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Smelting and fiberization of red mud (RM) is an attractive approach for rapid recovery of metal resources, production of mineral wool, and immobilization of hazardous alkalis. However, an enormous challenge remains in understanding alkali immobilization behavior in mineral wool over a broad A/S (Al 2 O 3 to SiO 2 mass ratio) range. Here we addressed the challenge through molecular dynamics, thermodynamic and experimental analyses. Increasing A/S ratio caused an increasing degree of structural order and the remarkable micro-phase separation occurred at A/S > 0.9. The role of Na+ and Ca2+ changed from the network-modifying cations to the charge-compensating cations. Melt viscosity decreased and then increased significantly with an intensified temperature sensitivity, identified by the increasing viscous flow activation energy from 211.5 to 377.03 kJ/mol in the temperature region from 1500 to 1570 °C. The transformation of thermodynamic properties (real mixed/excess molar Gibbs free energies, and entropy increment) corresponded to the structural changes. Thermal, mechanical and leaching tests confirmed the negative effect of this structural transformation on alkali immobilization. The A/S ratios controlled below 0.9 were proposed for environmental benefits and product stability. The investigation of immobilization mechanism provides valuable information for tuning the vitrification chemistry and developing safe and green mineral wool from RM. [Display omitted] [ABSTRACT FROM AUTHOR]

The co-sintering behavior of a ceramic-metal bilayer is carefully investigated. This bilayer is composed of a gold film deposited by screen-printing on a silica-based low-temperature cofired ceramic (LTCC) layer. First, behaviors of both materials in free sintering are finely characterized. LTCC exhibits a viscous flow sintering mechanism, whereas the densification mechanism of gold is controlled by grain boundary diffusion (with an identified apparent activation energy of 101 ± 15 kJ mol−1). Free sintering of gold is also marked by a two-step densification process due to its large bimodal particle size distribution. A methodology is proposed to estimate gold viscosity at high temperatures directly from raw experimental data in free sintering, without performing dedicated mechanical characterizations. Based on the constitutive laws identified for LTCC and gold materials, analytical and numerical models of the bilayer co-sintering process are built. During co-sintering, stresses generated by densification kinetic mismatch between gold and LTCC are progressively relaxed by camber phenomenon. Calculated evolutions of camber in co-sintering are compared to curvature monitoring by ombroscopy. Finite element simulation in 3D fits well with the experimental data, whereas the analytical solution strongly underestimates camber rates. This shows that the simplified numerical approach suggested here leads to a robust numerical model, faithfully describing thermomechanical interactions occurring in co-sintering within the ceramic-metal bilayer. [ABSTRACT FROM AUTHOR]

Lignin, one of the most abundant biopolymers on Earth, is of great research interest due to its industrial applications including biofuel production and materials science. The structural composition of lignin plays an important role in shaping its properties and functionalities. Notably, lignin exhibits substantial compositional diversity, which varies not only between different plant species but even within the same plant. Currently, it is unclear to what extent this compositional diversity plays on the overall structure and dynamics of lignin. To address this question, this paper reports on the development of two models of lignin containing all guaiacyl (G) subunits with varied linkage sequences and makes use of all-atom molecular dynamics simulations to examine the impact of linkage sequence alone on the lignin's structure and dynamics. This work demonstrates that the structure of the lignin polymer depends on its linkage sequence at temperatures above and below the glass transition temperature ( T g ), but the polymers exhibit similar structural properties as it is approaching the viscous flow state (480 K). At low temperatures, both of lignin models have a local dynamics confined in a cage, but the size of cages varies depending on structural differences. Interestingly, at temperatures higher than T g , the different linkage sequence leads to the subtle dynamical difference which diminishes at 480 K. [ABSTRACT FROM AUTHOR]

In this paper, we consider a singular limit problem for a diffuse interface model for two immiscible compressible viscous fluids. Via a relative entropy method, we obtain a convergence result for the low Mach number limit to a corresponding system for incompressible fluids in the case of well‐prepared initial data and same densities in the limit. [ABSTRACT FROM AUTHOR]

Purpose: This study investigates the behavior of viscous hybrid ferromagnetic fluids flowing through plain elastic sheets with the magnetic polarization effect. It examines flow in a porous medium using Stefan blowing and utilizes a versatile hybrid ferrofluid containing MnZnFe2O4 and Fe3O4 nanoparticles in the C2H2F4 base fluid, offering potential real-world applications. The study focuses on steady, laminar and viscous incompressible flow, analyzing heat and mass transfer aspects, including thermal radiation, Brownian motion, thermophoresis and viscous dissipation with convective boundary condition. Design/methodology/approach: The governing expression of the flow model is addressed with pertinent non-dimensional transformations, and the finite element method solves the obtained system of ordinary differential equations. Findings: The variations in fluid velocity, temperature and concentration profiles against all the physical parameters are analyzed through their graphical view. The association of these parameters with local surface friction coefficient, Nusselt number and Sherwood number is examined with the numerical data in a table. Originality/value: This work extends previous research on ferrofluid flow, investigating unexplored parameters and offering valuable insights with potential engineering, industrial and medical implications. It introduces a novel approach that uses mathematical simplification techniques and the finite element method for the solution. [ABSTRACT FROM AUTHOR]

Densities (ρ), speeds of sound (u), and viscosities (η) were derived for three distinct binary mixtures comprising allyl alcohol in conjunction with chlorinated methanes. The Exploration ranged from 303.15 K to 313.15 K, at atmospheric pressure across all composition. The empirical data from the measurements formed the foundational basis for the determination of excess molar volume, excess isentropic compressibility, viscosity deviation and excess Gibbs free energy with the activation of viscous flow. We computed partial molar and infinite dilution properties for each binary system. The results are interpreted in the forming complexes, chemical forces and specific interactions with binary mixtures. The implication drawn from the application of the Jouyban-Acree model are expounded, taking into account the mean relative deviation (MRDs) and individual relative deviation (IRD) between the calculated and experimental densities, speed of sound, and viscosities as a criterion for accuracy criterion. FTIR studies validate experimental findings in investigated mixtures. [ABSTRACT FROM AUTHOR]

Densities (ρ), speeds of sound (u), and viscosities (η) for three binary mixtures of 4-Hydroxy-4-methyl-pentan-2-one with 3-amino-propan-1-ol, 2-amino-2-methyl-propan-1-ol, and 1-amino propan-2-ol were calculated at temperatures ranging from 303.15 to 313.15 K and atmospheric pressure over the entire composition range. Experimental measurements were used to calculate the excess molar volume, excess isentropic compressibility, deviation in viscosity, and excess Gibbs free energy of the activation of viscous flow. Partial molar properties and infinite dilution molar partial properties are also calculated for each binary system. Heteroassociates molecules forming complexes and chemical forces with specific interactions can be discussed from the results. The Prigogine–Flory–Patterson theory is used to identify the most important interaction. The results of the Jouyban–Acree model are discussed in terms of the mean relative deviation and individual relative between the calculated and experimental densities, speed of sound, and viscosities as an accuracy criterion. FTIR studies confirm the experimental findings of the investigated mixtures. [ABSTRACT FROM AUTHOR]

