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Ni 1 − x TixMnSb polycrystalline alloys in the range 0 ≤ x ≤ 0. 2 0 were synthesized employing the standard solid-phase synthesis method. The crystal, magnetic, as well as electrical properties of the alloys were investigated using neutron powder diffraction and magneto-resistance measurements. The results reveal that the substitution of Ti for Ni within the temperature range of 2.5–300 K does not induce alterations in the crystal and magnetic structures of NiMnSb. The ordered Ni magnetic moment approaches zero. The study of the electrical transport properties of the Ni 1 − x TixMnSb alloys, where 0 ≤ x ≤ 0. 2 0 , has demonstrated a half-metallic state at low temperatures and metallic conductivity for temperatures exceeding 160 K. A semiconductor state manifests at titanium concentrations of x = 0.2 and was observed at temperatures below 21 K. The obtained experimental results are elucidated through first-principles theoretical calculations. [ABSTRACT FROM AUTHOR]

This study investigates the contemporary thermoelasticity theories in a photothermal semiconducting medium with voids influenced by the electromagnetic field. Boundary conditions of the phenomenon were based on the equations that regulate it concerning the stresses, carrier density, change in volume fraction field and temperature on the surface space. The equations were solved in normal mode technique, and the results are displayed by graphs. A comparison has been made with the findings of the literature when neglecting the new external parameters. The findings show that the presence or absence of electromagnetic field and carrier density significantly impacts on the phenomenon. From the results obtained, it is clear that the effects of electromagnetic field, carrier density, volume fraction and thermal relaxation times are very pronounced and applicable in diverse fields including geophysics, astronomy, engineering, biology, etc. [ABSTRACT FROM AUTHOR]

Cu2SnS3 (CTS) is expected to be an absorber material for next-generation solar cells because it is composed of nontoxic, low-cost elements and has an absorption coefficient of >104 cm−1. In this study, the effects of sulfurization in tin sulfide (Sn x S y) and S mixed vapors on various properties of CTS were investigated by using a 3-zone tube furnace to suppress carrier recombination at the grain boundaries and control the composition of the CTS. The CTS deposited via sulfurization in S vapor only (1-zone CTS) contained different monoclinic and tetragonal CTS structures. The grain size of the CTS thin films deposited via sulfurization in Sn x S y and S mixed vapors was not increased. On the other hand, crystal structure analysis revealed that the CTS had grown to single-phase monoclinic CTS. The results suggest that precipitation in Sn x S y and S mixed vapors contributes to the growth of monoclinic CTS with suitable power-generation characteristics. This finding is important for realizing high-efficiency CTS-based solar cells. [ABSTRACT FROM AUTHOR]

Understanding the electronic structures of gate oxides in Si-based devices is significant for improving device performance. We investigate the electronic properties of the oxygen vacancy defects in β -quartz SiO2/Si interface structure using first-principles calculations. The results indicate that the constructed (SiO2)4/(Si)4 structure is an indirect-gap semiconductor, with its band edges contributed by Si side and a large band-edge energy difference ( > 1.780 eV). Our study reveals that the presence of oxygen vacancy defects reduces the band gap, and V O 1 is transformed from indirect into direct band gap. The Si dangling bonds in V O 1 cause charge localization around the O vacancy, while the formation of Si–Si bonds in V O 2 and V O 3 lead to electron delocalization. In the calculation of defect formation energies, we find that V O 1 maintains the lowest formation energy across different states, making it more likely to form and structurally stable. Compared to O-rich environments, the formation energy in O-poor environments is overall reduced by approximately 4.5 eV, indicating that oxygen vacancy defects are more likely to form and be controlled under O-poor conditions. Our study emphasizes the importance of interface structure and defect characteristics in semiconductor research, providing insights for the development of Si-based devices. [ABSTRACT FROM AUTHOR]

