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Two organo‐soluble polyimide (PI) resins were prepared from a tricyclic fluoro‐containing dianhydride 9,9‐bis(trifluoromethyl)xanthene‐2,3,6,7‐tetracarboxylic dianhydride (6FCDA) and aromatic diamine of 2,2‐bis[4‐(4‐aminophenoxy)phenyl]hexafluoropropane (BDAF) for PI‐IIa and 1,3‐bis(3‐aminophenoxy)benzene (133APB) for PI‐IIb, respectively. For comparison, two analogous PIs were prepared from 4,4′‐(hexafluoroisopropylidene)diphthalic anhydride (6FDA) and the same diamines to afford PI‐Ia (6FDA‐BDAF) and PI‐Ib (6FDA‐133APB), respectively. Incorporation of the rigid and planar xanthene units in the 6FCDA‐PIs obviously decreased the solubility of the resins in organic solvents. Flexible and tough PI films were fabricated from the PI solutions in N,N‐dimethylacetamide (DMAc). The PI films derived from the rigid and planar 6FCDA dianhydride exhibited obviously enhance thermal stability, and high‐temperature dimensional stability. For example, PI‐IIa (6FCDA‐BDAF) showed the glass transition temperature (Tg) and coefficient of linear thermal expansion (CTE) values of 311.5°C and 50.5 × 10−6/K, respectively, which were all superior to those of the PI‐Ia counterpart (Tg = 264.6°C; CTE = 55.4 × 10−6/K). In addition, the 6FCDA‐PI films maintained the intrinsically excellent optical transparency of the fluoro‐containing PI films and showed the comparable optical properties to those of the 6FDA‐PI films. As for the properties highly related to the space applications, all the PI films exhibited low solar absorptivity (α) values of 0.18–0.20 and the good thermal emissivity (ε) values in the range of 0.68–0.70. PI‐Ia (6FDA‐BDAF) and PI‐IIa (6FCDA‐BDAF) films showed the similar atomic oxygen erosion behaviors with the standard Kapton® type of PI film derived from pyromellitic dianhydride (PMDA) and 4,4′‐oxydianiline (ODA). [ABSTRACT FROM AUTHOR]

The particle size of sediments below the seabed is a crucial factor affecting the formation and enrichment of gas hydrates. Apart from the formation and enrichment law of gas hydrate in coarse‐grained sediments (dominated by a sandy‐sized fraction), in the fine‐grained sediments (<62.5 μm) which accounts for more than 90% of offshore gas hydrate resources globally, the control effect of sediment particle size on gas hydrate is still unclear. Therefore, understanding the relationship between the fine‐grained sediment particle size and gas hydrate enrichment is essential for revealing the global distribution and dynamic evolution of gas hydrates. Here, we analyzed the vertical gas hydrate saturation, particle size parameters of sediments, whole‐rock minerals, and clay mineral components based on drilling data and sediment samples from fine‐grained gas hydrate reservoirs (GHRs) in the Shenhu area of the northern South China Sea. The results show that in fine‐grained sediments, the coarse particles cannot improve the reservoir quality or enrich the gas hydrate because many fine particles fill the intergranular pores formed by the coarse particles. Meanwhile, the fine particles were dominated by clay minerals, especially in the illite/smectite mixed layer, which significantly reduced the permeability of the sediment layer and was not conducive to the enrichment of gas hydrates. Moreover, sedimentary processes directly control the sediment particle size and mineral composition, which play an essential role in controlling GHRs at the macroscale. In the fine‐grained sediments, very fine sediments (<8 μm) have a more significant negative impact on gas hydrate enrichment. Plain Language Summary: Offshore gas hydrates have great global resources and environmental significance. Gas hydrate is the important pool that stores methane in offshore fine‐grained sediments. However, the formation and enrichment rules of gas hydrate in fine‐grained sediments still need to be clarified. We collected sediment samples from the gas hydrate reservoirs and adjacent layers in the northern South China Sea and analyzed the controlling effect of sediment particle size on the formation and enrichment of gas hydrate in the fine‐grained sediments. We found that the coarse particles in the fine‐grained sediments cannot play a positive role in the enrichment of gas hydrate. The very fine‐grained particles (<8 μm) seriously restrict the formation and enrichment of gad hydrate, which is worthy of attention in fine‐grained reservoirs. Our results on natural sediments partly conform to previous laboratory simulation results on induced gas hydrate formation, effectively establishing potential links between laboratory simulations and natural deposition records. Key Points: Pore‐filling type dominates the gas hydrate in fine‐grained reservoir, particle size between 5 and 6 Φ is beneficial to gas hydrate enrichmentIn fine‐grained gas hydrate reservoir, the very fine‐grained particles (≤8 μm) restricting the enrichment of gas hydrateDifferent sedimentary processes playing an essential role in the formation and enrichment of gas hydrate [ABSTRACT FROM AUTHOR]

To realize the effective profile control of a heavy oil reservoir, hydrolyzed polyacrylamide (HPAM) and water-soluble phenol-formaldehyde resin (PR) were chosen to prepare the profile control system, which gelled at medium or low temperatures and existed stably at high temperatures in the meantime. The effects of phenolic ratios, PR concentration, and HPAM concentration on the formation and strength of the gels were systematically studied by the gel-strength code method and rheological measurements. And the microstructure of the gels was investigated by scanning electron microscope measurements. The results showed that the gelling time of the HPAM-PR system was 13 h at 70 °C. The formed gel could stay stable for 90 days at 140 °C. In addition, the gels showed viscoelastic properties, and the viscosity reached 18,000 mPa·s under a 1.5 s−1 shearing rate due to their three-dimensional cellular network structure. The formation of the gels was attributable to the hydroxyl groups of the PR crosslinking agent, which could undergo the dehydration condensation reaction with amide groups under non-acidic conditions and form intermolecular crosslinking with HPAM molecules. And the organic crosslinker gel system could maintain stability at higher temperatures because covalent bonds formed between molecules. [ABSTRACT FROM AUTHOR]

This multicenter retrospective study aimed to compare the effects of HES and gelatin (GEL) on the risk of post-OLT AKI.