Densities (ρ), speeds of sound (u) and viscosities (η) were measured for three binary mixtures of propargyl alcohol with tetra chloromethane, trichloromethane, and dichloromethane from 303.15 K to 313.15 K at atmospheric pressure across the composition range. Excess molar volume, excess isentropic compressibility, deviation in viscosity, and excess Gibbs free energy of activation of viscous flow were calculated. Partial molar properties and infinite dilution molar partial properties were also determined for each system. Results suggest heteroassociates forming cross complexes and chemical forces with specific interactions. PFP theory was used to identify the predominant molecular interactions. The Jouyban–Acree model findings were discussed, considering mean relative deviation (MRDs) and individual relative deviation (IRD) between calculated and experimental data. FTIR studies were included to corroborate the experimental findings. [ABSTRACT FROM AUTHOR]

Excess molar volume, excess isentropic compressibility, deviation in viscosity and excess Gibbs free energy for activation of viscous flow for binary mixtures of propargyl alcohol (J) with benzyl aldehyde (J1), benzylamine (J2) and benzyl alcohol (J3) components with selected compositions were determined from the measured values of densities (ρ), viscosities (η), and speeds of sound (u) of pure components and their mixtures from 303.15 K to 313.15 K. The effect of various functional groups on the excess properties has been discussed in terms of attractive forces between the components. The results of the Jouyban-Acree model are discussed in terms of the mean relative deviation and individual relative between the calculated and experimental densities, speed of sound, and viscosities as an accuracy criterion.FTIR studies have also been added to confirm the experimental findings of the investigated mixtures [ABSTRACT FROM AUTHOR]

Densities (ρ), speeds of sound (u), and viscosities (η) for three binary mixtures of allyl alcohol with 3-amino-propan-1-ol, 2-amino-2-methyl-propan-1-ol (aminomethyl propanol), and 1-amino propan-2-ol (isopropanol amine) were calculated at temperatures ranging from 303.15 to 313.15K and at atmospheric pressure over the entire composition range. Experimental measurements were used to calculate the excess molar volume, excess isentropic compressibility, deviation in viscosity, and excess Gibbs free energy of the activation of viscous flow. Partial molar properties and partialmolar properties at infinite dilution are also calculated. The Prigogine–Flory–Patterson (PFP) theory is applied to identify the predominant molecular interaction. The results of the Jouyban–Acree model are discussed in terms of the mean relative deviation (MRDs) and individual relative deviation (IRD) between the calculated and experimental parameters as an accuracy criterion. FTIR studies have also been added to confirm the experimental findings of the investigated mixtures. [ABSTRACT FROM AUTHOR]

The thermodynamic and transport properties of binary mixtures of N-methyl benzyl amine (NMBA) with halo methane compounds at temperatures from 303.15 K to 313.15 K were investigated. The study analysed the excess molar volume, excess isentropic compressibility, deviation in viscosity, and excess Gibbs free energy for activation of viscous flow using measured densities (ρ), viscosities (η), and speeds of sound (u). The research also examined the impact of the inductive effect on excess properties concerning intermolecular attractive forces between the respective constituents. Furthermore, the Jouyban–Acree model was employed to correlate density, speed of sound, and viscosity with composition and obtained good agreement. [ABSTRACT FROM AUTHOR]

Excess molar volume, excess isentropic compressibility, deviation in viscosity, and excess Gibbs free energy of activation of viscous flow for binary mixtures of Hexylene glycol (2-methyl-pentanediol-2,4 or MPD) with aliphatic ketones (4-hydroxy-4-methyl-pentan-2-one (J1), 4-methyl-pentan-2-one (J2), and pentan-2-one (J3)) components selected compositions were determined from the measured values of densities (ρ), viscosities (η), and speeds of sound (u) of pure components and their mixtures from 303.15 K to 313.15 K. The results were analysed in terms of intermolecular interactions or hydrogen bonding or hetero-association interactions in the binary mixtures. Finally, the Prigogine-Flory-Patterson (PFP) theory is applied to identify the most predominant molecular interaction. The results of the Jouyban-Acree model are discussed in terms of mean relative deviation (MRDs) and individual relative deviation (IRD) between calculated and experimental densities, speeds of sound, and viscosities as an accuracy criterion. [ABSTRACT FROM AUTHOR]

Steady viscous flow past a circular cylinder with velocity slip boundary condition is numerically solved. The Navier–Stokes equations are solved using the vorticity-stream function formulation for two-dimensional incompressible flows. A time-accurate solver is developed which can be used for accurate solution of time-dependent flows. However, only steady results for Reynolds numbers up to 40 are presented in this paper. Most of the emphasis is dedicated to the validation of the solver and the results, something which is more or less missing in previous studies of slip flows. There has been a controversy regarding the computation of the drag coefficient and its various contributions in the past. As reviewed in the text, some papers did not present the formulation of the drag coefficient and only presented the results, some papers used the no-slip formulae and some papers presented formulae for the slip case but did not validate them. Due to this controversy, we derived formulae for the various contributions to the drag coefficient and validated them by comparison to existing data, especially using an analytical solution of Oseen's equation for creeping flow around a cylinder with slip condition. At the end, some results are presneted including wall vorticity and slip velocity distribution, streamlines, vorticity contours and various contributions to the drag coefficient. [ABSTRACT FROM AUTHOR]

In this work, the physiochemical properties of the drug, isoproterenol hydrochloride, were analyzed in the presence of β-cyclodextrin in an aqueous medium to gain a better understanding of the prevailing interactions among solute–solvent systems with the help of viscosity and conductivity studies. From viscosity measurements, the viscosity B -coefficient along with its transfer parameter was calculated using the Jones–Dole equation. In addition to this, the activation parameters such as Δ μ 1 o # , Δ μ 2 o # , Δ S 2 o # , and Δ H 2 o # were evaluated and discussed to gain a better understanding of the mechanism of viscous flow in terms of transition state theory. Along with this, conductivity studies were performed to investigate the thermodynamics of the ternary system in terms of changes in Gibbs free energy. Also, the delayed critical aggregate concentration of the ternary system supports favourable interaction between the studied drug and β-cyclodextrin molecules. [ABSTRACT FROM AUTHOR]

Thanks to the reinforcing and toughening of carbon fiber, carbon fiber reinforced mullite (C/Mullite) composites exhibit favorable application potential as thermal structural materials. To further reveal the failure mechanism of the C/Mullite composites in service environment, the oxidation resistance and failure behavior of the composites were systematically investigated in this study. It was found that the oxidation mechanism of the composites inclined to diffusion control at 1300 °C∼1500 °C, the cracks and pores of the composites provided diffusion channels for oxygen to oxidize the composites, the oxidation degree of carbon fibers and interfacial coating after oxidation was responsible for the weight loss and performance degradation of the composites. Additionally, the oxidation resistance of C/Mullite composites can be obviously enhanced by using the SiO 2 -rich (the Al/Si atomic ratio was 1/2) Al 2 O 3 –SiO 2 sol to densify at the later stage of fabrication, strength retention and modulus retention of the composites were increased by 28 % and 40 % after oxidation at 1500 °C in air, respectively. [ABSTRACT FROM AUTHOR]