This study introduces a generalized photothermal model to analyze the coupled thermo-hydromechanical behavior of a poroelastic, nonlocal semiconductor medium subjected to laser excitation. The medium is modeled as a saturated, dynamic, poroelastic half-space under time-harmonic loads, including thermal and mechanical forces and plasma electron distribution induced by laser pulses. A novel framework that integrates photo-thermoelasticity with hydrodynamic and poroelastic effects, capturing the nonlocal interactions at the nanoscale. At first, we subjected this medium to time-harmonic loads comprising thermal and normal loads and a distribution of plasma electrons applied with heating laser pulses. Afterward, we compared the photo-thermoelastic dynamic models to the coupled thermo-hydromechanical ones. The resulting nondimensional coupled equations were solved using two-dimensional normal mode analysis. The resulting nondimensional coupled equations were solved using two-dimensional normal mode analysis. The study examined the effects of nondimensional displacement, mechanical stress, excess pore water pressure, carrier concentration (density), and temperature distribution on the poroelastic half-space medium. Graphical representations were produced to highlight these effects based on specific parameters. [ABSTRACT FROM AUTHOR]

Herein, CdTe/MnS core/shell nanoparticles dispersed in an aqueous solution have been synthesized. The formation of MnS semiconductor shell occurs by spontaneous self‐assembly. This process is activated by thermal hydrolysis that removes the excess of thiol and releases S2− ions. In this process, Mn2+ ions on the surface of the CdTe nanoparticles bind to S2− ions to produce a fine semiconducting layer of MnS. Measurements of Raman spectroscopy, optical absorption, and electrochemical measurements are performed. The Raman spectrum shows CdTe characteristic bands at 141 and 163 cm−1. Bands at 221 and 444 cm−1 are associated with the MnS structure. Cyclic voltammetry and differential pulse voltammetry are used to estimate the electrochemical gap at ≈2.47 eV. Absorption optical measurements show tree absorption bands. A broad band between 460 and 520 nm is associated with the first transition in CdTe nanoparticle. The absorption spectrum reveals an optical gap in the range of 2.41–2.33 eV for all the refluxed samples. These values are consistent with those obtained with the electrochemical measurements. The results evidence the formation of a core–shell semiconducting nanostructure made of CdTe nanoparticles coated with a spontaneously self‐assembled thin layer of MnS nanoparticles. [ABSTRACT FROM AUTHOR]

The United States has tightened its technical embargo against China since the Sino-US rivalry began in the mid-2010s, especially in the semiconductor sector. It also has repercussions for China's relations with US allies such as South Korea (or the Republic of Korea, ROK). As China's technical growth is securitized, Sino-ROK collaboration in semiconductor technology becomes politicized, according to a securitization-politicization nexus derived from securitization theory. Under the pressure from Washington, even Korean semiconductor businesses may be forced to 'choose sides'. However, Seoul's pragmatic approach to Beijing prevents the politicization of Sino-ROK technological ties. While demanding security guarantees from Washington, Seoul is unwilling to enhance ties with the US at the price of those with China. Among three scenarios figured out in this paper, South Korea is likely to consolidate its ties with China in semiconductor industry in some form of 'smart' collaboration Ceteris paribus, and this is also in the interest of Beijing. [ABSTRACT FROM AUTHOR]

A novel approach for modifying zinc stannate nanomaterials involves using a bio-extract derived from the leaves of Hibiscus rosa-sinensis. Ag nanomaterial and biomolecule sensitization was conducted in a single pot. The composite materials of Ag and biomolecules were characterized using powder X-ray diffraction, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy analysis to determine their structural aspects. Based on the PXRD results, it was determined that the composites exhibit a face-centered cubic structure. The observed frequencies of C − H and Sn − O stretching in the FT-IR spectra indicate the existence of biomolecules within the composite material. Furthermore, the X-ray photoelectron spectroscopy findings validate the coordination of zinc and tin within the zinc stannate compound with biomolecules while indicating silver's presence on the surface. Scanning electron microscopy and transmission electron microscopy techniques have revealed the material's porous characteristics and reduction in size of the zinc stannate particles. In addition, the results demonstrated the spherical morphology of the silver particles that have undergone doping. Surface agglomeration and optical characteristics were investigated using UV–Vis spectroscopy. The observed phenomenon exhibits pronounced particle agglomeration resulting from biomolecules on the surface. In addition, the emergence of an additional absorption band at approximately 453 nm can be attributed to silver's surface plasmon resonance effect. The obtained J–V curve for all samples demonstrates the observed enhancements, resulting from incorporating Ag and biomolecules. The enhancements observed in the simulation results were further confirmed through the validation process, which demonstrated the extended absorption and surface plasmon resonance effect. [ABSTRACT FROM AUTHOR]

