Search

Your search keyword '"Petersell, W."' showing total 13 results
Start Over Author "Petersell, W." Language english
13 results on '"Petersell, W."'

1. GEMAS: Chemical weathering of silicate parent materials revealed by agricultural soil of Europe

Author

Albanese, S., Andersson, M., Baritz, R., Batista, M.J., Bel-lan, A., Cicchella, D., De Vivo, B., De Vos, W., Dinelli, E., Ďuriš, M., Dusza-Dobek, A., Eklund, M., Ernstsen, V., Filzmoser, P., Flem, B., Flight, D.M.A., Forrester, S., Fuchs, M., Fügedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., De Groot, W., Gulan, A., Halamić, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Kivisilla, J., Klos, V., Krone, F., Kwećko, P., Kuti, L., Lima, A., Locutura, J., Lucivjansky, D.P., Mann, A., Mackovych, D., Matschullat, J., McLaughlin, M., Malyuk, B.I., Maquil, R., Meuli, R.G., Mol, G., O'Connor, P., Oorts, R.K., Ottesen, R.T., Pasieczna, A., Petersell, W., Pfleiderer, S., Poňavič, M., Pramuka, S., Prazeres, C., Rauch, U., Radusinović, S., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A.J., Schoeters, I., Šefčik, P., Sellersjö, E., Skopljak, F., Slaninka, I., Šorša, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojević, D., Zissimos, A., Zomeni, Z., Négrel, Philippe, Ladenberger, Anna, Reimann, Clemens, Demetriades, Alecos, Birke, Manfred, and Sadeghi, Martiya

Published
2023
Full Text
View/download PDF

2. Bioavailable 87Sr/86Sr in European soils: A baseline for provenancing studies

Author

Albanese, S., Andersson, M., Baritz, R., Batista, M.J., Bel-lan, A., Birke, M., Cicchella, D., Demetriades, A., De Vivo, B., De Vos, W., Dinelli, E., Ďuriš, M., Dusza-Dobek, A., Eggen, O.A., Eklund, M., Ernstsen, V., Filzmoser, P., Flight, D.M.A, Forrester, S., Fuchs, M., Fügedi, U., Gilucis, A., Gregorauskiene, V., De Groot, W., Gulan, A., Halamić, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Kivisilla, J., Klos, V., Krone, F., Kwećko, F., Kuti, L., Lima, A., Locutura, J., Lucivjansky, D.P, Mann, A., Mackovych, D., Matschullat, J., McLaughlin, M., Malyuk, B.I, Maquil, R., Meuli, R.G., Mol, G., Negrel, P., Connor, O., Oorts, R.K, Ottesen, R.T., Pasieczna, A., Petersell, W., Pfleiderer, S.., Poňavič, M., Pramuka, S, Prazeres, C., Rauch, U., Radusinović, S., Reimann, C., Sadeghi, M., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A.J, Schoeters, I., Šefčik, P., Sellersjö, E., Skopljak, F., Slaninka, I., Soriano-Disla, J.M., Šorša, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojević, D., Zissimos, A., Zomeni, Z., Hoogewerff, Jurian A., Reimann, Clemens, Ueckermann, Henriette, Frei, Robert, Frei, Karin M., van Aswegen, Thalita, Stirling, Claudine, Reid, Malcolm, Clayton, Aaron, and Ladenberger, Anna

Published
2019
Full Text
View/download PDF

3. GEMAS: PREDICTION OF SOLID-SOLUTION PHASE PARTITIONING COEFFICIENTS (K-d) FOR OXOANIONS AND BORIC ACID IN SOILS USING MID-INFRARED DIFFUSE REFLECTANCE SPECTROSCOPY

Author

Janik, L. J., Forrester, S. T., Soriano Disla, J. M., Kirby, J. K., Mclaughlin, M. J., Reimann, C., ALBANESE, STEFANO, Andersson, M., Baritz, R., Batista, M. J., Bel lan, A., Birke, M., Cicchella, D., Demetriades, A., DE VIVO, BENEDETTO, De Vos, W., Dinelli, E., duriš, M., Dusza Dobek, A., Eggen, O. A., Eklund, M., Ernstsen, V., Filzmoser, P., Flight, D. M. A., Fuchs, M., Fügedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., De Groot, W., Gulan, A., Halamic, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Jordan, G., Kaminari, M., Klos, V., Krone, F., Kwecko, P., Kuti, L., Ladenberger, A., LIMA, ANNAMARIA, Locutura, J., Lucivjansky, P., Mann, A., Mackovych, D., Malyuk, B. I., Maquil, R., Meuli, R. G., Mol, G., Negrel, P., O’Connor, P., Oorts, K., Ottesen, R. T., Pasieczna, A., Petersell, W., Pfleiderer, S., Ponnavic, M., Prazeres, C., Rauch, U., Radusinovic, S., Sadeghi, M., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A. J., Schoeters, I., Sellersj€o, E., Slaninka, I., Šorša, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojevic, D., Zomeni, Z., Janik, L. J., Forrester, S. T., Soriano Disla, J. M., Kirby, J. K., Mclaughlin, M. J., Reimann, C., Albanese, Stefano, Andersson, M., Baritz, R., Batista, M. J., Bel lan, A., Birke, M., Cicchella, D., Demetriades, A., DE VIVO, Benedetto, De Vos, W., Dinelli, E., duriš, M., Dusza Dobek, A., Eggen, O. A., Eklund, M., Ernstsen, V., Filzmoser, P., Flight, D. M. A., Fuchs, M., Fügedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., De Groot, W., Gulan, A., Halamic, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Jordan, G., Kaminari, M., Klos, V., Krone, F., Kwecko, P., Kuti, L., Ladenberger, A., Lima, Annamaria, Locutura, J., Lucivjansky, P., Mann, A., Mackovych, D., Malyuk, B. I., Maquil, R., Meuli, R. G., Mol, G., Negrel, P., O’Connor, P., Oorts, K., Ottesen, R. T., Pasieczna, A., Petersell, W., Pfleiderer, S., Ponnavic, M., Prazeres, C., Rauch, U., Radusinovic, S., Sadeghi, M., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A. J., Schoeters, I., Sellersj€o, E., Slaninka, I., Šorša, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojevic, D., and Zomeni, Z.

Subjects
Anions, Soil, Solid-solution partitioning coefficients (K-d), Metal, metalloid, Anions Metal/metalloid Solid-solution partitioning coefficients (Kd) Mid-infrared spectroscopy Partial least squares regression Soil, Mid-infrared spectroscopy, Partial least squares regression
Abstract

The authors' aim was to develop rapid and inexpensive regression models for the prediction of partitioning coefficients (K-d), defined as the ratio of the total or surface-bound metal/metalloid concentration of the solid phase to the total concentration in the solution phase. Values of K-d were measured for boric acid (B[OH](3)(0)) and selected added soluble oxoanions: molybdate (MoO42-), antimonate (Sb[OH](6-)), selenate (SeO42-), tellurate (TeO42-) and vanadate (VO43-). Models were developed using approximately 500 spectrally representative soils of the Geochemical Mapping of Agricultural Soils of Europe (GEMAS) program. These calibration soils represented the major properties of the entire 4813 soils of the GEMAS project. Multiple linear regression (MLR) from soil properties, partial least-squares regression (PLSR) using mid-infrared diffuse reflectance Fourier-transformed (DRIFT) spectra, and models using DRIFT spectra plus analytical pH values (DRIFT+pH), were compared with predicted log Kd+1 values. Apart from selenate (R-2=0.43), the DRIFT+pH calibrations resulted in marginally better models to predict log Kd+1 values (R-2=0.62-0.79), compared with those from PSLR-DRIFT (R-2=0.61-0.72) and MLR (R-2=0.54-0.79). The DRIFT+pH calibrations were applied to the prediction of log Kd+1 values in the remaining 4313 soils. An example map of predicted log Kd+1 values for added soluble MoO42- in soils across Europe is presented. The DRIFT+pH PLSR models provided a rapid and inexpensive tool to assess the risk of mobility and potential availability of boric acid and selected oxoanions in European soils. For these models to be used in the prediction of log Kd+1 values in soils globally, additional research will be needed to determine if soil variability is accounted on the calibration. Environ Toxicol Chem 2014;9999:1-12. (c) 2014 SETAC

