (3) the floc size is correlated to the algae-sediment mass ratio, (4) in winter, with high salinity and small river discharge, the region has a significant stratification and the floc size was smaller than the one in summer

The purpose of this paper is to establish a relation between a few measurable quantities (the so-called zeta potential, organic matter content, and shear rate) and the flocculation behavior of mud. The results obtained with small-scale flocculation experiments (mixing jar) are compared to results of large-scale experiments (settling column). The mud used for all experiments has been collected in October 2007 in the lower Western Schelde, near Antwerp, Belgium. From this study, it was found that the mean floc size and the Kolmogorov microscale vary in a similar way with the shear rate for suspensions with different pH and salt concentrations. The size of flocs at a given shear rate depends on the properties of the suspension, which affect the electrokinetic properties of the sediment; these can be described by means of the zeta potential. The main findings of this paper are: (1) In saline suspensions at pH = 8, the mean floc size increases when the salt concentration and the zeta potential increase. (2) For a given zeta potential, the mean floc size at low pH is larger than observed at pH = 8 for any added salt. (3) The mean floc size increases with increasing organic matter content. (4) Mud with no organic matter at pH = 8 and no added salt flocculates very little. The response of mud suspensions to variations in salinity and pH is similar to that of kaolinite. This suggests that a general trend can be established for different and complex types of clays and mud. This systematic study can therefore be used for further development of flocculation models.

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