Based on the generalized results of experimental methods for studying the viscosity of oligomers—DSC, electron microscopy, NMR spin echo, x‐ray diffraction analysis, edge wetting angles, laser microinterference, atomic force microscopy, dynamic light scattering, plastic flow—an analysis of the features of the supramolecular organization of melts and solutions of epoxy oligomers was carried out. In terms of thermofluctuation approach, a qualitative assessment of the structural elements forming a macroscopic polymer body is given, and direct morphological evidence of their structure, thermodynamic stability, size evolution with temperature changes and elastic‐strain effects is presented. A mathematical apparatus has been developed to describe the destruction of domains in solutions and melts of oligomers. Analytical equations have been proposed for calculating the time of thermofluctuation relaxation of domains. Based on the analysis of the supramolecular structure of dian epoxy oligomers by transmission electron microscopy and translational mobility of oligomer macromolecules in the high temperature region (Tg + 150°C), it has been suggested that a structure such as "flickering clusters" of free volume elements is formed in the oligomer melts. Highlights: Phase diagrams of aromatic and aliphatic epoxy oligomers have been constructed.The influence of molecular weight on the activation energy of diffusion of viscous flow is estimated.It has been shown that the supramolecular structure of epoxy oligomers in the melt contains "flickering clusters."The lifetime of density fluctuations of epoxy oligomers domains in melts has been calculated. [ABSTRACT FROM AUTHOR]

Reliable predictions of the flow rate and viscous dissipation in the melt conveying zone of single‐screw extruders are crucial for designing high‐quality and efficient extrusion processes. Full‐scale computational fluid dynamics simulations offer deep insights into the process, but they cover only specific use cases. Conversely, state‐of‐the‐art analytical approximation models suffer from a systematic error by neglecting channel curvature. To overcome these limitations, we employed a hybrid modeling approach that efficiently combines analytical, numerical, and data‐based techniques. First, the mathematical problem was formulated for a three‐dimensional, isothermal Stokes flow of power‐law fluids in curved channel segments of unit length, and the theory of similarity was applied to render it in a dimensionless form. Using the finite‐volume method, the flow problem was then solved numerically for a wide range of extrusion setups. Finally, by means of symbolic regression and genetic programming, three dimensionless approximation equations were derived from the numerical dataset. These regression models provide continuous and remarkably accurate predictions of both flow rate and viscous dissipation rate, and clearly outperform existing approximations due to the included effects of channel curvature. Implemented within screw design software, our novel regression models will enable faster progress in screw design and process troubleshooting. Highlights: Three‐dimensional flow of power‐law fluids in helical screw channelsGeneralized problem description using dimensional analysisMelt conveying simulations considering both curvature and flight effectsIntegration of process knowledge into symbolic regression modelingAnalytical screw characteristic curves with extended scope of validity [ABSTRACT FROM AUTHOR]

A gas pressure distribution calculation method for viscous laminar and intermediate flows is developed. By introducing the pseudo-conductance for viscous laminar flow, linearized equations describing pressure distribution are obtained. In intermediate flow, the pressure distribution is iteratively obtained. The validity of the method is confirmed by demonstrating a pressure in a long-tube flow path with various flow rates. The result smoothly connects theoretical curves of molecular flow and viscous laminar flow between two regions. Then, the calculation method is applied to an actual device and is compared to the measurement. The comparison between the calculation and measurement shows the qualitative agreement and reveals the requirement for a more detailed implementation of the actual conditions. [ABSTRACT FROM AUTHOR]

This experimental study considers the exchange flow of two miscible fluids in a rectangular channel. The main purpose is to understand the mixing dynamics and explore how mixing and different channel inclinations can affect variations in front velocity. In contrast to previous studies, no steady state is assumed. The larger channel cross-section used in the current study provides an opportunity to visualize and analyze the inertia dominated regime in finer details. For horizontal channels, after opening the gate valve and allowing the transient phase to pass, it is observed that the front velocity remains almost constant for a period before gradually decreasing. In inclined flows, the mixing and transition to inertia dominated flow begin when the viscous flow rate of the main flow increases. This flow rate may exceed the maximum flow rate that the front can tolerate according to the equations describing the momentum balance at the front. At sufficiently high density contrasts or large inclinations, the front velocity may continue to decrease as the flow progresses due to interfacial instabilities and mixing. Under such conditions, the results may also cast doubt on the presence of a true steady state front velocity in miscible exchange flow. [ABSTRACT FROM AUTHOR]

This study reports the density (ρ), speed of sound (u), and viscosity (η) of N,N-dimethyl benzyl amine (DMBA) binary mixtures with propiophenone, p-methylacetophenone, and p-chloroacetophenone in a temperature range of 303.15–313.15 K for various compositions. Excess thermodynamic properties (excess molar volume, VE; excess isentropic compressibility, κsE; viscosity deviation, Δη; and excess Gibbs free energy of activation of viscous flow, ΔG*E) were derived from the experimental data. The analysis focused on understanding intermolecular interactions, particularly the influence of the inductive effect on hydrogen bonding and dipole–dipole interactions within the mixtures. The Jouyban-Acree model was employed to predict the densities, speeds of sound, and viscosities. The model’s accuracy was assessed using the mean relative deviations (MRDs) and individual relative deviations (IRDs) between the calculated and experimental values. To further support these findings, Fourier Transform Infrared (FT-IR) spectroscopy was conducted to provide complementary insights into the intermolecular interactions within the mixtures. [ABSTRACT FROM AUTHOR]

This study investigates the molecular interactions in binary mixtures of 3-pentanol with three allyl compounds (allyl amine, allyl alcohol, and allyl chloride) at various temperatures. The excess molar volume, excess isentropic compressibility, deviation in viscosity, and excess Gibbs free energy of activation of viscous flow were determined from measured values of densities, speeds of sound, and viscosities. The data were analysed to determine excess properties and deviations from ideal behaviour, highlighting the predominance of molecular interactions such as geometrical packing effects and free volume effects. The experimental results were correlated with the Jouyban−Acree model, which effectively relates the observed thermodynamic properties to the composition of the mixtures. This correlation allows for a deeper understanding of molecular interactions that influence the properties of these binary mixtures across different temperatures. [ABSTRACT FROM AUTHOR]

