Search

Pressure induced densification in a molecular arsenic sulfide glass is studied at ambient temperature using x-ray scattering, absorption and Raman spectroscopic techniques in situ in a diamond anvil cell. The relatively abrupt changes in the position of the first sharp diffraction peak, FSDP, and the pressure-volume equation of state near ∼2 GPa suggest a phase transition between low- and high-density amorphous phases characterized by different densification mechanisms and rates. Raman spectroscopic results provide clear evidence that the phase transition corresponds to a topological transformation between a low-density molecular structure and a high-density network structure via opening of the constituent As4S3 cage molecules and bond switching. Pressure induced mode softening of the high density phase suggests a low dimensional nature of the network. The phase transformation is hysteretically reversible, and therefore, reminiscent of a first-order phase transition. [ABSTRACT FROM AUTHOR]

This case study was the first of its kind, where neutron computed tomography (CT) was applied to a wrapped mummified animal. Conventional X‐ray CT was also used to allow for meaningful comparison, and complementary data for a comprehensive investigation. Previous applications of both techniques are limited to metallic objects, such as bronze Buddhas. The mummy used in this study (IA.2402) is dated between the Third Intermediate Period (1069–664 bce) to Late Period (664–332 bce) according to the wrapping style, and was originally believed to contain a complete skeleton of a feline. However, precise date and provenance were unknown. Our results prove the presence of only partial juvenile feline remains, and provide a date range for artefact creation (900–804 bce ± 30) and alteration (367–204 bce ± 30). Therefore, this study implements an established imaging technique (neutron CT) in a novel way, while preserving and conserving the intrinsic value of the artefact through non‐destructive investigation. [ABSTRACT FROM AUTHOR]

High-resolution x-ray diffraction with diamond-anvil cells, using argon as a quasi-hydrostatic pressure medium, documents the crystal structure and equation of state of osmium to over 60 GPa at room temperature. We find the zero-pressure bulk modulus in fair agreement with other experiments as well as with relativistic electronic band-structure calculations: Osmium is the densest but not the most incompressible element at ambient conditions. We also find no evidence for anomalies in the ratio of unit-cell parameters, c/a, or in the compressibility of osmium as a function of pressure. This is in agreement with other experiments and quantum mechanical calculations but disagrees with recent claims that the electronic structure and equation of state of osmium exhibit anomalies at pressures of ∼15-25 GPa; the discrepancies are may be due to the effects of texturing. [ABSTRACT FROM AUTHOR]

The thermodynamic nature of phase stabilities and transformations are investigated in crystalline and amorphous Ge1Sb2Te4 (GST124) phase change materials as a function of pressure and temperature using high-resolution synchrotron x-ray diffraction in a diamond anvil cell. The phase transformation sequences upon compression, for cubic and hexagonal GST124 phases are found to be: cubic → amorphous → orthorhombic → bcc and hexagonal → orthorhombic → bcc. The Clapeyron slopes for melting of the hexagonal and bcc phases are negative and positive, respectively, resulting in a pressure dependent minimum in the liquidus. When taken together, the phase equilibria relations are consistent with the presence of polyamorphism in this system with the as-deposited amorphous GST phase being the low entropy low-density amorphous phase and the laser melt-quenched and high-pressure amorphized GST being the high entropy high-density amorphous phase. The metastable phase boundary between these two polyamorphic phases is expected to have a negative Clapeyron slope. [ABSTRACT FROM AUTHOR]

We studied the compressibility of monolithic fully dense electrodeposited nanocrystalline Ni (∼29 nm grain size) under both quasihydrostatic and nonhydrostatic conditions up to a nominal pressure of 50 GPa using angle-dispersive x-ray diffraction. We obtained an equation of state consistently and unambiguously from each measured reflection. The apparent bulk modulus measured under nonhydrostatic conditions is larger than that of the corresponding coarse-grained material under either type of compression, but is nearly the same when measured under quasihydrostatic conditions. These results may be consistent with a strength, but not necessarily a bulk modulus, that is enhanced in the nanomaterial relative to its coarse-grained counterparts. [ABSTRACT FROM AUTHOR]

The article presents a case study of an 11-month-old baby boy was presented with rashes on the face and arms. Also discusses the diagnosis of variegated pigmentation, telangiectases and erosions on the skin after light microscopy, and identifying frameshift mutation in exons and introns through Sanger sequencing.

Because the deep Earth is not directly accessible, geoscientists rely on laboratory experiments and computer models in order to understand the properties of minerals at the extreme pressure and temperature conditions of deep crust, the mantle and the core. In the field of high-pressure mineral physics and chemistry, we use our understanding of mineral properties, stress–strain relationships in multiphase rocks, and processes such as partial melting at high pressures and temperatures, to interpret geophysical observations of the deep Earth. Studies have constrained the pressure sensitivity of deformation of minerals such as olivine under subduction zone conditions, and the effect of pressure on slip systems in high-pressure minerals such as wadsleyite and perovskite. These results have important implications for the variation of mantle viscosity with depth, the geodynamic interpretation of seismic anisotropy, and changes in mantle rheology as a function of composition. However, the rheology and dynamics of the deep Earth are still poorly understood. Fortunately, technical development has been undertaken over the past 10 years in the USA, and scientific advances have been helped by the development of high-P–T deformation apparatus, such as the large volume multi-anvil deformation apparatus known as the D-DIA. This has opened up the possibility of determining physical and chemical processes in the upper mantle, and into the mantle transition zone. To participate in this exciting new area of research, we are now developing a high-pressure facility at the Australian Synchrotron. In this overview paper, we describe the background and current research that is being conducted in other synchrotron high-pressure facilities and what will now be possible for the Australian Synchrotron. [ABSTRACT FROM PUBLISHER]

Quantum entanglement is the central resource behind quantum information science, from quantum computation and simulation to enhanced metrology and secure communication. These applications require the quantum control of large networks of qubits to realize gains and speed increases over conventional devices. However, propagating entanglement becomes difficult or impossible as the system grows in size. Here, we demonstrate the first step in a modular approach to scaling entanglement by using complementary quantum buses on a collection of three atomic ion qubits stored in two remote ion trap modules. Entanglement within a module is achieved with deterministic near-field interactions through phonons, and remote entanglement between modules is achieved with a probabilistic interaction through photons. This minimal system allows us to address generic issues in the synchronization of entanglement with multiple buses. It points the way towards a modular large-scale quantum information architecture that promises less spectral crowding and thus potentially less decoherence as the number of qubits increases. We generate this modular entanglement faster than the observed remotely entangled qubit-decoherence rate, showing that entanglement can be scaled simply by adding more modules. [ABSTRACT FROM AUTHOR]