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6 results on '"Mo, Mingjie"'

2. Catalytic asymmetric synthesis of 1,3-enyne scaffolds: design and synthesis of conjugated nitro dienynes as novel Michael acceptors and development of a new synthetic methodology.

Author

Li, Xiang, Peng, Fangzhi, Zhou, Mingtao, Mo, Mingjie, Zhao, Ruirui, and Shao, Zhihui

Subjects
ENANTIOSELECTIVE catalysis, CARBONYL compounds, TERBINAFINE, ANTINEOPLASTIC antibiotics, MATERIALS science
Abstract

A novel catalytic enantioselective synthesis of functionalized 1,3-enynes has been developed featuring the design and synthesis of conjugated nitro dienynes as a useful new class of Michael acceptors. Moreover, a simple, yet flexible catalytic cascade approach to functionalized enantioenriched acyclic α,β-enones and cyclic dienones has also been developed. [ABSTRACT FROM AUTHOR]

Published
2014
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6. Catalytic asymmetric assembly of C3-monosubstituted chiral carbazolones and concise formal synthesis of (-)-aspidofractinine: application of enantioselective Pd-catalyzed decarboxylative protonation of carbazolones.

Author

Zhao R, Sun Z, Mo M, Peng F, and Shao Z

Subjects
Carbazoles chemistry, Catalysis, Hydrogenation, Indole Alkaloids chemistry, Molecular Structure, Stereoisomerism, Carbazoles chemical synthesis, Indole Alkaloids chemical synthesis, Palladium chemistry
Abstract

The first method for the asymmetric synthesis of C3-monosubstituted chiral carbazolones, structural motifs common in medicinal chemistry, has been achieved using Pd-catalyzed decarboxylative protonation of carbazolones. This methodology has been applied to the first catalytic enantioselective formal synthesis of (-)-aspidofractinine with step economy and simplicity.

Published
2014
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