10 results on '"Marchhart, Oscar"'
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2. Cosmic pears from the Havelland (Germany): Ribbeck, the twelfth recorded aubrite fall in history.
- Author
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Bischoff, Addi, Patzek, Markus, Barrat, Jean‐Alix, Berndt, Jasper, Busemann, Henner, Degering, Detlev, Di Rocco, Tommaso, Ek, Mattias, Harries, Dennis, Godinho, Jose R. A., Heinlein, Dieter, Kriele, Armin, Krietsch, Daniela, Maden, Colin, Marchhart, Oscar, Marshal, Rachael M., Martschini, Martin, Merchel, Silke, Möller, Andreas, and Pack, Andreas
- Subjects
SMALL solar system bodies ,PEARS ,METAL sulfides ,ATMOSPHERE ,COSMIC rays ,ASTEROIDS - Abstract
In 1889 the German poet and novelist Theodor Fontane wrote the popular literary ballad "Herr von Ribbeck auf Ribbeck im Havelland." The Squire von Ribbeck is described as a gentle and generous person, who often gives away pears from his pear trees to children passing by and continued donating pears after his death. Now, 135 years later the rock called Ribbeck is giving us insight into processes that happened 4.5 billion years ago. The meteorite Ribbeck (official find location: 52°37′15″N, 12°45′40″E) fell January 21, 2024, and has been classified as a brecciated aubrite. This meteoroid actually entered the Earth's atmosphere at 00:32:38 UTC over Brandenburg, west of Berlin, and the corresponding fireball was recorded by professional all sky and video cameras. More than 200 pieces (two proved by radionuclide analysis to belong to this fresh fall) were recovered totaling about 1.8 kg. Long‐lived radionuclide and noble gas data are consistent with long cosmic ray exposure (55–62 Ma) and a preatmospheric radius of Ribbeck between 20 and 30 cm. The heavily brecciated aubrite consists of major (76 ± 3 vol%) coarse‐grained FeO‐free enstatite (En99.1Fs<0.04Wo0.9), with a significant abundance (15.0 ± 2.5 vol%) of albitic plagioclase (Ab95.3 An2.0Or2.7), minor forsterite (5.5 ± 1.5 vol%; Fo99.9) and 3.5 ± 1.0 vol% of opaque phases (mainly sulfides and metals) with traces of nearly FeO‐free diopside (En53.2Wo46.8) and K‐feldspar (Ab4.6Or95.4). The rock has a shock degree of S3 (U‐S3), and terrestrial weathering has affected metals and sulfides, resulting in the brownish appearance of rock pieces and the partial destruction of certain sulfides already within days after the fall. The bulk chemical data confirm the feldspar‐bearing aubritic composition. Ribbeck is closely related to the aubrite Bishopville. Ribbeck does not contain solar wind implanted gases and is a fragmental breccia. Concerning the Ti‐ and O‐isotope compositions, the data are similar to those of other aubrites. They are also similar to E chondrites and fall close to the data point for the bulk silicate Earth (BSE). Before the Ribbeck meteoroid entered Earth's atmosphere, it was observed in space as asteroid 2024 BX1. The aphelion distance of 2024 BX1's orbit lies in the innermost region of the asteroid belt, which is populated by the Hungaria family of minor planets characterized by their E/X‐type taxonomy and considered as the likely source of aubrites. The spectral comparison of an average large‐scale emission spectrum of Mercury converted into reflectance and of the Ribbeck meteorite spectrum does not show any meaningful similarities. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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3. The anomalous polymict ordinary chondrite breccia of Elmshorn (H3‐6)—Late reaccretion after collision between two ordinary chondrite parent bodies, complete disruption, and mixing possibly about 2.8 Gyr ago.