Published
2015
Full Text
View/download PDF

4. Geochemical fingerprinting and source discrimination of agricultural soils at continental scale

Author

Négrel, P., Sadeghi, M., Ladenberger, A., Reimann, C., Birke, M., Albanese, S., Andersson, M., Baritz, R., Batista, M. J., Bel lan, A., Cicchella, D., Demetriades, A., De Vivo, B., De Vos, W., Duriš, M., Dusza Dobek, A., Eggen, O. A., Eklund, M., Ernstsen, V., Filzmoser, P., Flight, D. M. A., Forrester, S., Fuchs, M., Fügedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., De Groot, W., Gulan, A., Halamic, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Kivisilla, J., Klos, V., Krone, F., Kwecko, P., Kuti, L., Lima, A., Locutura, J., Lucivjansky, D. P., Mann, A., Mackovych, D., Mclaughlin, M., Malyuk, B. I., Maquil, R., Meuli, R. G., Mol, G., O'Connor, P., Oorts, R. K., Ottesen, R. T., Pasieczna, A., Petersell, W., Pfleiderer, S., Ponavic, M., Pramuka, S., Prazeres, C., Rauch, U., Radusinovic, S., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A. J., Schoeters, I., Šefcik, P., Sellersjö, E., Skopljak, F., Slaninka, I., Šorša, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojevic, D., Zissimos, A., Z. , Zomeni, DINELLI, ENRICO, Négrel, P., Sadeghi, M., Ladenberger, A., Reimann, C., Birke, M., Albanese, S., Andersson, M., Baritz, R., Batista, M.J., Bel-lan, A., Cicchella, D., Demetriades, A., De Vivo, B., De Vos, W., Dinelli, E., Duriš, M., Dusza-Dobek, A., Eggen, O.A., Eklund, M., Ernstsen, V., Filzmoser, P., Flight, D.M.A., Forrester, S., Fuchs, M., Fügedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., De Groot, W., Gulan, A., Halamic, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Kivisilla, J., Klos, V., Krone, F., Kwecko, P., Kuti, L., Lima, A., Locutura, J., Lucivjansky, D.P., Mann, A., Mackovych, D., Mclaughlin, M., Malyuk, B.I., Maquil, R., Meuli, R.G., Mol, G., O'Connor, P., Oorts, R.K., Ottesen, R.T., Pasieczna, A., Petersell, W., Pfleiderer, S., Ponavic, M., Pramuka, S., Prazeres, C., Rauch, U., Radusinovic, S., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A.J., Schoeters, I., Šefcik, P., Sellersjö, E., Skopljak, F., Slaninka, I., Šorša, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojevic, D., Zissimos, A., Z., Zomeni., Bureau de Recherches Géologiques et Minières (BRGM) (BRGM), Geological Survey of Sweden, sgu, Geological Survey of Norway (NGU), Geological Survey of Norway, and Federal Institute for Geosciences and Natural Resources (BGR)

Subjects
Soil map, genetic structures, Soil test, Weathering, Parent material, Mineralogy, Sediment, Geology, 15. Life on land, Soil type, Agricultural soil, Upper continental crust UCC, Geochemistry, Geochemistry and Petrology, [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry, Soil water, Chemical composition
Abstract

International audience; 2108 agricultural soil samples (Ap-horizon, 0–20 cm) were collected in Europe (33 countries, area 5.6 million km2) as part of the recently completed GEMAS (GEochemical Mapping of Agricultural and grazing land Soil) soil mapping project. GEMAS soil data have been used to provide a general view of element origin and mobility with a main focus on source parent material (and source rocks) at the continental scale, either by reference to average crustal abundances or to normalized patterns of element mobility during weathering processes. The survey area covers a large territory with diverse types of soil parent materials, with distinct geological history and a wide range of climate zones, and landscapes.To normalize the chemical composition of European agricultural soil, mean values and standard deviation of the selected elements have been compared to model compositions of the upper continental crust (UCC) and mean European river suspended sediment. Some elements are enriched relative to the UCC (Al, P, Pb, Zr,) whereas others, such as Mg, Na and Sr are depleted. The concept of the UCC extended normalization pattern has been applied to selected elements. The mean values of Rb, K, Y, Ti, Al, Si, Zr, Ce and Fe are very similar to the values from the UCC model, even when standard deviations indicate slight enrichment or depletion. Zirconium has the best fit to the UCC model using both mean value and standard deviation. Lead and Cr are enriched in European soil when compared to the UCC model, but their standard deviation values span a large, particularly towards very low values, which can be interpreted as a lithological effect.GEMAS soil data have been normalized to Al and Na, taking into account the main lithologies of the UCC, in order to discriminate provenance sources. Additionally, sodium normalization highlights variations related to the soluble and insoluble behavior of some elements (e.g., K, Rb versus Ti, Al, Si, V, Y, Zr, Ba, and La, respectively), their reactivity (e.g, Fe, Mn, Zn) and association with carbonates (e.g., Ca and Sr). Maps of Europe showing the spatial distribution of normalized compositions and element ratios reveal difficulties with the use of classical element ratios because of the large lithological differences in compositions of soil parent material. The ratio maps and color composite images extracted from the GEMAS data can help to discriminate the main lithologies in Europe at the regional scale but need to be used with caution due to the complexity of superimposed processes responsible for the soil chemical composition.