A series of ester‐ and fluoro‐containing thermoplastic polyimide (PI) films, PEsI‐1 ~ PEsI‐4 have been prepared by the two‐step thermal imidization procedure via the soluble poly(amic acid) (PEsAA) precursors from the copolymerization of four monomers, including the dianhydrides of bisphenol A dibenzoate‐3,3′,4,4′‐tetracarboxylic acid dianhydride (TMBPA) and 3,3′, 4,4′‐biphenyl tetracarboxylic acid dianhydride (BPDA) and the diamine monomers of 4‐aminophenyl‐4′‐ aminobenzoate (APAB) and 2,2′‐bis(trifluoromethyl)‐4,4′‐diamino biphenyl (TFMB) in the polar aprotic solvent of N‐methyl‐2‐pyrrolidinone (NMP). The PI films obtained from the high‐temperature dehydration of the PEsAA solutions exhibited the good thermal stabilities with the glass transition temperatures (Tg) over 269°C, the 5% weight loss temperatures (T5%) higher than 480°C, and the linear coefficients of thermal expansion (CTE) values in the range of 17.7 × 10−6/K–33.6 × 10−6/K in the temperature range of 50–250°C. Meanwhile, the PI films showed good thermoplasticity in the dynamic mechanical analysis (DMA) tests, in which the storage modulus of the PI films dropped sharply in the temperature range of glass transition of the polymers. At last, the PI films exhibited the good dielectric properties with the breakdown voltages (Vb) over 5200 V, the dielectric strength (Ds) higher than 210 V/μm, the dielectric constants (Dk) in the range of 3.26 ~ 3.32 at the frequency of 10 GHz, and the dielectric dissipation factors (Df) of 0.0038 ~ 0.0047. Compared with the commonly used PEsI‐ref film for high‐frequency flexible copper clad laminates (FCCL), the currently developed PI films exhibited the obviously increased Tg values, decreased CTE values, and comparable dielectric properties. [ABSTRACT FROM AUTHOR]

Colorless and transparent polyimide (CPI) films with good atomic oxygen (AO) resistance and high thermal endurance are highly required in low earth orbit (LEO) space exploration. Conventional CPI films based on fluoro-containing 4,4′-(hexafluoroisopropylidene)diphthalic anhydride (6FDA) have been widely used in space applications. However, the AO erosion yields and glass transition temperatures (Tg) of the 6FDA-based CPI films have to be modified in order to meet the severe serving environments. In the current work, novel CPI films based on a multi-ring fluoro-containing 9,9-bis(trifluoromethyl)xanthene-2,3,6,7-tetracarboxylicdianhydride (6FCDA) monomer were developed. In order to enhance the AO resistance of the derived CPI film, a phosphorus-containing aromatic diamine, 2,5-bis[(4-aminophenoxy)phenyl]diphenylphosphine oxide (BADPO) was used to polymerize with the dianhydride to create the organo-soluble resin. Then, two phosphorus-containing CPI films (PPI), including PPI-1 (6FDA-BADPO) and PPI-2 (6FCDA-BADPO) were prepared by thermally curing of the PPI solutions at elevated temperatures. The PPI films maintained good optical transparency with transmittance values over 80% at a wavelength of 450 nm. PPI-2 exhibited a Tg value of 311.0 °C by differential scanning calorimetry (DSC) measurement, which was 46.7 °C higher than that of the PPI-1 counterpart (Tg = 264.3 °C). In addition, the PPI-2 film showed a coefficient of linear thermal expansion (CTE) value of 41.7 × 10−6/K in the range of 50~250 °C, which was apparently lower than that of the PPI-1 sample (CTE = 49.2 × 10−6/K). Lastly, both of the two PPI films exhibited good AO resistance with the erosion yields (Ey) of 6.99 × 10−25 cm3/atom for PPI-1 and 7.23 × 10−25 cm3/atom for PPI-2 at an exposure flux of 5.0 × 1020 atoms/cm2. The Ey values of the current PPI films were obviously lower than that of the standard polyimide (PI) film based on pyromellitic dianhydride (PMDA) and 4,4′-oxydianiline (ODA) (Ey = 3.0 × 10−24 cm3/atom). [ABSTRACT FROM AUTHOR]