The industrial significance of stability analysis for dual solutions and heat transfer sets the stage for this research. Focusing on Maxwell ternary nanofluid flow, the study aims to enhance thermal conductivity and stability by delving into viscous dissipation and velocity slip effects on a stretching/shrinking sheet. Employing a mathematical model, refined with nondimensional transformations and MATLAB's BVP4C solver, the research identifies dual solutions and examines the influence of key parameters on fluid dynamics and heat transfer. Results showcase a progressive improvement in convective heat transfer and skin friction from mono nanofluid (NF) to binary hybrid nanofluid (HNF), culminating with ternary hybrid nanofluid (THNF). These improvements are significantly associated with the suction/injection parameter (S), whereas the slip (σ) and elastic (K) parameters enhance thermal transfer but negatively affect skin friction efficiency at elevated levels. The robustness of the upper branch solutions underscores the reliability of these findings. Remarkably, at λ = − 1. 25 with a nanoparticle volume fraction of 0.04, ternary nanofluids achieve a 2.9% thermal efficiency leap over HNF, which itself surpasses NF by 0.46%. These findings hold potential for significant advancements in sectors such as electronics, manufacturing, energy, biomedical, environmental engineering, aerospace, and automotive, aiming at elevating thermal efficiency. [ABSTRACT FROM AUTHOR]

Measurements of densities (ρ), speeds of sound (u), and viscosities (η) for binary mixtures of N,N-dimethyl benzyl amine (DMBA) with 1-octanol (D1), 1-nonanol (D2), and 1-decanol (D3) were performed across temperatures from 303.15 K to 313.15 K under atmospheric pressure, covering all composition ranges. These experimental results were utilised to calculate the excess molar volume, excess isentropic compressibility, viscosity deviation, and the excess Gibbs free energy of activation for viscous flow. Calculations for partial molar properties and infinite dilution partial molar properties were also carried out for each binary mixture. The dominant intermolecular interactions within these mixtures were analysed using the PFP theory. Additionally, the Jouyban−Acree model was applied to predict the thermo physical properties such as density, speed of sound, and viscosity. The model’s accuracy was evaluated by comparing predicted values with experimental data through mean relative deviations (MRDs) and individual relative deviations (IRDs). [ABSTRACT FROM AUTHOR]

The shale formation, a common carbon-hydrogen reservoir, has numerous nanoscale pores that facilitate multiple gas transport mechanisms, including viscous flow, slip flow, Knudsen diffusion, and surface diffusion. Additionally, various action mechanisms involving effective stress, real gas effect, gas adsorption and desorption, and fracture-pore characteristics significantly influence gas transport. In this study, we conceptualize shale as a triple porosity medium comprising organic matrix, inorganic matrix, and microfractures. For each system, its hydraulic-mechanical coupled model with action mechanisms and gas transport mechanisms is derived based on fractal theory. After validating the model with Barnett and Marcellus data, the evolution of apparent permeability and gas pressure is studied, as well as the influences of pore fractal features, the real gas effect, and the number of hydraulic fractures on gas extraction. Simulation results indicate that, in comparison to organic matrix, inorganic pore fractal features exert a more noticeable effect on cumulative production. The real gas effect is critical in gas transport and reservoir reserve estimation; disregarding this effect results in a 17.4% underestimation of cumulative gas production by the 1600th day. Fracture interference attenuates the improvement in cumulative production gains from increased hydraulic fracture numbers. • A hydraulic-mechanical coupled triple porosity fractal model is established. • Inorganic matrix pore fractal features have a greater impact on gas transport than organic matrix. • Ignoring the real gas effect leads to an underestimation of gas productivity. • The hydraulic fracture interference significantly reduces gas productivity in the late stage of shale gas exploitation. [ABSTRACT FROM AUTHOR]

Diglycidyl ether of bisphenol A crosslinking with glutaric anhydride is used to form the conventional “covalent adaptive network”, polyether sulfone (PES) by coiling and aggregating on the adaptive network is used to significantly increase the uncured resin viscosity for improving the processability of epoxy resin, but inevitably affecting the curing reaction and dynamic transesterification reaction. This study investigates the crucial roles of PES in curing dynamics and stress relaxation behavior. The results indicate that although PES does not directly participate in the crosslinking reaction of polyester‐based epoxy vitrimers. Moreover, the isothermal curing studies reveal that the addition of PES can greatly bring forward the reaction rate peak from conversion α = 0.6 to α = 0.2, meaning that the curing mechanism transfers from chemical control to diffusion control. Dynamic property analysis shows that the addition of PES significantly accelerates stress relaxation, especially at lower temperatures, leading to low viscous flow activation energy Eτ and relatively insensitive stress relaxation behavior to temperature. Introducing PES into vitrimer resin greatly improves crosslinking density (2.31 × 10⁴ mol m−3), enhancing glass transition temperature (82.68 °C), tensile strength (68.66 MPa), and fracture toughness (6.25%). Additionally, the modified vitrimer resin exhibits satisfying shape memory performance and reprocessing capability. [ABSTRACT FROM AUTHOR]

Excess molar volume, excess isentropic compressibility, deviation in viscosity, and excess Gibbs free energy of activation for viscous flow for binary mixtures of N-Methyl benzyl amine (NMBA) with 2-Methyl-2-butanol (2M2B), 2-Methyl-1-butanol (2M1B), and 3-Methyl-1-butanol (3M1B) were determined from measured densities (ρ), viscosities (η) and speeds of sound (u) at 303.15 K to 313.15 K. Influence Structural disparities on excess properties is discussed concerning intermolecular forces. The Prigogine – Flory – Patterson (PFP) theory identifies predominant molecular interactions, and the Jouyban – Acree model correlates density, speed of sound, and viscosity with composition. Thermodynamic activation parameters were calculated using the Eyring equation to study viscous flow thermodynamics. FT-IR and 1H NMR spectra of equimolar binary mixtures were analysed to confirm experimental findings through absorption bands (cm−1) and chemical shifts. [ABSTRACT FROM AUTHOR]

A general solution to harmonic excitation of beam-shaped specimens made from porous, fluid-saturated, transversely isotropic, and viscoelastic materials is developed and presented. The solution draws from Biot's theory of dynamic poroviscoelasticity and adopts a modification of Timoshenko beam model to account for the moment due to pore fluid pressure. Closed-form expressions for transverse displacement and rotation angle of the beam are obtained for the case of three-point bending experiments. Solutions for Rayleigh and Euler-Bernoulli beam models are recovered as special cases. Implications for possible characterization through relevant dynamic mechanical analysis testing are discussed for materials which exhibit certain anisotropy in both the mechanical and flow properties. Three timescale groups shape the dynamic response of the vibrating beam. These timescales pertain to energy dissipation rate within the solid phase, viscous flow of the pore fluid, as well as the natural frequencies of the test specimen. The interplay of a varying excitation frequency with the described timescales is shown to enable simultaneous characterization of the viscoelastic and poroelastic parameters of the specimen constitutive behavior through the obtained dynamic moduli and loss angles of beam vibrations. [ABSTRACT FROM AUTHOR]