Published
2015
Full Text
View/download PDF

5. Geochemical fingerprinting and sources discrimination in soils and sediments at continental scale

Author

Négrel, P., Sadeghi, M., Ladenberger, A., Reimann, C., Birke, M., ALBANESE, STEFANO, Andersson, M., Baritz, R., Batista, M. J., Bel lan, A., Cicchella, D., Demetriades, A., DE VIVO, BENEDETTO, De Vos, W., Dinelli, E., Ďuriš, M., Dusza Dobek, A., Eggen, O. A., Eklund, M., Ernstsen, V., Fabian, K., Filzmoser, P., Flight, D. M. A., Forrester, S., Fuchs, M., Fügedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., de Caritat, P., De Groot, W., Gulan, A., Halamić, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Kivisilla, J., Klos, V., Krone, F., Kwećko, P., Kuti, L., LIMA, ANNAMARIA, Locutura, J., Lucivjansky, D. P., Mann, A., Mackovych, D., Mclaughlin, M., Malyuk, B. I., Maquil, R., Meuli, R. G., Mol, G., O’Connor, P., Oorts, R. K., Ottesen, R. T., Pasieczna, A., Petersell, W., Pfleiderer, S., Poňavič, M., Pramuka, S., Prazeres, C., Rauch, U., Radusinović, S., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A. J., Schoeters, I., Šefčik, P., Sellersjö, E, Skopljak, F., Slaninka, I., Šorša, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Turner, N., Valera, P., Verougstraete, V., Vidojević, D., Zissimos, Z. Zomeni, A. Zissimos, Z. Zomeni, Négrel, P., Sadeghi, M., Ladenberger, A., Reimann, C., Birke, M., Albanese, Stefano, Andersson, M., Baritz, R., Batista, M. J., Bel lan, A., Cicchella, D., Demetriades, A., DE VIVO, Benedetto, De Vos, W., Dinelli, E., Ďuriš, M., Dusza Dobek, A., Eggen, O. A., Eklund, M., Ernstsen, V., Fabian, K., Filzmoser, P., Flight, D. M. A., Forrester, S., Fuchs, M., Fügedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., de Caritat, P., De Groot, W., Gulan, A., Halamić, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Kivisilla, J., Klos, V., Krone, F., Kwećko, P., Kuti, L., Lima, Annamaria, Locutura, J., Lucivjansky, D. P., Mann, A., Mackovych, D., Mclaughlin, M., Malyuk, B. I., Maquil, R., Meuli, R. G., Mol, G., O’Connor, P., Oorts, R. K., Ottesen, R. T., Pasieczna, A., Petersell, W., Pfleiderer, S., Poňavič, M., Pramuka, S., Prazeres, C., Rauch, U., Radusinović, S., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A. J., Schoeters, I., Šefčik, P., Sellersjö, E, Skopljak, F., Slaninka, I., Šorša, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Turner, N., Valera, P., Verougstraete, V., Vidojević, D., Zissimos, Z. Zomeni, A. Zissimo, and Z., Zomeni

Abstract

2108 agricultural soil samples (Ap-horizon, 0-20 cm) were collected in Europe (33 countries, area 5.6 million km(2)) as part of the recently completed GEMAS (GEochemical Mapping of Agricultural and grazing land Soil) soil mapping project. GEMAS soil data have been used to provide a general view of element origin and mobility with a main focus on source parent material (and source rocks) at the continental scale, either by reference to average crustal abundances or to normalized patterns of element mobility during weathering processes. The survey area covers a large territory with diverse types of soil parent materials, with distinct geological history and a wide range of climate zones, and landscapes. To normalize the chemical composition of European agricultural soil, mean values and standard deviation of the selected elements have been compared to model compositions of the upper continental crust (UCC) and mean European river suspended sediment. Some elements are enriched relative to the UCC (Al, P, Pb, Zr,) whereas others, such as Mg, Na and Sr are depleted. The concept of the UCC extended normalization pattern has been applied to selected elements. The mean values of Rb, K, Y, Ti, Al, Si, Zr, Ce and Fe are very similar to the values from the UCC model, even when standard deviations indicate slight enrichment or depletion. Zirconium has the best fit to the UCC model using both mean value and standard deviation. Lead and Cr are enriched in European soil when compared to the UCC model, but their standard deviation values span a large, particularly towards very low values, which can be interpreted as a lithological effect. GEMAS soil data have been normalized to Al and Na, taking into account themain lithologies of the UCC, in order to discriminate provenance sources. Additionally, sodium normalization highlights variations related to the soluble and insoluble behavior of some elements (e.g., K, Rb versus Ti, Al, Si, V, Y, Zr, Ba, and La, respectively), their reactivity (e.g, Fe, Mn, Zn) and association with carbonates (e.g., Ca and Sr). Maps of Europe showing the spatial distribution of normalized compositions and element ratios reveal difficulties with the use of classical element ratios because of the large lithological differences in compositions of soil parent material. The ratio maps and color composite images extracted from the GEMAS data can help to discriminate the main lithologies in Europe at the regional scale but need to be used with caution due to the complexity of superimposed processes responsible for the soil chemical composition.

Published
2015

6. Mobile Metal Ion analysis of European agricultural soils : bioavailability, weathering, geogenic patterns and antrhropogenic anomalies

Author

Mann, A., Reimann, C., De Caritat, P., Turner, N., Birke, M., Albanese, S., Andersson, M., Baritz, R., Batista, M. J., Bel-Lan, A., Cicchella, D., Demetriades, A., De Vivo, B., De Vos, W., Dinelli, E., uri?, M., Dusza-Dobek, A., Eggen, O. A., Eklund, M., Ernstsen, V., Fabian, K., Filzmoser, P., Flight, D., Forrester, S., Fuchs, M., Fügedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., De Groot, W., Gulan, A., Halami?, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Kivisilla, J., Klos, V., Krone, F., Kwe?ko, P., Kuti, L., Ladenberger, A., Lima, A., Locutura, J., Lucivjansky, D. P., Mackovych, D., McLaughlin, M., Malyuk, B. I., Maquil, R., Meuli, R. G., Mol, G., Negrel, P., O'Connor, P., Oorts, R. K., Ottesen, R. T., Pasieczna, A., Petersell, W., Pfleiderer, S., Po?avi?, M., Pramuka, S., Prazeres, C., Rauch, U., Radusinovi?, S., Sadeghi, M., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A. J., Schoeters, I., ef?ik, P., Sellersjö, E., Skopljak, F., Slaninka, I., or?a, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojevi?, D., Zissimos, A., Zomeni, Z., Mann, A., Reimann, C., De Caritat, P., Turner, N., Birke, M., Albanese, S., Andersson, M., Baritz, R., Batista, M.J., Bel-Lan, A., Cicchella, D., Demetriades, A., De Vivo, B., De Vos, W., Dinelli, E., Ďuriš, M., Dusza-Dobek, A., Eggen, O.A., Eklund, M., Ernstsen, V., Fabian, K., Filzmoser, P., Flight, D., Forrester, S., Fuchs, M., Fügedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., De Groot, W., Gulan, A., Halamić, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Kivisilla, J., Klos, V., Krone, F., Kwećko, P., Kuti, L., Ladenberger, A., Lima, A., Locutura, J., Lucivjansky, D.P., Mackovych, D., Mclaughlin, M., Malyuk, B.I., Maquil, R., Meuli, R.G., Mol, G., Negrel, P., O’Connor, P., Oorts, R.K., Ottesen, R.T., Pasieczna, A., Petersell, W., Pfleiderer, S., Poňavič, M., Pramuka, S., Prazeres, C., Rauch, U., Radusinović, S., Sadeghi, M., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A.J., Schoeters, I., Šefčik, P., Sellersjö, E., Skopljak, F., Slaninka, I., Šorša, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojević, D., Zissimos, A., Zomeni, Z., de Caritat, P., Albanese, Stefano, Batista, M. J., Bel lan, A., DE VIVO, Benedetto, Dusza Dobek, A., Eggen, O. A., Flight, D. M. A., Lima, Annamaria, Lucivjansky, D. P., Malyuk, B. I., Meuli, R. G., Oorts, R. K., Ottesen, R. T., Scheib, A. J., Sellersjö, E, Zissimos, Z. Zomeni, A. Zissimo, and Z., Zomeni

Subjects
Lithology, Mineralogy, Weathering, GEMAS, Metal, chemistry.chemical_compound, Geochemistry and Petrology, Aqua regia, ICP-MS, geogenic pattern, anthropogenic anomalie, General Environmental Science, geochemical mapping, business.industry, Geogenic patterns, MMI (R) extraction, General Chemistry, mobile, metal, ion, Bioavailability, chemistry, Agriculture, visual_art, Environmental chemistry, Anthropogenic anomalies, Soil water, visual_art.visual_art_medium, General Earth and Planetary Sciences, MMI® extraction, business, bioavailability, Geology
Abstract

Two thousand one hundred and eight agricultural soils (0–20 cm depth) collected at a density of one sample per 2500 km2 under the auspices of the Geochemical Mapping of Agricultural Soils (GEMAS) project over most of the European continent have been analysed using the Mobile Metal Ion (MMI®) partial extraction technique with ICP-MS finish. For a number of elements, notably Ce, Ni, and Ca, coherent geogenic patterns have been observed which relate to underlying lithology. For Fe and Al, coherent patterns are also observed but the effects of weathering are evident, and provide a mechanism to explain the acidity of soils in high rainfall areas. Individual anomalies, many related to anthropogenic activity (mining, metallurgy, agriculture) have been observed for Ag, Au, Cu, Pb, Cd and Zn. Comparison of the results with aqua regia digestion and the equivalent National Geochemistry Survey of Australia (NGSA) provides insights into weathering processes and the concept of bioavailability. © 2015 AAG/The Geological Society of London.