The well productivity of high-waxy reservoirs is highly influenced by temperature changes. A decrease in temperature can cause the precipitation of wax from the crude oil, leading to a decrease in the formation's drainage capacity and a drop in oil production. In this study, the wax precipitation of crude oil is characterized by rheological properties tests and differential scanning calorimetry (DSC) thermal analysis. The wax damage characteristics of cores and the relative permeability curves at different temperatures were investigated through coreflood experiments. Furthermore, nanoemulsion is selected as a chemical agent for injection fluid. The nuclear magnetic resonance (NMR) scanning technique is used to investigate the effects of oil recovery enhancement at different pores by increasing temperature and adding nanoemulsion. By comparing the changes in T2 spectra and the distribution pattern of residual oil before and after liquid injection, the results have shown that both increasing temperature and adding nanoemulsion have a significant effect on oil recovery. The improvement of micropores is less pronounced compared to macropores. The produced oil mainly comes from the large pores. When the temperature is lower than the crude oil dewaxing point temperature, there is a serious dewaxing plugging phenomenon in the pores. Additionally, by observing the pattern of residual oil distribution at the end of the NMR online drive, it is hereby classified into wax deposition retention type, weak water washing retention type, and immobilized type, each with its own distinct characteristics. Wettability alteration and interfacial tension reduction can help to improve the drainage capacity of high-wax oil reservoirs, which is the main mechanism of nanoemulsion for enhanced oil recovery. These findings are highly valuable for enhancing the comprehension of the impact of highly waxed crude oils on drainage capacity and the ultimate oil recovery rate, particularly in relation to wax precipitation deposition. [ABSTRACT FROM AUTHOR]

Colorless and transparent semi‐alicyclic fluoro‐containing polyimide (PI) nanocomposite films with enhanced high‐temperature dimensional stability and sustained optical transparency were designed and prepared via incorporation of nano‐sized colloidal silica (SiO2) fillers into the PI matrix derived from hydrogenated pyromellitic dianhydride (HPMDA) and 2,2′‐bis[(4‐aminophenoxy)phenyl]hexafluoropropane (BDAF). The derived PI composite films, abbreviated as 6FCPI‐X in which X stands for the weight percent of the SiO2 in the composite films, exhibited superior thermal and comparable optical properties to the pristine 6FCPI‐0 (6FDA‐BDAF) matrix film. For example, as for the thermal properties, 6FCPI‐35 composite film showed a glass transition temperature (Tg) of 279.1°C and a residual weight ratio at 750°C (Rw750) of 66.1%, which were apparently higher than those of 6FCPI‐0 matrix (Tg = 272.2°C; Rw750 = 47.1%). More importantly, the 6FCPI/SiO2 nanocomposite films showed obviously lower linear coefficients of thermal expansion (CTE) values as compared with that of the 6FCPI‐0 matrix. 6FCPI‐35 composite film showed a CTE value of 36.1 × 10−6/K in the temperature range of 50–250°C, which was lower than half of that of the 6FCPI‐0 matrix (CTE = 77.9 × 10−6/K) in the same range of temperature. In addition, incorporation of nano‐sized colloidal SiO2 particles basically maintained the intrinsically good optical properties of the pristine 6FCPI‐0 matrix film. 6FCPI‐35 composite film showed the optical transmittances of 81.7%, 85.3%, and 87.2% at the wavelength of 400 nm (T400), 450 nm (T450), and 500 nm (T500), respectively, which were in the same level with those of the 6FCPI‐0 film (T400 = 84.0%; T450 = 86.3%; T500 = 87.6%). The 6FCPI series of nanocomposite films also exhibited similar CIE Lab color parameters, including the yellow indices (b*) lower than 2.0 and haze values lower than 1.0%. [ABSTRACT FROM AUTHOR]

Two solution‐processable semi‐alicyclic transparent polyimide (PI) films with improved high‐temperature dimensional stability and low‐optical retardations were prepared from the stereo‐isomeric alicyclic dianhydrides, 1S,2R,4S,5R‐hydrogenated pyromellitic dianhydride (ccHPMDA) and 1R,2S,4S,5R‐hydrogenated pyromellitic dianhydride (ctHPMDA) and an aromatic diamine, 9,9‐bis[4‐(4‐aminobenzamide)phenyl]fluorene (FDAADA), respectively. The alicyclic cyclohexane units in the dianhydride moiety endowed the derived PI‐1 (ccHPMDA‐FDAADA) and PI‐2 (ctHPMDA‐FDAADA) films good optical transparency, the rigid‐rod benzanilide units provided the PI films low coefficients of thermal expansion (CTE), and the fluorene units resulted in good solution processability and low‐optical retardations (Rth) for the PI films. The PI films exhibited the glass transition temperatures over 400°C and the CTE value of 33.2 × 10−6/K for PI‐1 and 29.0 × 10−6/K for PI‐2 in the temperature range of 50 ~ 250°C, respectively. In addition, the PI films showed good optical transparency in the ultraviolet–visible light region with the optical transmittances higher than 80% for PI‐1 film at the wavelength of 500 nm. The PI films exhibited the average refractive indices of 1.6505 for PI‐1 and 1.6485 for PI‐2 film, respectively. The birefringence values of the PI films were all lower than 0.01, resulting in the low‐optical anisotropies with the optical retardation (Rth) of 77 nm for PI‐1 film and 84 nm for PI‐2 film. [ABSTRACT FROM AUTHOR]

Nanotechnologies are being increasingly widely used in advanced energy fields. Triboelectric nanogenerators (TENGs) represent a class of new-type flexible energy-harvesting devices with promising application prospects in future human societies. As one of the most important parts of TENG devices, triboelectric materials play key roles in the achievement of high-efficiency power generation. Conventional polymer tribo-negative materials, such as polytetrafluoroethylene (PTFE), polyvinylidene difluoride (PVDF), and the standard polyimide (PI) film with the Kapton® trademark based on pyromellitic anhydride (PMDA) and 4,4′-oxydianiline (ODA), usually suffer from low output performance. In addition, the relationship between molecular structure and triboelectric properties remains a challenge in the search for novel triboelectric materials. In the current work, by incorporating functional groups of trifluoromethyl (–CF3) with strong electron withdrawal into the backbone, a series of fluorine-containing polyimide (FPI) negative friction layers have been designed and prepared. The derived FPI-1 (6FDA-6FODA), FPI-2 (6FDA-TFMB), and FPI-3 (6FDA-TFMDA) resins possessed good solubility in polar aprotic solvents, such as the N,N-dimethylacetamide (DMAc) and N-methyl-2-pyrrolidone (NMP). The PI films obtained via the solution-casting procedure showed glass transition temperatures (Tg) higher than 280 °C with differential scanning calorimetry (DSC) analyses. The TENG prototypes were successfully fabricated using the developed PI films as the tribo-negative layers. The electron-withdrawing trifluoromethyl (–CF3) units in the molecular backbones of the PI layers provided the devices with an apparently enhanced output performance. The FPI-3 (6FDA-TFMDA) layer-based TENG devices showcased an especially impressive open-circuit voltage and short-circuit current, measuring 277.8 V and 9.54 μA, respectively. These values were 4~5 times greater when compared to the TENGs manufactured using the readily accessible Kapton® film. [ABSTRACT FROM AUTHOR]