This study presents a comprehensive approach to vibrational analysis in a size-dependent, orthotropic thermo-piezo-photo-electric semiconductor half-space under Moore–Gibson–Thompson (MGT) photo-thermoelasticity theory with memory-dependent derivatives. Following Eringen's nonlocal elasticity theory, the governing equations for the considered material are derived. The normal mode technique is applied to investigate the photothermal excitation process. Focusing on the interface adjacent to the vacuum, the study considers plasma, thermal, and mechanical stress boundary conditions to determine fundamental physical quantities. Through a detailed exploration, this research examines the impact of various thermo-piezo-photo-electric models, time, nonlocal parameters, and spatial coordinates on different physical quantities. The effects are meticulously analyzed and visually represented through graphical illustrations. While the literature survey reveals numerous studies on vibrational analysis in thermo-piezo-photo-electric semiconductor mediums under different thermoelasticity theories, to the best of the authors' knowledge, no research emphasizing vibrational analysis in a size-dependent thermo-piezo-photo-electric semiconductor medium has been conducted. Moreover, the effect of memory-dependent MGT photo-thermoelasticity theory on a size-dependent thermo-piezo-photo-electric semiconductor half-space has not been illuminated until now, significantly defining the novelty of the conducted research. [ABSTRACT FROM AUTHOR]

Coordination polymers (CPs) are promising for direct X‐ray detection and imaging owing to higher designability and outstanding stability, however, it remains a challenge to achieve highly X‐ray detection performance, particularly both high sensitivity and low detection limit at the same operating voltage. Herein, we construct a new conjugated CP {[Co(BPTTz)(DIPA)] ⋅ DMA}n (1, BPTTz=2,5‐bis(pyridine‐4‐yl)thiazolo[5,4‐d]thiazole, H2DIPA=2,5‐diiodoterephthalic acid, DMA=N, N’‐dimethylacetamide), with multi‐channel charge transfer by regulating the linker mediated electronic‐state, which reduces carrier losses resulting from recombination or quenching, enhances the efficiency of charge separation and transfer, thus further optimizes X‐ray detection performance. The semiconductor prepared based on this strategy achieves record values including the highest mobility‐lifetime product (μτ, 8.05×10−3 cm2 V−1) and the lowest detectable X‐ray dose rate (128 nGyair S−1, 35 V) among CP‐based direct radiation detectors, as well as a high sensitivity (172 μC Gyair−1 cm−2, 35 V) at the same operating voltage. This detector shows excellent long‐time air stability under ambient conditions for over three months and operational stability. These findings demonstrate a rational structural design method to enhance the photoelectronic efficiency and stability of semiconductive CPs. [ABSTRACT FROM AUTHOR]

This manuscript examines the effects of memory-dependent and fractional-order derivatives on a novel generalized piezo-thermo-elastic semiconductor model. The medium is homogenous and orthotropic, subjected to photo-thermal excitation. The governing equations include fractional-order parameters, relaxation time, time delay, and kernel function tailored to specific problem requirements. Normal mode method use to solve the equations, yielding analytical expressions. Graphical representations show physical field distribution across various fractional-order parameters, kernel functions, time delay, and frequency values. This study has the potential to advance precise model development and future simulations. [ABSTRACT FROM AUTHOR]

Two rare earth isonicotinic acid compounds [Y(HIA)2(H2O)4(NO3)](2NO3) ((1); HIA = isonicotinic acid) and [LaHg3Cl8(HIA)4]nnCl (2) were reported. Compound one features an isolated (0-D) structure, while compound two has a two-dimensional (2-D) structure. The rare earth ions are coordinated by eight oxygen atoms to display a square antiprismatic REO8 geometry. Compound one shows blue photoluminescence and it has CIE chromaticity coordinates of 0.2332 and 0.3104. The CCT of compound 1 is 13755 K. Compound two exhibits green photoluminescence and it has CIE chromaticity coordinates of 0.3663 and 0.6184. The CCT is 4997 K. Their band gaps are 2.86 and 3.12 eV. [ABSTRACT FROM AUTHOR]