Published
2015
Full Text
View/download PDF

7. GEMAS: Prediction of solid-solution partitioning coefficients (Kd) for cationic metals in soils using mid-infrared diffuse reflectance spectroscopy

Author

Janik, L. J., Forrester, S. T., Soriano Disla, J. M., Kirby, J. K., McLaughlin, M. J., Reimann, C., Andersson, M., Baritz, R., Batista, M. J., Bel lan, A., Birke, M., Cicchella, D., Demetriades, A., De Vos, W., Dinelli, E., Ďuriš, M., Dusza Dobek, A., Eggen, O. A., Eklund, M., Ernstsen, V., Filzmoser, P., Flight, D. M. A., Fuchs, M., Fügedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., De Groot, W., Gulan, A., Halamić, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Jordan, G., Kaminari, M., Klos, V., Krone, F., Kwećko, P., Kuti, L., Ladenberger, A., Locutura, J., Lucivjansky, P., Mann, A., Mackovych, D., Malyuk, B. I., Maquil, R., Meuli, R. G., Mol, G., Négrel, P., O'Connor, P., Oorts, K., Ottesen, R. T., Pasieczna, A., Petersell, W., Pfleiderer, S., Poňavič, M., Prazeres, C., Rauch, U., Radusinović, S., Sadeghi, M., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A. J., Schoeters, I., Sellersjö, E, Slaninka, I., Šorša, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojević, D., Zomeni, Z., ALBANESE, STEFANO, DE VIVO, BENEDETTO, LIMA, ANNAMARIA, Janik, L. J., Forrester, S. T., Soriano Disla, J. M., Kirby, J. K., Mclaughlin, M. J., Reimann, C., Albanese, Stefano, Andersson, M., Baritz, R., Batista, M. J., Bel lan, A., Birke, M., Cicchella, D., Demetriades, A., DE VIVO, Benedetto, De Vos, W., Dinelli, E., Ďuriš, M., Dusza Dobek, A., Eggen, O. A., Eklund, M., Ernstsen, V., Filzmoser, P., Flight, D. M. A., Fuchs, M., Fügedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., De Groot, W., Gulan, A., Halamić, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Jordan, G., Kaminari, M., Klos, V., Krone, F., Kwećko, P., Kuti, L., Ladenberger, A., Lima, Annamaria, Locutura, J., Lucivjansky, P., Mann, A., Mackovych, D., Malyuk, B. I., Maquil, R., Meuli, R. G., Mol, G., Négrel, P., O'Connor, P., Oorts, K., Ottesen, R. T., Pasieczna, A., Petersell, W., Pfleiderer, S., Poňavič, M., Prazeres, C., Rauch, U., Radusinović, S., Sadeghi, M., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A. J., Schoeters, I., Sellersjö, E, Slaninka, I., Šorša, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojević, D., and Zomeni, Z.

Subjects
Cations Solid-solution partitioning coefficients (Kd) Mid-infrared spectroscopy Partial least squares regression Soil
Abstract

Partial least squares regression (PLSR) models, using mid-infrared (MIR) diffuse reflectance Fourier-transformed (DRIFT) spectra,wereusedtopredictdistributioncoefficient(Kd)valuesforselectedaddedsolublemetalcations(Agþ,Co 2þ,Cu 2þ,Mn 2þ,Ni 2þ, Pb2þ, Sn 4þ, and Zn2þ) in 4813 soils of the Geochemical Mapping of Agricultural Soils (GEMAS) program. For the development of the PLSR models, approximately 500 representative soils were selected based on the spectra, and Kd values were determined using a singlepointsolublemetal orradioactiveisotopespike.Theoptimummodels, usingacombinationofMIR–DRIFTspectra andsoilpH,resulted ingoodpredictionsforlogKdþ1forCo,Mn,Ni,Pb,andZn(R20.83)butpoorpredictionsforAg,Cu,andSn(R2

Published
2015

8. The EuroGeoSurveys geochemical mapping of agricultural and grazing land soils project (GEMAS) - Evaluation of quality control results of aqua regia extraction analysis

Author

REIMANN C., DEMETRIADES A., EGGEN O. A., FILMOZER P., THE EUROGEOSURVEYS GEOCHEMISTRY EXPERT GROUP, ALBANESE S., BATISTA M. J., BEL LAN A., BIRKE M., CICCHELLA D., DE VIVO B., DE VOS W., DURIS M., DUSZA DOBEK A., ERNSTSEN V., FLIGHT D., GILUCIS A., GOSAR M., GREGORAUSKIENE V., GULAN A., HAYOZ P., HALAMIC J., HASLINGER E., HRATOVIC H., ION A., IVANOVNA Y., JOHNSON C., JORDAN G., KISIVILLA J., KLEIN P., KWECKO P., LAX K., LIMA A., LOCUTURA J., MALYUK B. I., MAQUIL R., MARKU S., MARTINS L., MAZREKU A., MESSINA A., O’CONNOR P. J., OTTESEN R. T., PASIECZNA A., PETERSELL W., REEDER S., SALPETEUR I., SCHEDL A., SEFCIK P., SLANINKA I., SORSA A., SELINUS O., STAFILOV T., TARVAINEN T., TRENDAVILOV V., UTERMANN J., VALERA P., VIDOJEVIC D., VOLDEN T., DINELLI, ENRICO, REIMANN C., DEMETRIADES A., EGGEN O.A., FILMOZER P., THE EUROGEOSURVEYS GEOCHEMISTRY EXPERT GROUP, ALBANESE S., BATISTA M. J., BEL-LAN A., BIRKE M., CICCHELLA D., DE VIVO B., DE VOS W., DINELLI E., DURIS M., DUSZA-DOBEK A., ERNSTSEN V., FLIGHT D., GILUCIS A., GOSAR M., GREGORAUSKIENE V., GULAN A., HAYOZ P., HALAMIC J., HASLINGER E., HRATOVIC H., ION A., IVANOVNA Y., JOHNSON C., JORDAN G., KISIVILLA J., KLEIN P., KWECKO P., LAX K., LIMA A., LOCUTURA J., MALYUK B. I., MAQUIL R., MARKU S., MARTINS L., MAZREKU A., MESSINA A., O’CONNOR P. J., OTTESEN R. T., PASIECZNA A., PETERSELL W., REEDER S., SALPETEUR I., SCHEDL A., SEFCIK P., SLANINKA I., SORSA A., SELINUS O., STAFILOV T., TARVAINEN T., TRENDAVILOV V., UTERMANN J., VALERA P., VIDOJEVIC D., and VOLDEN T.