Polymeric optical films with light colors, good optical transparency and high thermal resistance have gained increasing attention in advanced optoelectronic areas in recent years. However, it is somewhat inter-conflicting for achieving the good optical properties to the conventional thermal resistant polymers, such as the standard aromatic polyimide (PI) films, which are well known for the excellent combined properties and also the deep colors. In this work, a series of wholly aromatic PI films were prepared via the polycondensation chemistry of one fluorene-containing dianhydride, 9,9-bis(3,4-dicarboxyphenyl)fluorene dianhydride (FDAn) and several aromatic diamines with amide linkages in the main chain, including 9,9-bis [4-(4-aminobenzamide)phenyl]fluorene (FDAADA), 2,2′-bis(trifluoromethyl)-4,4′-bis[4-(4-aminobenzamide)] biphenyl (ABTFMB), and 2,2′-bis(trifluoromethyl)-4,4′-bis[4-(4-amino-3-methyl)benzamide] biphenyl (MABTFMB). The derived FLPI-1 (FDAn-FDAADA), FLPI-2 (FDAn-ABTFMB) and FLPI-3 (FDAn-MABTFMB) resins showed good solubility in the polar aprotic solvents, such as N-methyl-2-pyrrolidone (NMP), N,N-dimethylacetamide (DMAc) and dimethyl sulfoxide (DMSO). The solution-processing FDAn-PI films exhibited good optical transmittance over 80.0% at a wavelength of 500 nm (T500), yellow indices (b*) in the range of 1.01–5.20, and haze values lower than 1.0%. In addition, the FDAn-PI films showed low optical retardance with optical retardation (Rth) values in the range of 31.7–390.6 nm. At the same time, the FDAn-PI films exhibited extremely high glass transition temperatures (Tg) over 420 °C according to dynamic mechanical analysis (DMA) tests. The FDAn-PI films showed good dimensional stability at elevated temperatures with linear coefficients of thermal expansion (CTE) in the range of (31.8–45.8) × 10−6/K. [ABSTRACT FROM AUTHOR]

Polyimide (PI) optical films with high glass transition temperatures (high-Tg), high optical transparency, and low optical retardations (low-Rth) are highly desired in advanced optoelectronic applications. However, the standard PI films usually suffer from deep colors, high optical anisotropies and limited Tg values. In the current work, a series of semi-alicyclic colorless and transparent PI (CPI) films were developed from hydrogenated pyromellitic dianhydride stereoisomers, 1S,2R,4S,5R-hydrogenated pyromellitic dianhydride and 1R,2S,4S,5R-hydrogenated pyromellitic dianhydride, and fluorene-containing diamines, including 9,9-bis(4-aminophenyl)fluorene and 9,9-bis(3-fluoro-4-aminophenyl)fluorene, respectively. The derived CPI films showed Tg values higher than 420 °C according to differential scanning calorimetry measurements. In addition, the fluorene-based CPI film showed optical transmittances higher than 80% at the wavelength of 400 nm, with yellow indices in the range of 0.60~1.01 and haze values below 3.0%. The CPI films showed average refractive indices from 1.5407 to 1.6309, extremely low birefringence at the level of minus fourth power of ten, and further exhibited quite low optical retardations below 10 nm. [ABSTRACT FROM AUTHOR]

Light-colored and transparent polyimide (PI) films with good high-temperature dimensional stability are highly desired for advanced optoelectronic applications. However, in practice, the simultaneous achievement of good optical and thermal properties in one PI film is usually difficult due to the inter-conflicting molecular design of the polymers. In the present work, a series of PI-SiO2 nanocomposite films (ABTFCPI) were developed based on the PI matrix derived from hydrogenated pyromellitic anhydride (HPMDA) and an aromatic diamine containing benzanilide and trifluoromethyl substituents in the structure, 2,2′-bis(trifluoromethyl)-4,4′-bis [4-(4-aminobenzamide)]biphenyl (ABTFMB). The inorganic SiO2 fillers were incorporated into the nanocomposite films in the form of colloidal nanoparticles dispersed in the good solvent of N,N-dimethylacetamide (DMAc) for the PI matrix. The derived ABTFCPI nanocomposite films showed good film-forming ability, flexible and tough nature, good optical transparency, and good thermal properties with loading amounts of SiO2 up to 30 wt% in the system. The ABTFCPI-30 film with a SiO2 content of 30 wt% in the film showed an optical transmittance of 79.6% at the wavelength of 400 nm (T400) with a thickness of 25 μm, yellow index (b*) of 2.15, and 5% weight loss temperatures (T5%) of 491 °C, which are all comparable to those the pristine ABTFCPI-0 matrix without filler (T400 = 81.8%; b* = 1.77; T5% = 492 °C). Meanwhile, the ABTFCPI-30 film exhibited obviously enhanced high-temperature dimensional stability with linear coefficients of thermal expansion (CTE) of 25.4 × 10−6/K in the temperature range of 50 to 250 °C, which is much lower than that of the AMTFCPI-0 film (CTE = 32.7 × 10−6/K). [ABSTRACT FROM AUTHOR]

