1. Spin-orbit entangled j= 12 moments in Ba2CeIrO6: A frustrated fcc quantum magnet
- Author
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Revelli, A., Loo, C. C., Kiese, D., Becker, P., Fröhlich, T., Lorenz, T., Moretti Sala, M., Monaco, G., Buessen, F. L., Attig, J., Hermanns, M., Streltsov, S. V., Khomskii, D. I., van den Brink, J., Braden, M., van Loosdrecht, P. H. M., Trebst, S., Paramekanti, A., and Grüninger, M.
- Subjects
ANTIFERROMAGNETIC MATERIALS ,X RAY SCATTERING ,DOUBLE PEROVSKITES ,Strongly Correlated Electrons (cond-mat.str-el) ,MOTT INSULATORS ,PEROVSKITE ,CURIE-WEISS TEMPERATURE ,FOS: Physical sciences ,QUANTUM ENTANGLEMENT ,GEOMETRIC FRUSTRATION ,CERIUM COMPOUNDS ,CALCULATIONS ,WAVE FUNCTIONS ,Condensed Matter - Strongly Correlated Electrons ,Condensed Matter::Materials Science ,IRIDIUM COMPOUNDS ,BARIUM COMPOUNDS ,GROUND STATE ,HEISENBERG ANTIFERROMAGNETS ,MAGNETOELASTIC EFFECTS ,MODEL CALCULATIONS ,Condensed Matter::Strongly Correlated Electrons ,GROUND STATE WAVEFUNCTIONS ,RESONANT INELASTIC X-RAY SCATTERING - Abstract
We establish the double perovskite Ba$_2$CeIrO$_6$ as a nearly ideal model system for j=1/2 moments, with resonant inelastic x-ray scattering indicating a deviation of less than 1% from the ideally cubic j=1/2 state. The local j=1/2 moments form an fcc lattice and are found to order antiferromagnetically at $T_N$=14K, more than an order of magnitude below the Curie-Weiss temperature. Model calculations show that the geometric frustration of the fcc Heisenberg antiferromagnet is further enhanced by a next-nearest neighbor exchange, indicated by ab initio theory. Magnetic order is driven by a bond-directional Kitaev exchange and by local distortions via a strong magneto-elastic effect - both effects are typically not expected for j=1/2 compounds making Ba2CeIrO6 a riveting example for the rich physics of spin-orbit entangled Mott insulators., Comment: published version, 10 pages, 7 figures
- Published
- 2019