Abstract

Rigorous quality control (QC) is one of the keystones to the success of any regional geochemical mapping programme. For the EuroGeoSurveys (EGS) GEMAS (Geochemical mapping of agricultural and grazing land soils) project 2211 samples (including field duplicates) of agricultural soil (Ap, Ap-horizon, 0-20 cm) and 2118 samples (including field duplicates) from land under permanent grass cover ("grazing land" - Gr, topsoil 0-10 cm) were collected from a large part of Europe, centrally prepared (air dried, sieved to

Published
2009

9. EuroGeoSurveys geochemical mapping of agricultural and grazing land soil of Europe (GEMAS). Field manual

Author

REIMANN C., ALBANESE S., BATISTA M. J., BEL LAN A., BIRKE M., CICCHELLA D., DEMETRIADES A., DE VIVO B., DE VOS W., DURIS M., DUSZA DOBEK A., ERNSTSEN V., FLIGHT D., GILUCIS A., GOSAR M., GREGORAUSKIENE V., GULAN A., HAYOZ P., HALAMIC J., HASLINGER E., HRATOVIC H., ION A., IVANOVNA Y., JOHNSON C., JORDAN G., KISIVILLA J., KLEIN P., KWECKO P., LAX K., LIMA A., LOCUTURA J., MALYUK B. I., MAQUIL R., MARKU S., MARTINS L., MAZREKU A., MESSINA A., O’CONNOR P. J., OTTESEN R. T., PASIECZNA A., PETERSELL W., REEDER S., SALPETEUR I., SCHEDL A. | SEFCIK P., SLANINKA I., SORSA A., SELINUS O., STAFILOV T., TARVAINEN T., TRENDAVILOV V., UTERMANN J., VALERA P., VIDOJEVIC D., VOLDEN T., DINELLI, ENRICO, REIMANN C., ALBANESE S., BATISTA M. J., BEL-LAN A., BIRKE M., CICCHELLA D., DEMETRIADES A., DE VIVO B., DE VOS W., DINELLI E., DURIS M., DUSZA-DOBEK A., ERNSTSEN V., FLIGHT D., GILUCIS A., GOSAR M., GREGORAUSKIENE V., GULAN A., HAYOZ P., HALAMIC J., HASLINGER E., HRATOVIC H., ION A., IVANOVNA Y., JOHNSON C., JORDAN G., KISIVILLA J., KLEIN P., KWECKO P., LAX K., LIMA A., LOCUTURA J., MALYUK B. I., MAQUIL R., MARKU S., MARTINS L., MAZREKU A., MESSINA A., O’CONNOR P. J., OTTESEN R. T., PASIECZNA A., PETERSELL W., REEDER S., SALPETEUR I., SCHEDL A.| SEFCIK P., SLANINKA I., SORSA A., SELINUS O., STAFILOV T., TARVAINEN T., TRENDAVILOV V., UTERMANN J., VALERA P., VIDOJEVIC D., and VOLDEN T.

Abstract

REACH (Registration, Evaluation and Authorisation of Chemicals), the new European Chemicals Regulation was adopted in December 2006. It came into force on the 1st June 2007. REACH, as well as the pending EU Soil Protection Directive, require additional knowledge about "soil quality" at the European scale. The GEMAS (geochemical mapping of agricultural soils and grazing land of Europe) project aims at providing harmonized geochemical data of arable land and land under permanent grass cover at the continental, European scale. Geological Surveys in 34 European countries, covering an area of 5.6 million km2, have agreed to sample their territory at a sample density of 1 site each, arable land (0-20 cm) and land under permanent grass cover (0-10 cm), per 2500 km2. Sampling will take place during 2008, following a jointly agreed field protocol which is presented in this report. All samples will be prepared in just one laboratory, a strict quality control procedure has been established and all samples will always be jointly analyzed in just one laboratory for any one chemical element/parameter.

Published
2008

10. Geochemical evidence of aeolian deposits in European soils

Author

Scheib A.J., Birke M., Dinelli E., Albanese S., Andersson M., Baritz R., Batista M.J., Bel-lan A., Cicchella D., Demetriades A., De Vivo B., De Vos W., DuriS M., Dusza-Dobek A., Eggen O.A., Eklund M., Ernstsen V., Filzmoser P., Flight D.M.A., Forrester S., Fuchs M., Fugedi U., Gilucis A., Gosar M., Gregorauskiene V., De Groot W., Gulan A., Halamic J., Haslinger E., Hayoz P., Hoffmann R., Hoogewerff J., Hrvatovic H., Husnjak S., Janik L., Jordan G., Kaminari M., Kirby J., Kivisilla J., Klos V., Krone F., Kwecko P., Kuti L., Ladenberger A., Lima A., Locutura J., Lucivjansky D.P., Mann A., Mackovych D., McLaughlin M., Malyuk B.I., Maquil R., Meuli R.G., Mol G., Negrel P., O'Connor P., Oorts R.K., Ottesen R.T., Pasieczna A., Petersell W., Pfleiderer S., Pon aviC M., Pramuka S., Prazeres C., Rauch U., Radusinovic S., Reimann C., Salpeteur I., Sadeghi M., Scanlon R., Schedl A., Schoeters I., SefCik P., Sellersjo E., Skopljak F., Slaninka I., Sor Sa A., Srvkota R., Stafilov T., Tarvainen T., Trendavilov V., Valera P., Verougstraete V., Vidojevic D., Zomeni Z., Scheib, A. J., Birke, M., Dinelli, E, Albanese, Stefano, Andersson, M., Baritz, R., Batista, M. J., BEL LAN, A., Cicchella, D., Demetriades, A., DE VIVO, Benedetto, DE VOS, W., Duris, M., DUSZA DOBEK, A., Eggen, O. A., Eklund, M., Ernstsen, V., Filzmoser, P., Flight, D. M. A., Forrester, S., Fuchs, M., Fugedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., DE GROOT, W., Gulan, A., Halamic, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Kivisilla, J., Klos, V., Krone, F., Kwecko, P., Kuti, L., Ladenberger, A., Lima, Annamaria, Locutura, J., Lucivjansky, P., Mann, A., Mackovych, D., Maclughlin, M., Malyuk, B. I., Maquil, R., Meuli, R. G., Mol, G., Négrel, P., O’Connor, P., Oorts, K., Rottesen, R. T., Pasieczna, A., Petersell, V., Pfleiderer, S., Poňavič, M., Pramuka, S., Prazeres, C., Rauch, U., Radusinovic, C., Reimann, C., Salpeteur, I., Sadeghi, M., Scanlon, A., Schedl, A., Schoeters, I., Sefcik, P., Sellersjö, E., Skopljak, F., Slaninka, I., Šorša, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojevic, D., and Zomeni, Z.