Wen, Xu Taylor, John R. The Routledge Handbook of Cognitive Linguistics London/New York Routledge 2021 978-1-138-49071-0 xx + 772 £ 152 As a comparatively new but rapidly growing language study discipline, cognitive linguistics originated from not only the developments of cognitive science, psychology and other related disciplines between the 1960s and 1970s but also the criticism of Chomskyan linguistics. Completely different from Chomskyan linguistics which emphasizes the formalistic syntactic analysis and assumes language is independent of other cognition forms, cognitive linguistics holds the conception that language is learned and processed substantially in the same way as other types of information about the world, and the identical cognitive processes are involved in language as they are involved in other forms of thinking. Cognitive sociolinguistics explores the compatibilities between cognitive linguistics and sociolinguistics in their approaches and theoretical frameworks, mainly committed to the sociolinguistic variations, lexical variations and language policies, etc. from the perspective of cognitive linguistics ([11]; [6]; [13]; [12]; [9]; [4]). Yuzhi Shi proposes that cognitive linguistics could explain cross-linguistic regularity and that linguistic typology could prove certain theoretical hypotheses of cognitive linguistics. [Extracted from the article]

Machine-type communication (MTC) is one of the main enabling technologies to support various applications with diverse quality of service (QoS) requirements. Finite blocklength transmission has great potential in meeting the strict delay requirements of delay-sensitive MTC devices (MTCDs), while also causing loss of network capacity due to the decoding error probability. Aiming at this problem, we introduce uplink non-orthogonal multiple access (NOMA) and buffer-aided relaying to assist the finite blocklength transmission with delay requirements for improving the achievable effective capacity (EC), which is defined as the maximum short-packet constant arrival rate under specific statistical QoS constraints. To solve the EC maximization problem, we derive the closed-form expression of time allocation coefficient. Then we establish a concave lower bound of EC using successive convex approximation (SCA) for power allocation of MTCDs, and formulate a non-cooperative game based distributed power allocation algorithm for relay. Furthermore, a joint time and power allocation (JTPA) algorithm is proposed to implement joint resource allocation. Simulation results show that under finite blocklength and statistical QoS constraints, adopting buffer-aided relaying can improve EC by 41.82% compared with no-buffer relaying. Moreover, the achievable EC of JTPA algorithm is only 3.12% lower than that of exhaustive search while reducing complexity. [ABSTRACT FROM AUTHOR]

Massive Machine-Type Communication (mMTC) is proposed by ITU to provide a large scale of connectivity services for billions of machine-type communications devices (MTCDs) via cellular networks. However, MTCDs are generally energy-constrained, security capability limited and short-packet transmission dominated. It has great challenges for massive MTCDs to perform short-packet transmission simultaneously while guaranteeing the confidentiality and energy efficiency of the information transmission. In this paper, we investigate the energy-efficient secure short-packet transmission of Non-Orthogonal Multiple Access (NOMA) assisted mMTC networks, in which MTCDs aim to transmit secrecy messages to the destination base station via trusted relays with a passive eavesdropper present. To realize secure, reliable and energy-efficient transmission, we maximize the secrecy energy efficiency (SEE) by implementing joint relay and power level selection. Furthermore, we formulate a decentralized stateless Q-learning-based multi-agent reinforcement learning (MARL) algorithm for the dynamic and complex mMTC systems. The simulation results show that adopting the proposed decentralized MARL algorithm and relaying with NOMA can improve the performance of SEE while reducing information exchange overhead. [ABSTRACT FROM AUTHOR]

Diagenesis typically exerts a crucial impact on the formation of high-quality sandstone reservoirs in the Eocene Shahejie Formation, Dongying Depression. To better understand the formation process of petrophysical properties, this research conducts petrographic and geochemical analyses to investigate the nature of diagenetic fluids. Petrographic observations suggest that the dominant cements are carbonate, authigenic quartz, and clay minerals, accompanied with the dissolution of feldspar and calcite. The homogenization temperature of aqueous inclusions in quartz overgrowth usually exceeds 90°C corresponding to the maturity of organic matter. Quartz overgrowths contain higher amounts of CaO and Al2O3 than detrital quartz. This indicates that the siliceous fluid mainly originates from the dissolution of feldspar. Moreover, the conversion of clay minerals also provides trace amounts of silica into pore water during the burial process. Carbonate cements consist of early-stage calcite as well as late-stage Fe-calcite and ankerite. Calcite with relatively higher MnO proportions shows yellow luminescence and dissolution signs. Fe-calcite and ankerite cements have a higher homogenization temperature than that of quartz overgrowth and mainly concentrate in FeO and MgO as well as contain a small amount of Na+, K+, and Sr2+. The rare earth element (REE) pattern of bulk mudstone and carbonate cements as well as C–O isotopic evidences indicate that the diagenetic fluids of carbonate cementation are primarily controlled by the adjacent mudstone, whereas mineral dissolution and altered clay minerals in sandstone provide additional cations for the local reprecipitation of late-stage carbonate. Therefore, diagenetic fluids within sandstone reservoirs are typically subject to alkaline–acid–alkaline conditions and are influenced by internal sources in a closed system. Compaction significantly reduces the pore space of sandstone reservoirs in the Boxing Sag. Carbonate cementation further increases the complexity of pore structure and obeys the principle of mass balance. [ABSTRACT FROM AUTHOR]

