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ZnO--TiO2 thin films containing 0.5 mol%, 1.0 mol%, and 5.0 mol% ZnO were synthesized by oxidative solidphase pyrolysis. The materials contained anatase and rutile phases with particle size of 6-13 nm, as confirmed using X-ray phase analysis and scanning electron microscopy. When a certain number of ZnO crystallites appeared in the TiO2 film structure in the temperature range of room temperature to 220 °C, a two-level response of the film resistance was observed, differing by approximately 10%, as obtained by electrophysical measurements. The two-level response correlates with the formation of two donor energy levels of 0.28 and 0.33 eV in the band structure of the ZnO--TiO2 films. The donor level with a higher activation energy corresponded to the Ti vacancy (V-Ti), and that with a lower activation energy corresponded to the Zn vacancy (V-Zn). Two levels of gas-sensitive properties were noted for 0.5ZnO--TiO2, 1ZnO--TiO2, and 5ZnO--TiO2 under the influence of 50 ppm NO2 at 250 °C. Such two-level responses can be ascribed to the pinning of the Fermi level on ZnO and TiO2 nanocrystallites. The mechanism of the beak-shaped and two-level responses of sensors based on composite nanomaterials when exposed to various gases was elucidated. [ABSTRACT FROM AUTHOR]

Thin nanocomposite films based on tin dioxide with a low content of zinc oxide (0.5–5 mol.%) were obtained by the sol–gel method. The synthesized films are 300–600 nm thick and contains pore sizes of 19–29 nm. The resulting ZnO–SnO2 films were comprehensively studied by atomic force and Kelvin probe force microscopy, X-ray diffraction, scanning electron microscopy, and high-resolution X-ray photoelectron spectroscopy spectra. The photoconductivity parameters on exposure to light with a wavelength of 470 nm were also studied. The study of the photosensitivity kinetics of ZnO–SnO2 films showed that the film with the Zn:Sn ratio equal to 0.5:99.5 has the minimum value of the charge carrier generation time constant. Measurements of the activation energy of the conductivity, potential barrier, and surface potential of ZnO–SnO2 films showed that these parameters have maxima at ZnO concentrations of 0.5 mol.% and 1 mol.%. Films with 1 mol.% ZnO exhibit high response values when exposed to 5–50 ppm of nitrogen dioxide at operating temperatures of 2 0 0 ∘ C and 2 5 0 ∘ C. [ABSTRACT FROM AUTHOR]

High-resolution two-phase flow data in the rod bundle are important in the development and validation of high-fidelity models for computational fluid dynamics and subchannel codes, in particular, those pertaining to light water reactor cooling systems. The Michigan Adiabatic Rod Bundle Flow Experiment (MARBLE) has been constructed as a modular assembly of an 8 × 8 lattice rod bundle to simulate scaled pressurized water reactor and boiling water reactor subchannel assemblies. To establish a high-spatial resolution database of the void fraction in the reactor fuel assembly geometries, tomographic measurements were performed with the High-Resolution Gamma-ray Tomography System, which was designed and built in house; the detector system has a spatial resolution of less than 1.0 mm using 240 LYSO (Lu1.8Y0.2SiO5) scintillators with a fan-beam array. In the present study, the local void fraction was measured with the MARBLE facility under various air-water flow conditions (jg = 0.04 to 0.85 m/s and jl = 0.12 to 0.77 m/s) covering from bubbly to cap-turbulent flows. The local void fraction was also successfully measured under nonuniform and asymmetric air bubble distribution conditions with an investigation of the effect of spacer grids and mixing vanes on void drift across subchannels. [ABSTRACT FROM AUTHOR]