Subjects
aeolian deposit, genetic structures, soil
Abstract

Hafnium (Hf) and zirconium (Zr) concentrations measured in over 4100 agricultural soil samples from Europe were assessed with the focus on their relationship to the distribution of aeolian deposits, such as loess and coversands. Comparison of extractable (aqua regia; ICP-MS) and total (XRFS) concentrations shows that only 1.0 to 1.7% of the total Hf and Zr is chemically extractable because of the resistant nature of their host minerals. Resistate minerals, such as zircon, are commonly found in the predominantly silty fraction of loess deposits. In this study a statistical analysis of total Hf and Zr soil data from areas with and without loess was carried out to derive threshold values of 10 mg kg−1 (Hf) and 318 mg kg−1 (Zr). These values were subsequently applied across the project area in an attempt to indicate the presence of aeolian deposits. The spatial distribution of abovethreshold concentrations suggests a more extensive and coherent loess belt across central and eastern Europe, providing additional evidence of loess across Brittany, Aquitaine and near the Vosges mountains in France as well as in the basins of central and northern Spain. Above-threshold concentrations were also detected in loess regardless of its thickness, emphasising the importance of the abundance of zircon in the upper part of the soil profile rather than the actual thickness of the deposit. Soil data however, failed to indicate various loess facies within most of the Pannonian Basin, suggesting that this approach only works where deposits contain a sufficient amount of zircon. This may also explain why the extensive coversands across northern Germany and Poland were largely undetected. This study demonstrates that continental-scale soil geochemical data can help identify and map the distribution of zircon-rich loess and coversand, and subsequently enhance and improve current knowledge of the extent of these deposits.

Published
2014
Full Text
View/download PDF

11. GEMAS: Geochemical distribution of Mg in agricultural soil of Europe

Author

M. Fuchs, P. Kwecko, P. Hayoz, Jörg Matschullat, B. I. Malyuk, Anna Ladenberger, B. De Vivo, Stjepan Husnjak, Rainer Baritz, V. Verougstraete, S. Pfleiderer, E. Haslinger, P. O'Connor, V. Gregorauskiene, Andreas M. Zissimos, L. Janik, Philippe Négrel, M. Eklund, V. Ernstsen, Alecos Demetriades, V. Trendavilov, A. Dusza-Dobek, Jurian Hoogewerff, Clemens Reimann, Martiya Sadeghi, W. De Groot, G. Mol, R. Maquil, E. Sellersjö, A. Bel-lan, Enrico Dinelli, Belinda Flem, M. Kaminari, W. Petersell, Andreas Scheib, Annamaria Lima, Anna Pasieczna, R. Hoffmann, M. Andersson, Paolo Valera, R. Scanlon, V. Klos, I. Slaninka, M. Duris, S. Forrester, S. Pramuka, D. Mackovych, S. Radusinović, U. Fugedi, C. Prazeres, A. Gulan, W. De Vos, A. Mann, Ajka Šorša, Jason K. Kirby, F. Krone, Z. Zomeni, J. Kivisilla, G. Jordan, Manfred Birke, L. Kuti, Rolf Tore Ottesen, Dee Flight, H. Hrvatovic, R. Srvkota, P. Sefcik, I. Salpeteur, Josip Halamić, Peter Filzmoser, D. P. Lucivjansky, Trajče Stafilov, F. Skopljak, M. Ponavic, Mateja Gosar, Stefano Albanese, R. G. Meuli, D. Vidojević, Maria João Batista, R. K. Oorts, A. Schedl, Domenico Cicchella, Timo Tarvainen, J. Locutura, A. Gilucis, I. Schoeters, U. Rauch, Mike J. McLaughlin, Bureau de Recherches Géologiques et Minières (BRGM) (BRGM), Geological Survey of Norway (NGU), Bundesanstalt für Geowissenschaften und Rohstoffe (BGR), Negrel, P., Ladenberger, A., Reimann, C., Birke, M., Demetriades, A., Sadeghi, M., Albanese, S., Andersson, M., Baritz, R., Batista, M. J., Bel-lan, A., Cicchella, D., De Vivo, B., De Vos, W., Dinelli, E., Duris, M., Dusza-Dobek, A., Eklund, M., Ernstsen, V., Filzmoser, P., Flem, B., Flight, D. M. A., Forrester, S., Fuchs, M., Fugedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., De Groot, W., Gulan, A., Halamic, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Kivisilla, J., Klos, V., Krone, F., Kwecko, P., Kuti, L., Lima, A., Locutura, J., Lucivjansky, D. P., Mann, A., Mackovych, D., Matschullat, J., Mclaughlin, M., Malyuk, B. I., Maquil, R., Meuli, R. G., Mol, G., O'Connor, P., Oorts, R. K., Ottesen, R. T., Pasieczna, A., Petersell, W., Pfleiderer, S., Ponavic, M., Pramuka, S., Prazeres, C., Rauch, U., Radusinovic, S., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A. J., Schoeters, I., Sefcik, P., Sellersjo, E., Skopljak, F., Slaninka, I., Sorsa, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojevic, D., Zissimos, A., Zomeni, Z., Negrel P., Ladenberger A., Reimann C., Birke M., Demetriades A., Sadeghi M., Albanese S., Andersson M., Baritz R., Batista M.J., Bel-lan A., Cicchella D., De Vivo B., De Vos W., Dinelli E., Duris M., Dusza-Dobek A., Eklund M., Ernstsen V., Filzmoser P., Flem B., Flight D.M.A., Forrester S., Fuchs M., Fugedi U., Gilucis A., Gosar M., Gregorauskiene V., De Groot W., Gulan A., Halamic J., Haslinger E., Hayoz P., Hoffmann R., Hoogewerff J., Hrvatovic H., Husnjak S., Janik L., Jordan G., Kaminari M., Kirby J., Kivisilla J., Klos V., Krone F., Kwecko P., Kuti L., Lima A., Locutura J., Lucivjansky D.P., Mann A., Mackovych D., Matschullat J., McLaughlin M., Malyuk B.I., Maquil R., Meuli R.G., Mol G., O'Connor P., Oorts R.K., Ottesen R.T., Pasieczna A., Petersell W., Pfleiderer S., Ponavic M., Pramuka S., Prazeres C., Rauch U., Radusinovic S., Salpeteur I., Scanlon R., Schedl A., Scheib A.J., Schoeters I., Sefcik P., Sellersjo E., Skopljak F., Slaninka I., Sorsa A., Srvkota R., Stafilov T., Tarvainen T., Trendavilov V., Valera P., Verougstraete V., Vidojevic D., Zissimos A., and Zomeni Z.

Subjects
Mediterranean climate, Lithology, Earth science, Weathering, Parent materials, Mineralogy, Total concentration, Partial extraction, 010501 environmental sciences, 010502 geochemistry & geophysics, 01 natural sciences, chemistry.chemical_compound, Geochemistry and Petrology, Aqua regia, 0105 earth and related environmental sciences, 2. Zero hunger, geography, geography.geographical_feature_category, Land use, Bedrock, 15. Life on land, Karst, Soil quality, Parent material, chemistry, [SDU]Sciences of the Universe [physics], Environmental science, Economic Geology
Abstract

Agricultural soil (Ap-horizon, 0–20 cm) samples were collected from 33 European countries as part of the GEMAS (GEochemical Mapping of Agricultural and grazing land Soil) soil-mapping project. The Mg data derived from total concentrations (XRF) and two acid digestion methods, aqua regia (AR) and Mobile Metal Ion (MMI®), were used to provide an overview of its spatial distribution in soil at the continental-scale. Magnesium is one of the most abundant elements in the Earth's crust and essential nutrient for plants and animals and its presence in soil is, therefore, important for soil quality evaluation. In this study, the geochemical behaviour of Mg in European agricultural soil was investigated in relation to a variety of soil parent materials, climatic zones, and landscapes. The chemical composition of soil reflects mostly the primary mineralogy of the source bedrock, and the superimposed effects of pre- and post-depositional chemical weathering, controlled by element mobility and formation of secondary phases such as clays. Low Mg concentrations in agricultural soil occur in regions with quartz-rich glacial sediments (Poland, Baltic States, N. Germany), and in soil developed on quartz-rich sandstone parent materials (e.g., central Sweden). High Mg concentrations occur in soil developed over mafic lithologies such as ophiolite belts and in carbonate-rich regions, including karst areas. The maximum extent of the last glaciation is well defined by a Mg concentration break, which is marked by low Mg concentrations in Fennoscandia and north-central Europe, and high Mg concentrations in Mediterranean region. Lithology of parent materials seems to play a key role in the Mg nutritional status of agricultural soil at the European scale. Influence from agricultural practice and use of fertilisers appears to be subordinate. Comparison of the continental-scale spatial distribution of Mg in agricultural soil by using the results from three analytical methods (XRF, AR and MMI®) provides complementary information about Mg mobility and its residence time in soil. Thus, allowing evaluation of soil weathering grade and impact of land use exploitation.