The Ediacaran-Cambrian (E-C) transition period witnessed one of the most important environmental changes in Earth’s history. The western margin of the South China Block (SCB), a shallow-water environment, shows a complete sedimentary record of the E-C transition. Section surveys revealed that dolostone, microbial carbonate, chert, and phosphorite predominantly compose the lithologies of the western margin of the SCB during the E-C transition. Petrological analysis indicates that microbial carbonates in this region exhibit stromatolitic, thrombolytic, cavitated, and sporadic microbial structures. Microbial carbonates with stromatolitic, thrombolytic/cavitated, and sporadic structures correspond to strong, moderate, and weak hydrodynamic conditions, respectively. Microcrystalline dolomites crystallize during the syngenesis stage, while meso- to macrocrystalline and sparry dolomites develop during the burial diagenesis stage. Analysis of major elements and rare earth elements anomalies (δCe: 0.580 ~ 0.753; δEu: 1.234 ~ 1.433) suggests that the siliceous component originates from hot-water sources and is transported into shallow-water environments by upwelling. The absence of a δEu anomaly and the morphology of peloids indicate that the phosphatic component is primarily influenced by biological activity and upwelling. During the Tongwan Movement (545–535 Ma) in the E-C transition period, cyclical upwelling transported increased amounts of deep-source materials into shallow platform waters, leading to higher concentrations of siliceous components and widespread microbial mortality. Following the widespread microbial mortality, the phosphatic component became enriched in deep-water environments. Subsequently, the upwelling transported siliceous- and phosphatic-rich fluids back into the shallow-water environments. The phosphatic component was ultimately assimilated by small shelly fauna and deposited in the phosphatic-rich strata of the early Cambrian period. This study elucidates the origins of complex lithological compositions and the sedimentary evolution model in shallow water environments of the E-C transition period in western SCB, offering evidence for global environmental changes during this period. [ABSTRACT FROM AUTHOR]

Millimeter-wave (mmWave) and ultra-dense networks are two key technologies for the fifth-generation (5G) and beyond communication system. However, the ultra-dense deployment of small base stations (SBSs) might introduce severe interference to users that connect to SBSs. This paper analyzes the performance of 5G communication networks where the SBSs with coordinated beamforming, operating at mmWave frequency band and macro base stations (MBSs) operating at sub-6 GHz coexist. First, by utilizing a stochastic geometry approach, we obtain the cell association probability expressions in terms of different cell association biases, base station density ratios and probabilities of line of sight (LoS) link. Furthermore, we propose a clustering method to choose some SBSs to eliminate intra-cell interference. Then, we put forward an average distance from the Kth SBS to a user to obtain signal-to-interference-ratio (SINR) and rate coverage probability expressions. The simulation results validate the correctness of the expressions, and indicate that the optimal cardinality of coordinated SBSs increases with the density of SBSs. In addition, the relationship between the cluster size K and the average energy efficiency is obtained, which can be used to guide the coordination principle in 5G and beyond communication systems. [ABSTRACT FROM AUTHOR]

Calcite veins, which developed parallel to the bedding, are widespread in laminated source rocks in the Eocene Dongying Depression. However, there is a lack of systematic description and classification of the veins. This study presents a systematic characterization of the calcite veins, host rocks, and micritic carbonate laminae by applying petrographic and geochemical methods to understand vein-forming mechanisms. Antitaxial and syntaxial veins are examined. Antitaxial veins contain typical fibrous crystals with the most intense fluorescence, and the median zone of these veins is often the micritic carbonate. Calcite crystals in syntaxial veins develop a blocky morphology of various sizes, indicating obvious growth competition. Data of rare earth elements and trace elements obtained from the micritic laminae, host rocks, and calcite veins are very similar. This indicates that the vein-forming nutrients originated from the carbonate in the host rocks and micritic laminae. The minor difference in C and Sr isotopes between calcite veins and micritic carbonate within the host rock and the negative shift in O isotopes in the veins are caused by ion exchange and dehydration of swelling clay minerals in the burial environment. This further proves that the calcite veins are formed in a closed system. Geochemical analysis suggests that the rocks are in the oil window and have good hydrocarbon potential. Thermal evolution of the acidic fluids generated from organic matter (OM) resulted in the dissolution of carbonate and formed fluid overpressure in the rocks. Fluid overpressure induced the formation of fractures in the interlayer and expanded the veins with the force of crystallization due to fibrous calcite growth. Blocky crystals grow in the fractures from the margins toward the center. Hydrocarbon expulsed via OM maturation in the host rock fills the intercrystalline pores. Moreover, shale with bedding-parallel calcite has the characteristics of high-quality shale oil reservoirs. These characteristics will probably provide guidance for shale oil exploration. [ABSTRACT FROM AUTHOR]

The 5th-generation (5G) mobile networks and beyond need to support massive machine-type communications (MTC) devices with limited available radio resources. In this paper, we study the power-domain non-orthogonal multiple access (NOMA) technology to support energy-efficient massive MTC networks, where MTC devices exchange information using sporadic and low-rate short packets. We investigate the subchannel allocation and power control policy to maximize the achievable effective energy efficiency (EE) for uplink NOMA-based massive MTC networks, taking into account of short-packet communication characteristics. We model the subchannel allocation problem as a multi-agent Markov decision process and propose an efficient Q-learning algorithm to solve it. Furthermore, we obtain the optimal transmission power policy by approximating the achievable effective rate of uplink NOMA-based short packet communications. Compared with the existing OFDMA scheme, simulations validate that the proposed scheme can improve the achievable effective EE of massive MTC networks with 5.93%. [ABSTRACT FROM AUTHOR]