Measuring the flow rate in High-Temperature Gas-cooled Reactors is a challenge for traditional flowmeters due to the high flow rate (10 to 15 m/s at nominal operating conditions), high operating temperatures (>700°C), and high neutron flux and gamma fields in the reactor core. This paper discusses developing a novel flowmeter that can work under these extreme conditions. Oak Ridge National Laboratory first proposed using acoustics to measure the flow in the reactor, more specifically, using a Kelvin-Helmholtz resonator to correlate the gas flow rate with vibration frequency. With the primary goal of developing an acoustic measurement technique, we propose an acoustic corrugated pipe as a candidate for the development of a novel gas flowmeter. Experimental investigations on corrugated pipes have confirmed the dependence of the whistling frequency on the gas flow rate. Also, a tube-in-tube configuration is proposed for the flowmeter prototype, which can help mitigate resonance between the system and the flowmeter. Experimental investigation using the prototype has shown good independence from the piping system. Furthermore, Unsteady Reynolds-Averaged Navier-Stokes (URANS) simulations have been performed and validated with a satisfactory agreement, providing confidence that URANS models can adequately predict the characteristic curve (flow rate versus frequency) of the corrugated pipe and can therefore be used to optimize the flowmeter designs cost-effectively. [ABSTRACT FROM AUTHOR]

Heat pipe microreactors are reactor designs that primarily use liquid-metal heat pipes to cool the core. The main interest in heat pipes is the fact that they can remove heat passively. This, along with the use of liquid metal, allows the reactor to operate at higher temperatures. Although the use of heat pipes in nuclear reactors is new, liquid-metal heat pipe technology is mature. Nevertheless, experimental data on heat pipes are scarce, and very little is known about their behavior during abnormal operations and close to their thermal limits. Therefore, new experiments and accurate heat pipe simulations are needed to develop reliable closure models. This work describes a joint experimental and numerical investigation into heat pipes that attempts an initial closure of this gap. The numerical and experimental efforts are currently proceeding in parallel, aimed at different aspects of heat pipes. The numerical part is focused on gaps in local closures, and the experiments capture the overall heat pipe behavior. [ABSTRACT FROM AUTHOR]

Air ingress measurements using the 1/20th-scaled Helium Air Ingress gas Reactor Experiment (HAIRE) facility show key geometric variables of interest and their effect on air ingress in small- and medium-sized breaks in High Temperature Gas cooled Reactors. These variables include but are not limited to break diameter, break angle, and break wall thickness. Differing wall thicknesses for the same break diameter can have order-of-magnitude changes to the air ingress rate, which is a key figure of merit in the air ingress accident scenario. Additionally, different break sizes can change the importance of the angle in the break scenario. With smaller breaks, the flow will not transition from intermittent flow, to countercurrent flow, to diffusive flow as the break rotates from vertically upward toward vertically downward. This would lead to less variability with smaller breaks, which in turn would make the accident scenario more predictable for smaller-sized breaks. [ABSTRACT FROM AUTHOR]

Radiation transmission measurement methods have become widely implemented in the study of two-phase flow due to leaping advancements in detector efficiency, spatial resolution, and high-speed measurement capabilities. However, radiation-based measurements of boiling experiments bear several challenges due to the mismatch of calibration to experimental conditions, beam hardening, thermal expansion, and material and working fluid density changes with temperature. The present research focuses on developing methods to analyze the high-resolution X-ray radiography measurements of the post-critical heat flux (Post-CHF) heat transfer facility built at the University of Michigan that is intended to perform high-pressure and high-temperature measurements; the experimental test section is made of Incoloy-800H and is characterized as a cylindrical geometry expanding 1.0 m in length. The broad goal of the experiment is to build a high-resolution database to develop models for inverted annular film boiling and inverted slug film boiling through dispersed flow film boiling. The methods developed in this research model the thermal effects of the postulated challenges in order to properly scale the X-ray calibration measurements to the experimental conditions. Additionally, a cross-section-weighted method is developed to estimate the axial void fraction; this method is validated by modeling the test section with synthetic void fraction data. Last, preliminary high-speed X-ray measurements performed at subcooled boiling conditions are presented and analyzed with the developed methods, which include bubbly, slug, and churn flows. [ABSTRACT FROM AUTHOR]