Shakhmatkin and Vedishcheva thermodynamic model (SV TDM) of the 45S5 Bioglass® doped with three different amounts of Li2O (4.1, 9.9, and 12.3 mol%) was evaluated at T = 800 K. The 55 components of SV TDM were considered, among them 12 lithium containing compounds. Different number of components with not negligible equilibrium molar amount was found for different glass compositions (9 or 10). In all glass compositions containing nonzero amount of Li2O, the four lithium compounds with not negligible equilibrium amount were identified, i.e., Li2O·SiO2, 3Li2O·P2O5, Li2O·2CaO·2SiO2, and 2Li2O·SiO2. In the 45S5 glass composition four phosphate compounds with not negligible abundance were identified: 9Na2O·6SiO2·2P2O5, Na2O·2CaO·P2O5, 5Na2O·4SiO2·P2O5, and Na2O·CaO·P2O5. In all other glasses the 3Li2O.P2O5 was found with not negligible abundance. Moreover, in the glass with 4.1 mol% Li2O the Na2O·2CaO·P2O5 and 3Li2O·P2O5 compounds were found with not negligible abundance. For each studied glass the glass transition temperature, coefficient of thermal expansion of glass and metastable melt were measured by thermodilatometry. The low temperature viscosity was measured by thermomechanical analysis. The viscous flow activation energy was evaluated from the viscosity temperature dependence. The compositional dependence of measured thermal properties was analyzed by correlation analysis with the Q-distribution of silicate and phosphate units. [ABSTRACT FROM AUTHOR]

Acoustic metasurfaces are mostly designed in a static medium, ignoring the influence of flow characteristics. However, in actual aeroacoustic noise reduction, e.g., aircraft engine liner design, the background flow can have effects on the sound performance of acoustic metasurfaces, especially for a viscous shear flow. The effect of a viscous shear flow is often neglected in previous studies on the design and sound field prediction of acoustic metasurfaces. For considering the viscous and thermal dissipation effects, an analytical model is developed to predict the sound field of a periodic metasurface in a viscous shear boundary layer. In this model, the effective impedance based on the high-frequency limits is utilized to consider both the actual impedance of the acoustic metasurface and the effect of a finite-thickness viscous shear boundary layer. An acoustic metasurface designed in the static medium or even redesigned with only the effect of an inviscid shear flow is not suitable for wave manipulation when the Reynolds number (Re) changes significantly, since the viscosity is an important and non-negligible factor affecting the sound performance. For the cases in this work, the sound performance gradually deteriorates with the decrease in Re when Re ≥ 5 × 10 6 . When Re ≤ 1 × 10 6 , especially at Re = 1 × 10 5 , the existence of viscous shear flows could result in the destruction of expected anomalous reflection and significant intensity change of the reflected waves. This research provides a method for the design of acoustic metasurfaces under viscous shear flow conditions, which is significant for future aeroacoustic applications. [ABSTRACT FROM AUTHOR]

In this work, a three-dimensional aerodynamic shape optimization (ASO) framework is established based on the high-order (direct) discontinuous Galerkin (DG/DDG) discretization, which serves as a flow solver for solving compressible Euler/Navier–Stokes equations. The design variables are introduced to represent the shapes via two parameterization approaches, including Hicks–Henne and Free-Form deformation methods. At each loop, the radial basis function mesh deformation technique is employed to redistribute the meshes. Two typical gradient-based optimization methods are employed to update the shapes. One is the Sequential Quadratic Programming method, whose gradients are computed based on the discrete adjoint-based method using finite difference approximation via perturbating the design variables individually. The other is the steepest decent approach, where the gradients are provided by the Simultaneous Perturbation Stochastic Approximation method using finite difference approximation via perturbating the design variables simultaneously and stochastically. These modules work with the DG/DDG flow solver to search for improved shapes in ASO framework. Several airfoil drag minimization experiments involving 2D/3D inviscid/viscous flow are presented to demonstrate the performance of high-order DG/DDG flow solver in ASO, where the drag coefficients can be reduced significantly with the constraints well preserved. [ABSTRACT FROM AUTHOR]

Although significant efforts have been devoted to advancing hydrodynamic cloaks for a single object, limited exploration has focused on cloaking multiple objects. By cloak, we mean a state of hydrodynamic invisibility achieved by eliminating flow disturbances caused by intrusive objects in the surrounding fluids. These gaps in understanding present challenges in developing effective strategies for achieving hydrodynamic stealth for multiple objects in collaborative operations. To address these issues, we propose a multi-object hydrodynamic cloak with isotropic and homogeneous fluid viscosity in viscous potential flows through a combination of neutral inclusion theory and convection-diffusion-balance method. By effectively transforming the intrusive objects into one single object while maintaining the overall invasive volume unchanged—a critical factor in flow disturbances—we successfully derive the analytical solution of fluid viscosity for multi-object hydrodynamic cloaks. Numerical simulations demonstrate the proposed cloaks considerably minimize the hydrodynamic perturbations generated by objects in groups with symmetric or asymmetric distributions, various sizes, and even arbitrary shapes. In addition, we reveal that the antagonism between the defined boundary effect of flow disturbances and vorticity magnitudes primarily determines the effectiveness of the proposed cloaks, laying the foundation for the future development of multi-object hydrodynamic cloaks involving interactions among objects. Hopefully, this research will advance the fields of hydrodynamic metamaterials for multiple objects in collaborative settings and contribute to the broader understanding of complexity science. [ABSTRACT FROM AUTHOR]

Swirling flows are extensively used to enhance mixing in chemical and physical processes. Although many fundamental studies involve decaying laminar swirls in circular ducts with constant area—for which several theoretical descriptions exist—converging and diverging pipe sections are often employed, demanding the extension of the analysis to swirling laminar flows in pipes with varying areas. This work analytically investigates axial swirl decay in laminar axisymmetric flows in converging and diverging pipes at moderate Reynolds numbers. The theoretical model extends the classical theory for laminar low swirling flows in straight pipes with impermeable walls to pipes with slowly varying areas. Inlet Reynolds number and converging/diverging angle effects are analyzed for incompressible axisymmetric laminar flows in slender pipes (lengths much greater than the radius). Results show that diverging pipes enhance the swirl decay rate, whereas converging systems have a weakening effect for flows with the same inlet Reynolds number. Conversely, increasing the inlet angle in converging flows decreases the decay rate, whereas larger diverging pipe inlet angles promote swirl decay. A simplified eigenvalue analysis shows that the relationship between the swirl decay lengths in diverging ( ℓ d , div ), straight ( ℓ d , st ), and converging ( ℓ d , conv ) pipes is given by ℓ d , div < ℓ d , st < ℓ d , conv for flows with similar inlet Reynolds numbers. Comparisons with numerical simulations show that the model predictions are almost exact for nondimensional pipe lengths up to 5 × 10 − 2 times the inlet Reynolds number. Approximating the axial velocity profile through a fully developed function representative of laminar flows with heat transfer through the walls shows that the narrower axial velocity profile in diverging flows increases viscous effects, enhancing the swirl decay rate. On the contrary, the flatter axial velocity profile in converging pipes further extends the decay length. [ABSTRACT FROM AUTHOR]