Tumor cells, including cancer stem cells (CSCs) resistant to radio- and chemotherapy, must enhance metabolism to meet the extra energy demands to repair and survive such genotoxic conditions. However, such stress-induced adaptive metabolic alterations, especially in cancer cells that survive radiotherapy, remain unresolved. In this study, we found that CPT1 (Carnitine palmitoyl transferase I) and CPT2 (Carnitine palmitoyl transferase II), a pair of rate-limiting enzymes for mitochondrial fatty acid transportation, play a critical role in increasing fatty acid oxidation (FAO) required for the cellular fuel demands in radioresistant breast cancer cells (RBCs) and radiation-derived breast cancer stem cells (RD-BCSCs). Enhanced CPT1A/CPT2 expression was detected in the recurrent human breast cancers and associated with a worse prognosis in breast cancer patients. Blocking FAO via a FAO inhibitor or by CRISPR-mediated CPT1A/CPT2 gene deficiency inhibited radiation-induced ERK activation and aggressive growth and radioresistance of RBCs and RD-BCSCs. These results revealed that switching to FAO contributes to radiation-induced mitochondrial energy metabolism, and CPT1A/CPT2 is a potential metabolic target in cancer radiotherapy. [ABSTRACT FROM AUTHOR]

In this paper, we consider the physical layer security for non-orthogonal multiple access (NOMA)-based uplink massive machine type communication (mMTC) networks. Aiming at the maximization of the system secrecy capacity, with the presence of eavesdroppers, we propose a joint power and sub-channel allocation for secrecy capacity (JPSASC) algorithm to obtain the suboptimal solution of the joint problem. Particularly, the power allocation problem is modeled as a non-cooperative game with a distributed perspective, where each MTC device selfishly optimizes its power allocation over multi-channels to maximize its own secrecy capacity. The existence of Nash equilibrium (NE) is proved and a sufficient condition to ensure the uniqueness of NE is given. Moreover, the distributed power allocation and preference secrecy capacity maximum (PSCM) algorithms are proposed for power allocation and sub-channel allocation problem, respectively. Simulation results verify that JPSASC algorithm outperforms other algorithms in maximizing secrecy capacity. Furthermore, the secrecy capacity in NOMA-based mMTC is improved compared with that in orthogonal multiple access schemes. [ABSTRACT FROM AUTHOR]

Sequences of wave‐enhanced sediment‐gravity flows (WESGFs) have been widely recognized in the marine shelf environment. In this study, we show observations of WESGF deposits in lacustrine settings using well core and thin section data from the Paleogene in the Jiyang sub‐basin, Bohai Bay basin, eastern China. The findings of this study include the following: 1) the sequence of WESGFs in the lacustrine basin is similar to that of marine; it consists of three units, MF1 unit: siltstone with basal erosion surface, MF2 unit: silt‐streaked claystone, and MF3 unit: silty‐mudstone; and 2) prodelta sand sheets are found in the lacustrine WESGF sequence and are classified as the MFd unit: clay‐streaked siltstone. However, because the system size and variability in hydrodynamic conditions are different between the lacustrine and marine basins, lacustrine WESGFs do appear to have three distinguishable features: 1) the sediment grain size and sand content are slightly higher than those of the marine WESGFs; 2) lacustrine WESGFs may contain prodelta sediments or sedimentary sequences of other types of gravity flows, such as hyperpycnal flows; and 3) the scale of the sedimentary structures for lacustrine WESGFs is smaller. The WESGFs found in the continental lacustrine basin provide a new model for sediment dispersal processes in lake environments and may be helpful to explain and predict the distribution of sandy reservoirs for oil and gas exploration. [ABSTRACT FROM AUTHOR]

A new cis-caffeoyl coumarin glycoside, cichorigenin-5-O-(4′-cis-caffeoyl)-β-D-glucopyranoside (1), wasisolated from the stem barks of Fraxinus depauperata, together with two known coumarins, cichorigenin (2) and esculin (3). The chemical structures of compounds 1-3 were elucidated through spectroscopic and chemical analysis, as well as by comparison with the literature. Compounds 2 and 3 are reported from this species for the first time. [ABSTRACT FROM AUTHOR]

Two new ternary borates, Rb3MB5O10 (M = Zn, Cd) have been synthesized by solid-state reactions, and their structures were determined by single-crystal X-ray diffraction. They crystallize in the same monoclinic space group P21/n with lattice constants a = 10.449(11) A˚ , b = 9.414(10) A˚ , c = 11.690(12) A˚ , and b = 105.888(11)º for Rb3ZnB5O10, while a = 7.6391(5)A˚ , b =19.2304(13)A˚ , c = 7.6905(5)A˚ , and β = 116.698(4)º for Rb3CdB5O10. And their crystal structures both contain the interesting two-dimension (2D) infinite [MB5O10]1∞ (M = Zn, Cd) layers. However, owing to the different configurations and stacking directions of the [MB5O10]1∞ (M = Zn, Cd) layers, Rb3ZnB5O10 and Rb3CdB5O10 are not isostructural. The IR spectra further confirm the presence of both BO3 and BO4 groups and UV-Vis-NIR diffuse reflectance spectra show their band gaps are 2.66 and 2.34 eV for Rb3ZnB5O10 and Rb3CdB5O10, respectively. [ABSTRACT FROM AUTHOR]