Thin nanocrystalline transparent Al-doped ZnO (1–10 at.% Al) films were synthesized by solid-phase pyrolysis at 700 °C. Synthesized Al-doped ZnO films were investigated by X-ray diffraction (XRD), scanning and transmission electron microscopy (SEM, TEM). All obtained materials were crystallized into the wurtzite structure, which was confirmed by XRD. The material crystallinity decreases with the introduction of aluminum. SEM and TEM showed that the films are continuous and have a uniform distribution of nanoparticles with an average size of 15–20 nm. TEM confirmed the production of Al-doped ZnO films. The transmittance of Al-doped ZnO films in the range of 400–1000 nm is more than 94%. The introduction of 1% Al into ZnO leads to a narrowing of the band gap compared to ZnO to a minimum value of 3.26 eV and a sharp decrease in the response time to the radiation exposure with a wavelength of 400 nm. An increase in aluminum concentration leads to a slight increase in the band gap, which is associated with the Burstein–Moss effect. The minimum response time (8 s) was shown for film containing 10% Al, which is explained by the shortest average lifetime of charge carriers (4 s). [ABSTRACT FROM AUTHOR]

The work is aimed at the investigation of the influence of nonlinear active ions concentration profiles in Yb:YAG laser elements on temperature distribution and wavefront distortions during amplification using sub-kilowatt level diode pumping. A mathematical model is presented for the theoretical study of the amplification process in crystals with cubic crystal system. A detailed comparison of Yb:YAG active elements with the same thickness and absorbed pumping power, but with various concentration profiles of Yb3+, ions is carried out. It is shown that the use of active elements with an increasing dopant concentration in the pump beam direction allows one to optimize the temperature profile inside the active element and, thus, reduce the thermal-induced wavefront distortions of the amplified radiation. Modeling is carried out for the experimentally grown crystal with linear concentration gradient profile. It is shown that the linear doping profile with a gradient of 0.65 at.%/mm allows increasing the small-signal gain up to 10% and decreasing the thermal-induced wavefront distortions by ~15%. [ABSTRACT FROM AUTHOR]

Thin nanocomposite films based on zinc oxide (ZnO) added with cobalt oxide (Co3O4) were synthesized by solid-phase pyrolysis. According to XRD, the films consist of a ZnO wurtzite phase and a cubic structure of Co3O4 spinel. The crystallite sizes in the films increased from 18 nm to 24 nm with growing annealing temperature and Co3O4 concentration. Optical and X-ray photoelectron spectroscopy data revealed that enhancing the Co3O4 concentration leads to a change in the optical absorption spectrum and the appearance of allowed transitions in the material. Electrophysical measurements showed that Co3O4-ZnO films have a resistivity up to 3 × 104 Ohm∙cm and a semiconductor conductivity close to intrinsic. With advancing the Co3O4 concentration, the mobility of the charge carriers was found to increase by almost four times. The photosensors based on the 10Co-90Zn film exhibited a maximum normalized photoresponse when exposed to radiation with wavelengths of 400 nm and 660 nm. It was found that the same film has a minimum response time of ca. 26.2 ms upon exposure to radiation of 660 nm wavelength. The photosensors based on the 3Co-97Zn film have a minimum response time of ca. 58.3 ms versus the radiation of 400 nm wavelength. Thus, the Co3O4 content was found to be an effective impurity to tune the photosensitivity of radiation sensors based on Co3O4-ZnO films in the wavelength range of 400–660 nm. [ABSTRACT FROM AUTHOR]

Abstract Turbulent mixing of coolant streams can result in an oscillatory mixing phenomenon called thermal striping. These fluctuations have the potential to lead to anticipated thermal fatigue failures in advanced nuclear reactors. To predict thermal striping, robust and computationally affordable modeling tools that are capable of accurately representing complex turbulence are needed. Hybrid turbulence approaches, such as detached-eddy simulation and scale-adaptive simulation, have shown some success in resolving complex unsteady turbulence for massively separated flows, however the applicability of these models to internal flows is limited.A STRUCTure-based (STRUCT) second-generation Unsteady Reynolds-Averaged Navier–Stokes turbulence model was recently proposed at the Massachusetts Institute of Technology to robustly extend the applicability of hybrid closures. In this work, the STRUCT model is evaluated using experimental data taken at the Reactor Cavity Cooling System separate-effects test facility at the University of Michigan. The experiments observed the interaction of parallel symmetric rectangular jets, and include measurements for mean profiles of velocity and Reynolds stresses. In the present work, the simulation results are assessed against mean profiles of velocity and Reynolds stresses, demonstrating the ability to reproduce the unsteadiness of the jets in close agreement with the measurements at considerably reduced computational cost. [ABSTRACT FROM AUTHOR]