The aerodynamics of aerosols and their deposition on face masks play a critical role in determining the effectiveness of respiratory protection. While existing studies have focused on the risks associated with aerosol dispersion during exhalation, little attention has been paid to aerosol aerodynamics in an open environment, where aerosols can circumvent masks, during inhalation. This is because mask performance has primarily been evaluated by the particle filtration efficiency in closed pipe setups, which do not account for the aerodynamics of aerosols around the wearer's face. In this study, we conduct experiments in an open environment to investigate the aerosol flow around a face mask and the aerosol deposition under varying inhalation pressures. Our results indicate that an aerosol flow near a mask surface behaves like a viscous flow, stagnating within the range of human inhalation. Within this range, we find that the amount of aerosol deposited can be predicted by modifying existing aerodynamics theory. Using a theoretical model, a critical inhalation pressure is identified at which water aerosols begin to penetrate through a mask. Finally, we propose the aerosol circumvention efficiency as a new metric to assess mask performance in open environments by taking into account the effects of aerosol circumvention. [ABSTRACT FROM AUTHOR]

This paper reports the splitting morphology of low-viscous fingers in the microchannels that are associated with flat T-shaped, curved T-shaped, and Y-shaped junctions. The numerical simulations are based on the finite volume approach and the volume of the fluid model. In this study, microchannels are filled with silicon oil. Perfluorodecalin is used to displace silicon oil from the microchannels. Due to viscosity differences, the low-viscous finger (LVF)-shaped instability evolves at the interface of fluids. A single LVF propagates in the parent channel, and at the junction, it splits into two identical LVFs. It is noted that the splitting morphology of LVF depends upon the shape of the junction and its wettability. Therefore, there are three different junctions, i.e. flat T-shaped, curved T-shaped, and Y-shaped, with three different wettability conditions (θ) , i.e. hydrophilic (6 0 ∘ ), hydrophobic (1 2 0 ∘ ), and superhydrophobic (1 5 0 ∘ ) are used for numerical investigation. It is found that a LVF splits symmetrically at all three different junctions but tips of LVFs are found to be convex in superhydrophobic conditions. The LVFs-shaped are curved in the limbs of curved T-shaped microchannel and straight in the limbs of flat T-shaped and Y-shaped microchannels. The findings of this paper may be used in lung biomechanics, respiratory diseases, biochemical testing, and many more. [ABSTRACT FROM AUTHOR]

The elastic surface algorithm (ESA) is an iterative inverse design method for airfoils, considering the airfoil wall as an elastic curved beam pinned at its beginning and ending points. This structure deforms in response to the disparity between existing and target pressure distributions. This paper introduces an improvement to the ESA, allowing controlled movement of the airfoil's leading edge within a vertical groove. This advancement enables the adjustment of the angle of attack during the inverse design process, enhancing the airfoil's robustness and flexibility. In contrast to a fixed angle of attack approach, the proposed method prevents unrealistic geometric features, such as airfoil fishtailing, improving convergence potential. The developed method was validated through the inverse design of NACA0012 and FX63-137 airfoils in a viscous subsonic flow regime. The flow solver was validated using existing experimental results, showing good agreement. Finally, the pressure distribution of the FX63-137 airfoil was modified to increase lift or decrease drag. The corresponding geometries were obtained via the advanced ESA method, resulting in an almost 4 % increase in the lift-to-drag ratio. [ABSTRACT FROM AUTHOR]

Physical properties of the binary solutions, toluene with 2-propanol and 2-methyl-1-propanol, were measured at T = 293.15, 298.15, 303.15, 308.15, and 313.15 K and P = 100 kPa. The experimental density values were tested with the Emmerling et al. and Gonzalez-Olmos–Iglesias equations. The results indicate that the equation by Emmerling et al. is the best to correlate the density for toluene + 2-methyl-1-propanol system, while for toluene + 2-propanol, both proposed equations are proper to correlate the density with composition and temperature. The viscosity results were verified with different models containing two adjustable parameters. The values of viscosity deviation ( ∆ η ), excess molar volume (VE), excess Gibbs energy (ΔG*E), partial molar volumes ( V 1 ¯  and  V 2 ¯ ), and apparent molar volume ( V φ , 1  and  V φ , 2 ) were calculated. The values of the excess molar volume were positive for both systems, while negative values were obtained for the viscosity deviation and the excess Gibbs energy. The excess properties of the mixtures were adjusted to the Redlich–Kister equation. The values of thermodynamic functions of activation of viscous flow were computed and analyzed. Additionally, the Prigogine–Flory–Patterson (PFP) theory was applied to calculate VE and then compared with experimental values. The values of the percentage absolute average deviation obtained suggest the validity of this theory. The Fourier transform infrared spectroscopy (FTIR) spectra of the binary solutions studied in this work allowed for the understanding of the interactions between the molecules of these systems. [ABSTRACT FROM AUTHOR]

In a review paper in this same volume, we present the state of the art on modeling of compressible viscous flows ranging from single‐phase to two‐phase systems. It focuses on mathematical properties related to weak stability because they are important for numerical resolution and on the homogenization process that leads from a microscopic description of two separate phases to an averaged two‐phase model. This review serves as the foundation for Parts I and II, which present averaged two‐phase models with phase exchange applicable to magma flow during volcanic eruptions. Part I establishes a two‐phase transient conduit flow model ensuring: (1) mass and volatile species conservation, (2) disequilibrium degassing considering both viscous relaxation and volatile diffusion, and (3) dissipation of total energy. The relaxation limit of this model is then used to obtain a drift‐flux system amenable to simplification. Here, in Part II, we summarize this model and propose a 1.5D simplification of it that alleviates three issues causing difficulties in its numerical implementation. We compare our model outputs to those of another steady‐state, equilibrium degassing, isothermal model under conditions typical of an effusive eruption at an andesitic volcano. Perfect equilibrium degassing is unreachable with a realistic water diffusion coefficient because conduit extremities always contain melt supersaturated with water. Such supersaturation has minor consequences on mass discharge rate. In contrast, releasing the isothermal assumption reduces significantly mass discharge rate by cooling due to gas expansion, which in turn increases liquid viscosity. We propose a simplified system using Darcy's law and omitting several processes such as shear heating and liquid inertia. This minimal system is not dissipative but approximates the steady‐state mass discharge rate of the full system within 10%. A regime diagram valid under a limited set of conditions indicates when this minimal system captures the ascent dynamics of effusive eruptions. Interestingly, the two novel aspects of the full model, diffusive degassing and heat balance, cannot be neglected. In some cases with high diffusion coefficients, a shallow region where porosity and velocities tend toward zero develops initially, possibly blocking an eventual steady state. This local porosity loss also occurs when a steady‐state solution is subjected to a change in shallow permeability. The resulting shallow porosity loss features many characteristics of a plug developing prior to a Vulcanian eruption. [ABSTRACT FROM AUTHOR]

