1. SrO Doping Effect on Fabrication and Performance of Ni/Ce1-xSrxO2-x Anode-Supported Solid Oxide Fuel Cell for Direct Methane Utilization.
- Author
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Nicharee Wongsawatgul, Shinichi Momiyama, Soamwadee Chaianansutcharit, Kenichi Yoshida, Makoto Nanko, and Kazunori Sato
- Subjects
SOLID oxide fuel cells ,ANODES ,SOLID solutions ,STRONTIUM oxide ,METAL fabrication ,SEMICONDUCTOR doping - Abstract
The performance of Ni/SrO-doped CeO
2 (SrDC) anode-supported cells, combined with the Sm2 O3 -doped CeO2 (SDC) electrolyte layer, has been investigated for the direct supply of a dry CH4 . The SrO content in the Ce1-x SrxO2-x solid solution affects the porous structure of the starting anode support comprising of the sintered NiO and Ce1-x SrxO2-x grains and denseness of the SDC layer by co-sintering. The cell using the 5 mol% SrO-doped CeO2 shows the highest cell performance without time-dependent degradation even at 750°C. This cell (the 5SrDC cell) also provides better cell performance with decreasing operating temperature than the conventional Ni/YSZ anode-supported cell (the YSZ cell); the maximum power density of the 5SrDC cell is higher than that of the YSZ cell by 73% at 650°C. This enhancement effect is discussed in light of the mixed ionic-electronic conduction of the CeO2 -based solid electrolytes. [ABSTRACT FROM AUTHOR]- Published
- 2021
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