- Author
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Bischoff, Addi, Patzek, Markus, Alosius, Romain M. L., Barrat, Jean‐Alix, Berndt, Jasper, Busemann, Henner, Degering, Detlev, Di Rocco, Tommaso, Ek, Mattias, Gattacceca, Jérôme, Godinho, Jose R. A., Heinlein, Dieter, Krietsch, Daniela, Maden, Colin, Marchhart, Oscar, Martschini, Martin, Merchel, Silke, Pack, Andreas, Peters, Stefan, and Rüfenacht, Miriam
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STONE ,NOBLE gases ,MAGNETIC susceptibility ,COSMIC rays ,ISOTOPIC analysis ,CHONDRITES ,CARBONACEOUS chondrites (Meteorites) ,OXYGEN isotopes - Abstract
Elmshorn fell April 25, 2023, about 30 km northwest of the city of Hamburg (Germany). Shortly after the fall, 21 pieces were recovered totaling a mass of 4277 g. Elmshorn is a polymict and anomalous H3‐6 chondritic, fragmental breccia. The rock is a mixture of typical H chondrite lithologies and clasts of intermediate H/L (or L, based on magnetic properties) chondrite origin. In some of the 21 pieces, the H chondrite lithologies dominate, while in others the H/L (or L) chondrite components are prevalent. The H/L chondrite assignment of these components is based on the mean composition of their olivines in equilibrated type 4 fragments (~Fa21–22). The physical properties like density (3.34 g cm−3) and magnetic susceptibility (logχ <5.0, with χ in 10−9 m3 kg−1) are typical for L chondrites, which is inconsistent with the oxygen isotope compositions: all eight O isotope analyses from two different fragments clearly fall into the H chondrite field. Thus, the fragments found in the strewn field vary in mineralogy, mineral chemistry, and physical properties but not in O isotope characteristics. The sample most intensively studied belongs to the stones dominated by H chondrite lithologies. The chemical composition and nucleosynthetic Cr and Ti isotope data are typical for ordinary chondrites. The noble gases in Elmshorn represent a mixture between cosmogenic, radiogenic, and primordially trapped noble gases, while a solar wind component can be excluded. Because the chondritic rock of Elmshorn contains (a) H chondrite parent body interior materials (of types 5 and 6), (b) chondrite parent body near‐surface materials (of types 3 and 4), (c) fragments of an H/L chondrite (dominant in many stones), (d) shock‐darkened fragments, and (e) clasts of various types of impact melts but no solar wind‐implanted noble gases, the different components cannot have been part of a parent body regolith. The most straightforward explanation is that the fragmental breccia of Elmshorn represents a reaccreted rock after a catastrophic collision between an H chondrite parent body and another body with H/L (or L) chondrite characteristics but with deviating O isotope values (i.e. that of H chondrites), complete disruption of the bodies, mixing, and reassembly. This is the only straightforward way that the implantation of solar wind gases could have been avoided in this kind of complex breccia. The gas retention ages of about 2.8 Gyr possibly indicate the closure time after the catastrophic collision between H and H/L (or L) chondrite parent bodies, while the cosmic ray exposure age for Elmshorn, which had a preatmospheric radius of 25–40 cm, is ~17–20 Myr. [ABSTRACT FROM AUTHOR]
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- 2024
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4. Highly sensitive 26Al measurements by Ion-Laser-InterAction Mass Spectrometry
- Author
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Lachner, Johannes, Martschini, Martin, Kalb, Andreas, Kern, Michael, Marchhart, Oscar, Plasser, Felix, Priller, Alfred, Steier, Peter, Wieser, Alexander, and Golser, Robin
- Published
- 2021
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5. 26Al and 10Be concentrations from alluvial drill cores across the Indo-Gangetic plain reveal multimillion-year sediment-transport lag times
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Bhattacharjee, Sohini, Bookhagen, Bodo, Sinha, Rajiv, Wieser, Alexander, and Marchhart, Oscar
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- 2023
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6. Novel 90Sr analysis of environmental samples by Ion-Laser InterAction Mass Spectrometry.
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Honda, Maki, Martschini, Martin, Marchhart, Oscar, Priller, Alfred, Steier, Peter, Golser, Robin, Sato, Tetsuya K., Kazuaki, Tsukada, and Sakaguch, Aya
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- 2022
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7. 5 YEARS OF ION-LASER INTERACTION MASS SPECTROMETRY—STATUS AND PROSPECTS OF ISOBAR SUPPRESSION IN AMS BY LASERS.
- Author
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Martschini, Martin, Lachner, Johannes, Hain, Karin, Kern, Michael, Marchhart, Oscar, Pitters, Johanna, Priller, Alfred, Steier, Peter, Wiederin, Andreas, Wieser, Alexander, and Golser, Robin
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MASS spectrometry ,ACCELERATOR mass spectrometry ,ION energy ,MOLECULAR gas lasers ,ION beams - Abstract
A setup for ion-laser interaction was coupled to the state-of-the-art AMS facility VERA five years ago and its potential and applicability as a new means of isobar suppression in accelerator mass spectrometry (AMS) has since been explored. Laser photodetachment and molecular dissociation processes of anions provide unprecedented isobar suppression factors of >10
10 for several established AMS isotopes like36 Cl or26 Al and give access to new AMS isotopes like90 Sr,135 Cs or182 Hf at a 3-MV-tandem facility. Furthermore, Ion-Laser InterAction Mass Spectrometry has been proven to meet AMS requirements regarding reliability and robustness with a typical reproducibility of results of 3%. The benefits of the technique are in principle available to any AMS machine, irrespective of attainable ion beam energy. Since isobar suppression via this technique is so efficient, there often is no need for any additional element separation in the detection setup and selected nuclides may even become accessible without accelerator at all. [ABSTRACT FROM AUTHOR]- Published