The widespread use of polymer composite materials (PCM) leads to an increase in non-recyclable waste. This paper discusses the feasibility of recycling fiberglass with an epoxy matrix by solvolysis in ethanol under supercritical conditions. The solvolysis process completes successfully within four hours in an environment of a pure solvent containing 10% water at a temperature of 280 °C when the solvent passes into the supercritical state. The treatment time increases up to 10 h at a process temperature of 250 °C. When using a coordination compound of copper(II) chloride with organic chloride salt having 2,3,5-triphenyltetrazolium as the counterion, having the composition of (2,3,5-triphenyltetrazolium)2[CuCl4], the treatment time is reduced. The addition of the complex of 5% by weight makes it possible to completely remove the epoxy matrix at a temperature of 250 °C for two hours. The products separated from the solvolysis liquid were studied by infrared spectroscopy. The resulting fibers were examined by thermogravimetric analysis and scanning electron microscopy. The residual strength of the recovered fibers is 98%. Thus, the resulting fibers can be reused in the composite industry. Including both for the production of decorative products and for the production of structural products made of polymer composite materials. [ABSTRACT FROM AUTHOR]

Arrays of zinc oxide (ZnO) nanorods were synthesized over quartz substrates by the hydrothermal method. These nanorods were grown in a predominantly vertical orientation with lengths of 500–800 nm and an average cross-sectional size of 40–80 nm. Gold, with average sizes of 9 ± 1 nm and 4 ± 0.5 nm, and tin nanoclusters, with average sizes of 30 ± 5 nm and 15 ± 3 nm, were formed on top of the ZnO nanorods. Annealing was carried out at 300 °C for 2 h to form ZnO/SnO2 and ZnO/Au nanorods. The resulting nanorod-arrayed films were comprehensively studied using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectrometry (EDS) and X-ray photoelectron spectroscopy (XPS). To fabricate resistive sensor elements, the films were supplied with V/Ni contact metallization on top of the nanorods. The gas sensor performance of the prepared films was evaluated at various temperatures in order to select 200 °C as the optimum one which enabled a selective detection of NO2. Adding UV-viz irradiation via a light-emitting diode, λ = 400 nm, allowed us to reduce the working temperature to 50 °C and to advance the detection limit of NO2 to 0.5 ppm. The minimum response time of the samples was 92 s, which is 9 times faster than in studies without exposure to UV-viz radiation. [ABSTRACT FROM AUTHOR]

Currently, laser systems based on active elements doped with Yb3+ with simultaneously high pulse repetition rates and high peak power are in demand for many applications. High thermal load of active elements is the primary limiting factor for average power scaling. Experimental investigation of temperature distribution in active elements is of particular importance for estimation of cooling efficiency and for thermal processes' monitoring. In the present work, the method of dynamic laser thermometry is proposed for temperature distribution investigation within cryogenically cooled Yb3+-doped active elements. The method is based on the dependence of the Yb3+ ion absorption cross-section on temperature at a wavelength of 1030 nm. The method was tested to study the 2D temperature map of the Yb:YAG active element of the high-power, diode-pumped, cryogenically cooled laser amplifier. The best measurement accuracy ±3 K is achieved at the maximal temperature 176 K. The results of numerical simulation are in good agreement with the experimental data. On the basis of the investigation, the quality of the cooling system is evaluated. The advantages and other possible applications of the method are discussed. [ABSTRACT FROM AUTHOR]

The space-time structure of hail-hazardous cumulonimbus clouds evolving on the sea- breeze fronts in northwestern Black Sea coast for the period of 1996-1999 is investigated with the help of MRL-5. A chart of number of days with radio echo of cumulonimbus clouds with radar reflectivity more than 65 dBZ in days with evolution of sea-breeze fronts is obtained. Statistic characteristics of sea-breeze fronts are presented.