Published
2021
Full Text
View/download PDF

12. GEMAS: Source, distribution patterns and geochemical behaviour of Ge in agricultural and grazing land soils at European continental scale

Author

Négrel, Philippe, Ladenberger, Anna, Reimann, Clemens, Birke, Manfred, Sadeghi, Martiya, The GEMAS Project Team: S. Albanese, M. Andersson, R. Baritz, M. J. Batista, A. Bel lan, D. Cicchella, A. Demetriades, B. De Vivo, W. De Vos, M. Duris, A. Dusza Dobek, O. A. Eggen, M. Eklund, V. Ernstsen, P. Filzmoser, D. M. A. Flight, S. Forrester, M. Fuchs, U. Fügedi, A. Gilucis, M. Gosar, V. Gregorauskiene, W. De Groot, A. Gulan, J. Halamic, E. Haslinger, P. Hayoz, R. Hoffmann, J. Hoogewerff, H. Hrvatovic, S. Husnjak, L. Janik, G. Jordan, M. Kaminari, J. Kirby, J. Kivisilla, V. Klos, F. Krone, P. Kwecko, L. Kuti, A. Lima, J. Locutura, D. P. Lucivjansky, A. Mann, D. Mackovych, M. McLaughlin, B. I. Malyuk, R. Maquil, R. G. Meuli, G. Mol, P. O'Connor, R. K. Oorts, R. T. Ottesen, A. Pasieczna, W. Petersell, S. Pfleiderer, M. Ponavic, S. Pramuka, C. Prazeres, U. Rauch, S. Radusinovic, I. Salpeteur, R. Scanlon, A. Schedl, A. J. Scheib, I. Schoeters, P. Sefcik, E. Sellersjo, F. Skopljak, I. Slaninka, A. Sorsa, R. Srvkota, T. Stafilov, T. Tarvainen, V. Trendavilov, P. Valera, V. Verougstraete, D. Vidojevic, A. Zissimos, Z. Zomeni, DINELLI, ENRICO, Negrel, P., Ladenberger, A., Reimann, C., Birke, M., Sadeghi, M., Albanese, Stefano, Andersson, M., Baritz, R., Batista, M. J., BEL LAN, A., Cicchella, D., Demetriades, A., DE VIVO, Benedetto, DE VOS, W., Dinelli, E., Duris, M., DUSZA DOBEK, A., Eggen, O. A., Eklund, M., Ernstsen, V., Filzmoser, P., Flight, D. M. A., Forrester, S., Fuchs, Fügedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., DE GROOT, W., Gulan, A., Halamic, J., Haslinger, E., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Kivisilla, J., Klos, V., Krone, F., Kwecko, P., Kuti, L., Lima, Annamaria, Locutura, J., Lucivjansky, D. P., Mann, A., Mackovych, D., Mclaughlin, M., Malyuk, B. I., Maquil, R., Meuli, R. G., Mol, G., O'Connor, P., Oorts, R. K., Ottesen, R. T., Pasieczna, A., Petersell, W., Pfleiderer, S., Ponavic, M., Pramuka, S., Prazeres, C., Rauch, U., Radusinovic, S., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A. J., Schoeters, I., Sefcik, P., Sellersjo, E., Skopljak, F., Slaninka, I., Sorsa, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojevic, D., Zissimos, A., Zomeni, Z., Bureau de Recherches Géologiques et Minières (BRGM) (BRGM), Geological Survey of Sweden, sgu, Geological Survey of Norway (NGU), Geological Survey of Norway, Federal Institute for Geosciences and Natural Resources (BGR), Négrel, Philippe, Ladenberger, Anna, Reimann, Clemen, Birke, Manfred, Sadeghi, Martiya, The GEMAS Project Team: S. Albanese, M. Andersson, R. Baritz, M.J. Batista, A. Bel-lan, D. Cicchella, A. Demetriade, B. De Vivo, W. De Vo, Dinelli Enrico, M. Duri, A. Dusza-Dobek, O.A. Eggen, M. Eklund, V. Ernstsen, P. Filzmoser, D.M.A. Flight, S. Forrester, M. Fuch, U. Fügedi, A. Giluci, M. Gosar, V. Gregorauskiene, W. De Groot, A. Gulan, J. Halamic, E. Haslinger, P. Hayoz, R. Hoffmann, J. Hoogewerff, H. Hrvatovic, S. Husnjak, L. Janik, G. Jordan, M. Kaminari, J. Kirby, J. Kivisilla, V. Klo, F. Krone, P. Kwecko, L. Kuti, A. Lima, J. Locutura, D. P. Lucivjansky, A. Mann, D. Mackovych, M. McLaughlin, B.I. Malyuk, R. Maquil, R.G. Meuli, G. Mol, P. O'Connor, R. K. Oort, R.T. Ottesen, A. Pasieczna, W. Petersell, S. Pfleiderer, M. Ponavic, S. Pramuka, C. Prazere, U. Rauch, S. Radusinovic, I. Salpeteur, R. Scanlon, A. Schedl, A.J. Scheib, I. Schoeter, P. Sefcik, E Sellersjo, F. Skopljak, I. Slaninka, A. Sorsa, R. Srvkota, T. Stafilov, T. Tarvainen, V. Trendavilov, P. Valera, V. Verougstraete, D. Vidojevic, A. Zissimo, and Z. Zomeni

Subjects
Regosol, Soil production function, Weathering, Soil science, 010501 environmental sciences, 010502 geochemistry & geophysics, Agricultural soil, 01 natural sciences, Soil survey, Soil series, Geochemistry and Petrology, [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry, Environmental Chemistry, 0105 earth and related environmental sciences, Soil map, Germanium, Geochemistry, Pedalfer, 15. Life on land, Pollution, Chemistry, Pedogenesis, Agriculture and Soil Science, 13. Climate action, Soil water, Earth Sciences, Geology
Abstract

International audience; Agricultural soil (Ap-horizon, 0–20 cm) and grazing land soil (Gr-horizon, 0–10 cm) samples were collected from a large part of Europe (33 countries, 5.6 million km2) as part of the GEMAS (GEochemical Mapping of Agricultural and grazing land Soil) soil mapping project. GEMAS soil data have been used to provide a general view of element mobility and source rocks at the continental scale, either by reference to average crustal abundances or to normalized patterns of element mobility during weathering processes. The survey area includes a diverse group of soil parent materials with varying geological history, a wide range of climate zones, and landscapes.The concentrations of Ge in European soil were determined by ICP-MS after an aqua extraction, and their spatial distribution patterns generated by means of a GIS software.The median values of Ge and its spatial distribution in Ap and Gr soils are almost the same (0.037 vs. 0.034 mg/kg, respectively). The majority of Ge anomalies is related to the type of soil parent material, namely lithology of the bedrock and minor influence of soil parameters such as pH, TOC and clay content. Metallogenic belts with sulphide mineralisation provide the primary source of Ge in soil in several regions in Europe, e.g. in Scandinavia, Germany, France, Spain and Balkan countries.Comparison with total Ge concentrations obtained from the Baltic Soil Survey shows that aqua regia is a very selective method with rather low-efficiency and cannot provide a complete explanation for Ge geochemical behaviour in soil. Additionally, large differences in Ge distribution are to be expected when different soil depth horizons are analysed.