We review the modeling and mathematical properties of compressible viscous flows, ranging from single‐phase systems to two‐phase systems, with a focus on the occurrence of oscillations and/or concentrations. We explain how establishing the existence of nonlinear weak stability ensures that no such instabilities occur in the solutions because of the system formulation. When oscillation/concentration are inherent to the nature of the physical situation modeled, we explain how the averaging procedure by homogenization helps to understand their effect on the averaged system. This review addresses systems of progressive complexity. We start by focusing on nonlinear weak stability—a crucial property for numerical simulations and well posedness—in single‐phase viscous systems. We then show how a two‐phase immiscible system may be rewritten as a single‐phase system. Conversely, we show then how to derive a two‐phase averaged system from a two‐phase immiscible system by homogenization. As in many homogenization problems, this is an example where physical oscillation/concentration occur. We then focus on two‐phase averaged viscous systems and present results on the nonlinear weak stability necessary for the convergence of numerical schemes. Finally, we review some singular limits frequently developed to obtain drift–flux systems. Additionally, the appendix provides a crash course on basic functional analysis tools for partial differential equation (PDE) and homogenization (averaging procedures) for readers unfamiliar with them. This review serves as the foundation for two subsequent papers (Part I and Part II in this same volume), which present averaged two‐phase models with phase exchange applicable to magma flow during volcanic eruptions. Part I introduces the physical processes occurring in a volcanic conduit and establishes a two‐phase transient conduit flow model ensuring: (1) mass and volatile species conservation, (2) disequilibrium degassing considering both viscous relaxation and volatile diffusion, and (3) dissipation of total energy. The relaxation limit of this model is then used to obtain a drift–flux system amenable to simplification. Part II revisits the model introduced in Part I and proposes a 1.5D simplification that addresses issues in its numerical implementation. Model outputs are compared to those of another well‐established model under conditions typical of an effusive eruption at an andesitic volcano. [ABSTRACT FROM AUTHOR]

Eukaryotic cell rheology has important consequences for vital processes such as adhesion, migration, and differentiation. Experiments indicate that cell cytoplasm can exhibit both elastic and viscous characteristics in different regimes, while the transport of fluid (cytosol) through the cross-linked filamentous scaffold (cytoskeleton) is reminiscent of mass transfer by diffusion through a porous medium. To gain insights into this complex rheological behaviour, we construct a computational model for the cell cytoplasm as a poroviscoelastic material formulated on the principles of nonlinear continuum mechanics, where we model the cytoplasm as a porous viscoelastic scaffold with an embedded viscous fluid flowing between the pores to model the cytosol. Baseline simulations (neglecting the viscosity of the cytosol) indicate that the system exhibits seven different regimes across the parameter space spanned by the viscoelastic relaxation timescale of the cytoskeleton and the poroelastic diffusion timescale; these regimes agree qualitatively with experimental measurements. Furthermore, the theoretical model also allows us to elucidate the additional role of pore fluid viscosity, which enters the system as a distinct viscous timescale. We show that increasing this viscous timescale hinders the passage of the pore fluid (reducing the poroelastic diffusion) and makes the cytoplasm rheology increasingly incompressible, shifting the phase boundaries between the regimes. [ABSTRACT FROM AUTHOR]

We present LinStab2D, an easy-to-use linear stability analysis MATLAB tool capable of handling complex domains, performing temporal and spatial linear stability, and resolvent analysis. We present the theoretical foundations of the code, including the linear stability and resolvent analysis frameworks, finite differences discretization schemes, and the Floquet ansatz. These concepts are explored in five different examples, highlighting and illustrating the different code capabilities, including mesh masking, mapping, imposition of boundary constraints, and the analysis of periodic flows using Cartesian or axisymmetric coordinates. These examples were constructed to be a departure point for studying other flows. [ABSTRACT FROM AUTHOR]

We consider the Cahn–Hilliard/Navier–Stokes system with non–degenerate mobility in the space–periodic case, describing the flow of two viscous immiscible and incompressible Newtonian fluids with matched densities. We identify sufficient conditions on the velocity field for weak solutions to satisfy an energy identity, improving previous results on the literature. [ABSTRACT FROM AUTHOR]

We study surface gravity waves for viscous fluid flows governed by Darcy's law. The free boundary is acted upon by an external pressure posited to be in traveling wave form with a periodic profile. It has been proven that for any given speed, small external pressures generate small periodic traveling waves that are asymptotically stable. In this work, we construct a class of slowly traveling waves that are of arbitrary size and asymptotically stable. Our results are valid in all dimensions and for both the finite and infinite depth cases. [ABSTRACT FROM AUTHOR]

A three-dimensional model of polydisperse reactive sedimentation is developed by means of a multilayer shallow water approach. The model consists of a variety of solid particles of different sizes and densities, and substrates diluted in water, which produce biochemical reactions while the sedimentation process occurs. Based on the Masliyah–Lockett–Bassoon settling velocity, compressibility of the sediment and viscosity of the mixture, the system of governing equations is composed by non-homogeneous transport equations, coupled to a momentum equation describing the mass-average velocity. Besides, the free-surface depicted by the total height of the fluid column is incorporated and fully determined through the multilayer approach. A finite volume numerical scheme on Cartesian grids is proposed to approximate the model equations. Numerical simulations of the denitrification process exemplify the performance of the numerical scheme and model under different scenarios and bottom topographies. • Polydisperse reactive sedimentation. • Multilayer shallow water approach. • Denitrification and eutrophication processes. [ABSTRACT FROM AUTHOR]

Fluid resonance in the narrow gap formed by a two-box system under irregular wave actions is investigated by employing a viscous numerical wave flume based on the OpenFOAM package. The accuracy of the numerical model is validated by comparing it with previous experimental data and numerical results in the literature. It can be observed that the viscous fluid flow model can work well in predicting the free surface amplitudes around the resonant frequency, while the potential flow model overpredicts the resonant amplitude. Numerical simulations suggested that the periods of wave responses in the narrow gap are always around the resonant period with small standard deviations. This can be explained by the spectral analysis that the wave energy in the narrow gap is concentrated at the resonant frequency. The normalized wave amplitudes calculated from the samplings of the large free surface amplitudes are always smaller than the samplings of the small free surface amplitudes. With the increase of the peak enhancement factor, the normalized significant wave heights under irregular wave actions increase and decrease around resonant and nonresonant frequencies, respectively. Compared to the results under regular wave actions, smaller and larger wave amplitudes appeared in the results of irregular wave actions around the resonant and nonresonant frequency ranges, respectively. The decreased normalized wave amplitudes with the increase of incident irregular wave amplitudes can be observed at all the frequency ranges. [ABSTRACT FROM AUTHOR]

