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35. A Secure Communication System of Synchronized Chua’s Circuits in LC Parallel Coupling

Author

Sadanandachary A, Narender Reddy S, and Satya Prakash V

Subjects
chua’s circuit, chaotic masking, secure communications, lc parallel coupling, complete synchronization, ltspice., Electronic computers. Computer science, QA75.5-76.95, Applied mathematics. Quantitative methods, T57-57.97
Abstract

Synchronization capability of two identical chaotic systems can be used for constructing the secure communication systems where the chaotic signal is used as the information carrier. In this paper, a secure communication system is designed by using the bi-directionally synchronized identical Chua’s circuits in LC parallel coupling. LC parallel circuit is used as the new coupling element instead of using a single resistor or capacitor or inductor as the coupling element. This makes the complete synchronization of Chua’s circuits possible for many different sets of coupling inductance and capacitance values so that the flexibility of constructing the secure communication systems is realized. Both the synchronized Chua’s circuits in LC parallel coupling and the corresponding secure communication system are constructed by using the LTspice software. The simulation results show that the secure communication system proposed in the present paper is very efficient for the message transmission for different pairs of coupling inductance and coupling capacitance values where the complete synchronization of Chua’s circuits is observed occur. The two essential properties of an ideal secure communication system - perfect message masking and recovery are observed when compared to other secure communication systems already proposed and constructed previously. So, the simulation results of the present study can be used for practically constructing the efficient communication systems in future.

Published
2023
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36. Intramolecular singlet fission: Quantum dynamical simulations including the effect of the laser field.

Author

Reddy, S. Rajagopala, Coto, Pedro B., and Thoss, Michael

Subjects
*INDUCTIVE effect, *MOLECULAR vibration, *VIBRONIC coupling, *EXCITED states, *CHARGE transfer
Abstract

In the previous work [Reddy et al., J. Chem. Phys. 151, 044307 (2019)], we have analyzed the dynamics of the intramolecular singlet fission process in a series of prototypical pentacene-based dimers, where the pentacene monomers are covalently bonded to a phenylene linker in ortho, meta, and para positions. The results obtained were qualitatively consistent with the experimental data available, showing an ultrafast population of the multiexcitonic state that mainly takes place via a mediated (superexchange-like) mechanism involving charge transfer and doubly excited states. Our results also highlighted the instrumental role of molecular vibrations in the process as a sizable population of the multiexcitonic state could only be obtained through vibronic coupling. Here, we extend these studies and investigate the effect of the laser field on the dynamics of intramolecular singlet fission by explicitly including the coupling to the laser field in our model. In this manner, and by selectively tuning the laser field to the different low-lying absorption bands of the systems investigated, we analyze the wavelength dependence of the intramolecular singlet fission process. In addition, we have also analyzed how the nature of the initially photoexcited electronic state (either localized or delocalized) affects its dynamics. Altogether, our results provide new insights into the design of intramolecular singlet fission-active molecules. [ABSTRACT FROM AUTHOR]

Published
2024
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