The recent claimed room-temperature superconductivity in Cu-doped lead apatite at ambient pressure is under debate. To identify its physical origin, we conducted a detailed analysis of the crystal structure, band structure, lattice dynamics and magnetic properties of the parent Pb10(PO4)6O compound and the two different phases of Pb9Cu(PO4)6O (LK-99) compound. Our results show that the parent Pb10(PO4)6O compound is an indirect band gap semiconductor, where Cu doping at the 4f site of Pb leads to a semiconducting to half-metallic transition. Two half-filled flat bands spanning the Fermi energy levels are present in the 4f phase of LK-99, which are mainly formed by hybridization of the d orbitals of Cu with the 2p orbitals of O. In addition, 6h phase of LK-99 always has spin polarization at the bottom of the conduction band and at the top of the valence band, making the material a magnetic semiconductor. Our theoretical research reveals recent experimental reports on the different transport properties of LK-99. [ABSTRACT FROM AUTHOR]

The future of next‐generation electronics relies on low‐cost organic semiconductors that are tailored to simultaneously provide all requisite optoelectronic properties, focusing greatly on ambipolar charge‐transport and solution processability. In this regard, room‐temperature discotic liquid crystals (DLCs) are potential candidates, where quasi‐1D self‐assembly affords a charge‐transport channel along their columnar axis. This work shows a molecular design strategy by utilizing anthraquinone as the primary motif, surrounded by ester functionalized tri‐alkoxy phenyl units to develop room‐temperature DLCs (1.1–1.3). Here, the polar ester functionality stabilizes the columnar mesophase over a wide range through the involvement of dipole‐dipole interaction along with the π–π stacking. Throughout the entire mesophase transition, reported compounds 1.1–1.3 exhibit a highly ordered 2D columnar oblique (Colob) self‐assembly. Space charge limited current (SCLC) experiments reveal balanced ambipolar charge transport, with the maximum hole and electron mobilities of 5.04 and 4.93 cm2 V−1 s−1, respectively. From the conoscopic results, their propensity to align in a highly homeotropic fashion is demonstrated. It is further justified by the azimuthal plot corresponding to the (11) peak of grazing incidence small angle X‐ray scattering (GISAXS), denoting the crucial role of the design and alignment for efficient movement of charge carriers in the material. [ABSTRACT FROM AUTHOR]

The current study deals with reflected waves through a porous medium with viscoelastic properties. The considered continuum media is a semiconductor with elastic and thermal properties which varies exponentially along the depth of the medium. The thermal disturbance caused by elastic propagation is then encountered by the refined phase-lag heat conduction model. The scattering relation for the coupled waves has been computed. It is observed that the functionally graded, voids and non-local parameters reduce the amplitude ratios of reflected waves propagating through the medium. The solution in the form of amplitude ratios for reflected waves has been obtained analytically and represented graphically for a particular medium. [ABSTRACT FROM AUTHOR]

Mesoporous Titanium dioxide (TiO2) sphere, nanosheet and nanoparticle were synthesized by a simple wet chemical method using Trichloroaniline (TCA) as a capping agent. The presence of a lone pair of electrons in the TCA is used to modify the TiO2 structure when it is added with different amounts of ratios. The as-synthesized TiO2 nanostructures were characterized by powder X-ray diffraction, Raman spectroscopy (FT-Raman), ultraviolet–visible spectroscopy, Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy and transmission electron microscopy. The anatase phase of TiO2 was confirmed by Powder X-ray diffraction and Raman spectroscopy. The particle size of TCA-capped TiO2 was reduced when compared with the sample without TCA capping. FTIR results demonstrated the TiO2 nanoparticles were capped by the TCA molecule. The impact of different TiO2 nanostructure morphology for DSSCs was investigated. The photoanode cells were fabricated with mesoporous spheres and mixed morphology of TiO2 nanoparticle and nanosheet. Their optimal efficiencies were found to be 5.537 and 1.539%, respectively. Mesoporous spheres coated photoanode cells reached the maximum efficiency when compared to that of the mixed morphology of nanosheet with nanoparticle-coated photoanode. The enhanced performance of mesoporous spheres coated photoanode cells is due to the anatase phase of TiO2 with high crystallinity and interconnected mesoporous network. [ABSTRACT FROM AUTHOR]