- 2022
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8. Exploration study for trace detection of long lived fission products at VERA
- Author
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Marchhart, Oscar
- Abstract
Beschleuniger-Massespektrometrie (AMS) ist in der Lage extrem niedrige Konzentrationen von Spurenisotopen zu detektieren. Je nach Nuklid können Isotopenverhältnisse von bis zu 10^(–16) gemessen werden. Limitiert wird AMS durch stabile Isobare mit hoher natürlicher Häufigkeit, weil im Massenbereich A~100amu die Isobare weder durch die elektrostatischen Analysatoren und Magnete noch in den Detektoren ausreichend von den Spurenisotopen getrennt werden können. Eine neuartige Methode am Vienna Environmental Research Accelerator (VERA) ist die Unterdrückung von Isobaren durch nicht-resonantes Laser Photodetachment in einem gasgefüllten Hochfrequenzquadrupol mithilfe des Ion Laser Interaction Mass Spectrometry (ILIAMS) Setups. Dies wird durch Überlappen des Ionenstrahls, bestehend aus atomaren oder molekularenn Anionen deren Elektronenaffinitäten (EA) für optische Filterung geeignet sind, mit einem Laserstrahl erreicht. Damit ein Anionensystem geeignet ist muss die EA des Isobars kleiner sein als die EA des Spurenisotops. Dadurch wird das isobare Anion durch Laser Photodetachment neutralisiert während das Spurenisotop unbeeinflusst bleibt. Ziel dieser Masterarbeit war es die Umsetzbarkeit der Messung von Umweltkonzentrationen der langlebigen Spaltprodukte (LLFP) 90-Sr, 99-Tc and 107-Pd mit dem ILIAMS-Setup für VERA zu untersuchen. Die atomaren EA dieser LLFPs sind ungeeignet für Laser Photodetachment, daher müssen entsprechend geeignete molekulare Systeme verwendet werden. Die Untersuchungen bezüglich 90-Sr waren sehr erfolgreich. Erste AMS Messungen konnten mit selbst hergestellten Referenzmaterialien durchgeführt werden. Ein Blanklevel von (4.5±3.2)x10^(–15), was einem Detektionslimit (LoD) von, Accelerator mass spectrometry (AMS) is able to detect extremely low concentrations of trace isotopes. Depending on the chosen nuclide, isotopic ratios down to 10^(–16) can be measured. The interference of abundant stable isobars is the limiting factor of AMS, because in the mass range A~100amu these isobars can not be sufficiently separated from the trace isotopes neither by the electrostatic analyzers and bending magnets nor in the detectors. A novel approach at the Vienna Environmental Research Accelerator (VERA) is to suppress isobars via non-resonant laser photodetachment in a gas-filled radiofrequency quadrupole (RFQ) ion guide with the Ion Laser Interaction Mass Spectrometry (ILIAMS) setup. This is achieved by overlapping the ion beam with a laser beam using elemental or molecular anions whose electron affinities (EA) are suitable for optical filtering. Suitable anionic systems require that the EA of the interfering isobar is lower than that of the isotope of interest. Hence, the unwanted isobars are neutralized via laser photodetachment while the isotope of interest remains unaffected. The aim of this master thesis was to explore the feasibility of measuring environmental concentrations of the long lived fission products (LLFP) 90-Sr, 99-Tc and 107-Pd with the ILIAMS setup at VERA. The elemental EAs of these LLFPs are not suitable for laser photodetachment, therefore suitable molecules have to be used. The investigations on 90-Sr were successful. First AMS measurements with in-house made reference materials were conducted and resulted in a blank level of (4.5±3.2)x10^(–15) corresponding to a limit of detection (LoD)
- Published
- 2020
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9. Correction: Novel 90 Sr analysis of environmental samples by Ion-Laser InterAction Mass Spectrometry.
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Honda M, Martschini M, Marchhart O, Priller A, Steier P, Golser R, Sato TK, Kazuaki T, and Sakaguchi A
- Abstract
Correction for 'Novel
90 Sr analysis of environmental samples by Ion-Laser InterAction Mass Spectrometry' by Maki Honda et al. , Anal. Methods , 2022, 14 , 2732-2738, https://doi.org/10.1039/D2AY00604A.- Published
- 2022
- Full Text
- View/download PDF
10. Novel 90 Sr analysis of environmental samples by Ion-Laser InterAction Mass Spectrometry.
- Author
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Honda M, Martschini M, Marchhart O, Priller A, Steier P, Golser R, Sato TK, Kazuaki T, and Sakaguch A
- Subjects
- Animals, Lasers, Mass Spectrometry methods, Soil, Strontium Radioisotopes analysis
- Abstract
The sensitive analysis of
90 Sr with accelerator mass spectrometry (AMS) was developed to advance environmental radiology. One advantage of AMS is the ability to analyze environmental samples with90 Sr/88 Sr atomic ratios of 10-14 in following a simple chemical separation. Three different IAEA samples with known90 Sr concentrations (moss-soil, animal bone, Syrian soil: 1 g each) were analyzed to assess the validity of the chemical separation and the AMS measurement. The90 Sr measurements were conducted on the AMS system VERA combined with the Ion Laser InterAction Mass Spectrometry (ILIAMS) setup at the University of Vienna, which has excellent isobaric separation performance. The isobaric interference of90 Zr in the90 Sr AMS was first largely removed by chemical separation. The separation factor of Zr in two-step column chromatography with Sr resin and anion exchange resin was 106 . The90 Zr remaining in the sample was effectively suppressed by ILIAMS. This procedure achieved a limit of detection <0.1 mBq in the90 Sr AMS, which is lower than typical β-ray detection. The agreement between AMS measurements and nominal values for the90 Sr concentrations of IAEA samples indicated that the new highly-sensitive90 Sr analysis in the environmental samples with AMS is reliable.- Published
- 2022
- Full Text
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