Understanding the effective diffusion coefficient (D) is crucial for describing atomic transport during crystal nucleation in supercooled liquids and glasses. However, pinpointing the key structural units driving crystallization in intricate, multicomponent glass-formers remains a challenge. This study presents a novel analysis of lithium diborate (Li₂O·2 B₂O₃ - LB₂) crystallization in supercooled and glassy states by using available viscosity and crystallization data for samples of the same batch. An original key feature is that the nucleation rates were measured using a single-stage rather than the traditional double-stage heat treatment. We compared three proxies for D : D η obtained from viscosity, D U derived from crystal growth rates, and D τ estimated from nucleation time-lags. Our analysis revealed that at deep supercoolings, below the glass transition temperature, D U and D τ yield similar steady-state nucleation rate estimates, which significantly exceed those predicted by using D η (the most frequently used diffusion proxy). This result suggests that the atomic jumps governing crystal nucleation may be comparable to those in crystal growth, but distinct from those associated with cooperative rearrangements controlling viscous flow. Additionally, the estimated kinetic spinodal temperature (T k s) is above the Kauzmann temperature T k , implying that crystal nucleation precedes relaxation to the supercooled liquid state, circumventing the entropy paradox and corroborating recent MD simulations for other substances. These findings are valuable for refining theoretical models of crystal nucleation and highlight the complexities of the glassy state. [ABSTRACT FROM AUTHOR]

This article investigates the laminar flow of power-law fluids through two porous square cylinders in a side-by-side configuration. The effects of power-law index (n), Darcy number (Da), and gap ratio (g/W) are examined within ranges of g/W = 0.5–5, n = 0.4–0.8, and Da = 10−6–10−2, respectively. Two flow conditions are considered: first, for a creeping flow (unseparated flow) at Re = 1 where Darcy's law is applicable; second, for a viscous dominant flow at Re = 100, where Darcy–Forchheimer-extended model is exercised. Flow patterns behind the porous cylinders are analyzed using streamlines, velocity profiles, pressure distribution curves, and vorticity structural parameters (Г). In low permeability levels, the flow exhibits an irregular nonperiodic vortex shedding characterized by a single large vortex street far off the downstream for g/W = 0.5. However, synchronized wake patterns were observed in either antiphase or in-phase modes for higher gap ratios. Leading-edge separation with two-side recirculation induces quasi-periodicity in the flow for all g/W. It was found that increasing the permeability can prevent the leading edge separation. Additionally, a transition from antiphase to in-phase mode occurs when the permeability is altered while maintaining constant flow-time. The presence of a jet-like flow between cylinders significantly impacts unsteady wake patterns. The impact of g/W, power-law index, and permeability on drag is also examined. A jump in some flow parameters was observed at higher Re for the midrange Darcy number, but no such increase was noted for the high shear-thinning behavior. These findings provide a potential approach for improving the design of fluidic systems involving porous cylinders. [ABSTRACT FROM AUTHOR]

A comprehensive study on the thermodynamic and transport properties of binary mixtures composed of active amyl alcohol (AAA) and haloalkane’s was conducted within a temperature range of 303.15 K to 313.15 K. Experimental data on densities (ρ), viscosities (η), and speeds of sound (u) were employed to calculate excess molar volume (VE), isentropic compressibility (KsE), viscosity deviation (Δη), and excess Gibbs free energy for viscous flow (∆G*E). The impact of dipole moment on these excess properties was investigated to gain insights into the prevailing intermolecular interactions within the mixtures. The Prigogine – Flory – Patterson (PFP) theory is applied to identify the predominant molecular interaction. The accuracy of the Jouyban–Acree model in correlating densities (ρ), viscosities (η), and speeds of sound (u) with composition were evaluated, demonstrating satisfactory agreement with experimental data. [ABSTRACT FROM AUTHOR]

Capillarity-driven transport in nanoporous solids is widespread in nature and crucial for modern liquid-infused engineering materials. During imbibition, curved menisci driven by high negative Laplace pressures exert an enormous contractile load on the porous matrix. Due to the challenge of simultaneously monitoring imbibition and deformation with high spatial resolution, the resulting coupling of solid elasticity to liquid capillarity has remained largely unexplored. Here, we study water imbibition in mesoporous silica using optical imaging, gravimetry, and high-resolution dilatometry. In contrast to an expected Laplace pressure-induced contraction, we find a squareroot-of-time expansion and an additional abrupt length increase when the menisci reach the top surface. The final expansion is absent when we stop the imbibition front inside the porous medium in a dynamic imbibition-evaporation equilibrium, as is typical for transpiration-driven hydraulic transport in plants, especially in trees. These peculiar deformation behaviors are validated by single-nanopore molecular dynamics simulations and described by a continuum model that highlights the importance of expansive surface stresses at the pore walls (Bangham effect) and the buildup or release of contractile Laplace pressures as menisci collectively advance, arrest, or disappear. Our model suggests that these observations apply to any imbibition process in nanopores, regardless of the liquid/solid combination, and that the Laplace contribution upon imbibition is precisely half that of vapor sorption, due to the linear pressure drop associated with viscous flow. Thus, simple deformation measurements can be used to quantify surface stresses and Laplace pressures or transport in a wide variety of natural and artificial porous media. [ABSTRACT FROM AUTHOR]

Herein, the influence of P2O5 on the break temperature and phase composition of slag from the double slag converter steelmaking process is investigated comprehensively. The composition and micromorphology of crystallized phase are analyzed by X‐Ray diffractometer and scanning electron microscope equipped with energy dispersive spectrometer. The results reveal that the break temperature of slag increases owing to an increase of P2O5 content. When the P2O5 content is 2%, the break temperature is 1198 °C, and it increases to 1209 °C for the slag with 4% P2O5. With the increase of P2O5 content from 2% to 8%, the activation energy for viscous flow shows an upward trend. The crystallized phase at the same temperature with different P2O5 contents remains nearly unchanged, but the diffraction peak intensity is different. When the P2O5 content remains constant, a decrease in temperature results in significant changes in the micromorphology of crystallized phases. The present results improve the knowledge about the P‐rich slag, and are also significant in optimizing the double slag converter steelmaking process. [ABSTRACT FROM AUTHOR]

This article discusses the thermal radiation significance on the 2-D laminar MHD boundary layer flow of a nanofluid, as well as the heat transfer associated with the viscous flow across a nonlinear stretching surface. The flow is produced by a nonlinearly enlarging sheet with varying temperatures in the existence of suction, radiation, and viscous dissipation. By applying suitable similarity conversions, the resultant governed PDEs are transformed to a set of nonlinear ODE's, and then, they are solved by applying the Keller–Box approach numerically. The impact of several flow pertinent factors on heat, species concentration, and velocity fields are exposed graphically and numerically. Numerical calculations for friction factor, mass, and heat transmission rates are discussed in table form. Prior results were examined under constraining circumstances and found to be adequate. It is discovered that when the velocity slip factor is enhanced, the fluid velocity distribution declines whereas the heat and concentration gradients increase. The principal results indicate that the porosity parameter effectively decreases the velocity distribution. [ABSTRACT FROM AUTHOR]