Published
2016
Full Text
View/download PDF

13. GEMAS: Spatial distribution of the pH of European agricultural and grazing land soils

Author

Fabian C., Reimann C., Fabian K., Birke M., Baritz R., Haslinger E., Albanese S., Andersson M., Batista M. J., Bel lan A., Cicchella D., Demetriades A., De Vivo B., De Vos W., Duriš M., Dusza Dobek A., Eggen O. A., Eklund M., Ernstsen V., Filzmoser P., Flight D. M. A., Forrester S., Fuchs M., Fügedi U., Gilucis A., Gosar M., Gregorauskiene V., De Groot W., Gulan A., Halamić J., Hayoz P., Hoffmann R., Hoogewerff J., Hrvatovic H., Husnjak S., Janik L., Jordan G., Kaminari M., Kirby J., Kivisilla J., Klos V., Krone F., Kwećko P., Kuti L., Ladenberger A., Lima A., Locutura J., Lucivjansky D. P., Mann A., Mackovych D., McLaughlin M., Malyuk B. I., Maquil R., Meuli R. G., Mol G., Negrel P., O'Connor P., Oorts R. K., Ottesen R. T., Pasieczna A., Petersel, W., Pfleiderer S., Poňavič M., Pramuka S., Prazeres C., Rauch U., Radusinović S., Salpeteur I., Scanlon R., Schedl A., Scheib A. J., Schoeters I., Šefčik P., Sellersjö E., Skopljak F., Slaninka I., Šorša A., Srvkota R., Stafilov T., Tarvainen T., Trendavilov V., Valera P., Verougstraete V., Vidojević D., Zissimos A., Zomeni Z., DINELLI, ENRICO, Fabian C., Reimann C., Fabian K., Birke M., Baritz R., Haslinger E., Albanese S., Andersson M., Batista M.J., Bel-lan A., Cicchella D., Demetriades A., De Vivo B., De Vos W., Dinelli E., Duriš M., Dusza-Dobek A., Eggen O.A., Eklund M., Ernstsen V., Filzmoser P., Flight D.M.A., Forrester S., Fuchs M., Fügedi U., Gilucis A., Gosar M., Gregorauskiene V., De Groot W., Gulan A., Halamić J., Hayoz P., Hoffmann R., Hoogewerff J., Hrvatovic H., Husnjak S., Janik L., Jordan G., Kaminari M., Kirby J., Kivisilla J., Klos V., Krone F., Kwećko P., Kuti L., Ladenberger A., Lima A., Locutura J., Lucivjansky D.P., Mann A., Mackovych D., McLaughlin M., Malyuk B.I., Maquil R., Meuli R.G., Mol G., Negrel P., O'Connor P., Oorts R.K., Ottesen R.T., Pasieczna A., Petersel, W., Pfleiderer S., Poňavič M., Pramuka S., Prazeres C., Rauch U., Radusinović S., Salpeteur I., Scanlon R., Schedl A., Scheib A.J., Schoeters I., Šefčik P., Sellersjö E., Skopljak F., Slaninka I., Šorša A., Srvkota R., Stafilov T., Tarvainen T., Trendavilov V., Valera P., Verougstraete V., Vidojević D., Zissimos A., Zomeni Z., Fabian, C., Reimann, C., Fabian, K., Birke, M., Baritz, R., Haslinger, E., Albanese, Stefano, Andersson, M., Batista, M. J., BEL LAN, A., Cicchella, D., Demetriades, D., DE VIVO, Benedetto, DE VOS, W., Dinelli, E., Duriš, M., DUSZA DOBEK, A., Eggen, O. A., Eklund, M., Ernstsen, V., Filzmoser, P., Flight, D. M. A., Forrester, S., Fuchs, M., Fugedi, U., Gilucis, A., Gosar, M., Gregorauskiene, V., DE GROOT, W., Gulan, A., Halamic, J., Hayoz, P., Hoffmann, R., Hoogewerff, J., Hrvatovic, H., Husnjak, S., Janik, L., Jordan, G., Kaminari, M., Kirby, J., Kivisilla, J., Klos, V., Krone, F., Kwecko, P., Kuti, L., Ladenberger, A., Lima, Annamaria, Locutura, J., Lucivjansky, D. P., Mann, A., Mackovych, D., Mclaughlin, M., Malyuk, B. I., Maquil, R., Meuli, R. G., Mol, G., Negrel, P., O’Connor, P., Oorts, R. K., Ottesen, R. T., Pasieczna, A., Petersell, W., Pfleiderer, S., Ponavic, M., Pramuka, S., Prazeres, C., Rauch, U., Radusinovic, S., Salpeteur, I., Scanlon, R., Schedl, A., Scheib, A. J., Schoeters, I., Šefcik, P., Sellersjo, E., Skopljak, F., Slaninka, I., Šorša, A., Srvkota, R., Stafilov, T., Tarvainen, T., Trendavilov, V., Valera, P., Verougstraete, V., Vidojevic, D., Zissimos, A., and Zomeni, Z.

Subjects
Hydrology, Soil test, Spatial distribution, Pollution, Agricultural soil, Grazing soil, GEMAS, chemistry.chemical_compound, soil pH, GEochemical Mapping, chemistry, Geochemistry and Petrology, Soil pH, Soil water, Grazing, Environmental Chemistry, Carbonate, Environmental science, Precipitation, Glacial period, grazing land soil, pH value, Grazing land soil, geochemistry
Abstract

During 2008 the GEochemical Mapping of Agricultural Soils (GEMAS) project collected 2108 agricultural (ploughed soil, Ap horizon, 0–20 cm) and 2023 grazing land soil samples (Gr, 0–10 cm) evenly spread over 33 European countries and covering an area of 5.6 million km2. The pH of all samples was determined by one single laboratory applying a 0.01 M CaCl2 extraction, and following a strict quality-control procedure. The resulting pH-value distributions for European Ap and Gr soil are both bimodal. Broad acidic modes, with pH between 4 and 6, and sharp alkaline modes, with pH between 7 and 8 due to the Ca2+ buffer system, are clearly separated. The European median pH is 5.8 for the GEMAS Ap soil samples and 5.5 for the GEMAS Gr soil samples. According to the pH distribution maps, Europe is separated into two main zones: northern Europe with generally lower pH values (Ap: 5.2, Gr: 4.8), dominated by acidic soils occurring in Fennoscandia, and southern Europe with higher pH values (Ap: 6.3, Gr: 5.9), dominated by carbonate rich soils. The separation line coincides with the southern border of the sediments of the last glaciation. The dominant factors controlling pH at the European scale are thus geology (crystalline bedrock) in combination with climate (temperature and precipitation). The GEMAS pH maps mainly reflect the natural site conditions on the European scale, whilst anthropogenic impact is hardly detectable. The GEMAS results provide a unique set of homogenous and spatially representative soil pH data for the continent. The data set defines a dependable continental-scale background, and offers the possibility to calibrate studies on more detailed scales.

Published
2014

Catalog

Books, media, physical & digital resources
See catalog results