Flexible resource scheduling and network forecast are crucial functions to enhance mobile vehicular network performances. However, BaseStations (BSs) and their computing unit which undertake the functions cannot meet the delay requirement because of limited computation capability. Offloading the time-sensitive functions to User Equipment (UE) is believed to be an effective method to tackle this challenge. The disadvantage of the method is offloading occupies communication resources, which deteriorate the system capability. To better coordinate offloading and communication, a multi-connectivity enhanced joint scheduling scheme for distributed computation offloading and communication resources allocation in vehicular networks is proposed in this article. Computation tasks are divided into many slices and distributed to UEs to aggregate the computation capability. A communication-incentive mechanism is provided for involving UEs to compensate the loss of UEs, while multi-connectivity is adopted to enhance the system throughput. We also defined offloading failure ratio as a conclusive condition for offloading size by analyzing the movement of UEs. By a two-step optimization, the co-scheduling of offloading size and throughput is solved. The system-level simulation results show that the offloading size and throughput of the proposed scheme are larger than comparisons when the time constraint is tight. [ABSTRACT FROM AUTHOR]

The present research study was aimed to identifies the effect of the lithofacies (assemblages) on lacustrine shale oil accumulation, the shale oil layers of the Eocene Shahejie Formation in the Bohai Bay Basin, China, were characterized. The petrological analysis, included core, thin section and scanning electron microscopy observations and X-ray diffraction, indicated that the shale oil layers of the Shahejie Formation are dominated by carbonates, which are characterized by uniform or laminar distributions. The laminar carbonate components were formed through sedimentogenesis or diagenesis. Based on the genesis patterns and the petrology, five major lithofacies (assemblages) were identified in the formation: LF (lithofacies) 1 + 5 is characterized by thin lenticular laminae of crystalline carbonates with black shale; LF2+3 depicts laminae of micritic carbonates with massive lime mudstone; LF3 is a thick layer of massive lime mudstone; LF4 is massive claystone; and LF5 is black shale. The relationship between the lithofacies and the favorability for hosting shale oil reservoirs was investigated using microdrill sampling of the total organic content, reservoir quality analysis, and shale oil-bearing property. In LF1+5, the crystalline carbonates contain abundant interparticle pores, which can act as reservoir spaces, whereas the shale layers have a high potential for hydrocarbon generation. In addition, the hydrocarbon reserves can enter the crystalline carbonates of the assemblage after migrating a short distance. Consequently, LF1+5 is the most favorable assemblage for shale oil accumulation. In addition, LF4 and LF5 have high hydrocarbon generation potentials, and thus a relatively smaller amount of hydrocarbons could accumulate in these assemblages through clay mineral adsorption. Thus, LF4 and LF5 are also valuable sites for shale oil accumulation. • The lacustrine shale oil accumulation could be classified into two categories, "crystalline carbonate reservoir (CCR)" and "in-situ generation and in-situ reservoir (GR)" model. • In CCR model, the crystalline carbonate provides reservoir space and the adjacent shale generate hydrocarbon. • In GR model, the hydrocarbon in-situ is generated and accumulated in shale and mudstone. [ABSTRACT FROM AUTHOR]

• LG- g -PDLA can simultaneously improving the original properties and recovery efficiency of PLLA. • A small amount of PDLA in LG- g -PDLA did not lead to an increase of D-LA production of PLLA. • More L-LA and less D- and meso -LA were recovered from PLLA/LG- g -PDLA at 240 °C. • The thermal degradation of PLLA/LG- g -PDLA was put forward as less random and more unzipping depolymerization.. The biorefinery and high-value utilization are the development tendency in the study of lignin. Lignin- graft -poly(D-lactic acid) (LG- g -PDLA) is a new kind of poly(L-lactide) (PLLA) filler. In order to clarify the effects of LG- g -PDLA on PLLA pyrolysis, PLLA/LG- g -PDLA (1 wt% filler) and pure PLLA were prepared and subjected to reveal the degradation mechanisms with proton and carbon-13 nuclear magnetic resonance spectrometer (H- and 13C-NMR) and gel permeation chromatography (GPC). More L-LA and less D- and meso -lactide (D- and meso -LA) were recovered from PLLA/LG- g -PDLA at 240 °C. By analyzing the NMR and GPC data, the thermal degradation of PLLA/LG- g -PDLA was put forward as being possible mechanisms of less random and more unzipping depolymerization. The results of lactides yields at different conditions better guide the optimization of PLLA recovery. Moreover, this innovative blending approach can simultaneously achieve high-value utilization of lignin and recovery efficiency of PLLA. [ABSTRACT FROM AUTHOR]

As an attempt to shed more light on the utility of blogs in educational contexts, the current research set out to explore the effectiveness of blog-based writing instruction on the writing skill and writing motivation of Chinese English-as-a-Foreign Language (EFL) students. Forty-nine Chinese EFL students from two intact classes in a language school were selected as the participants through convenience sampling. Then they were assigned to an experimental (26 students) and a control condition (23 students) randomly. The students of the experimental group utilized blogs for posting their writing assignments whereas the control group were taught traditionally with no use of blogs or other technology devices. The IELTS writing tasks and L2 writing motivation scale were used for the data collection as pre-and post-tests. The findings revealed that although both groups improved their writing skill and motivation, the participants of the blog group performed better than those in the control group, confirming that the blog-based teaching substantially enhanced the writing skill and writing motivation of the EFL students. These findings may have notable implications for EFL instructors., Competing Interests: The author declares that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest., (Copyright © 2023 Han.)