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The scientific battle between two major classes of materials as to the best option for immobilization and disposal of high-level nuclear wastes (HLW) has endured since the 1970s. Both glass and ceramic materials afford different characteristics and properties that make them specifically suitable for certain types of radioactive wastes; both material types have been previously selected as preferred solutions for different waste treatment programs. During the 1980s, glass predominated following its selection for US defense wastes, and this choice is reflected in the available industrial waste treatment facilities to treat HLW. France, the United Kingdom, and the United States are each pursuing huge industrial programs of HLW treatment that isolate radioactive elements in glass forms for ultimate geologic disposal. However, several existing legacy wastes and emerging wastes from future nuclear technologies and fuel cycles will require innovative waste forms, including ceramics and glass-ceramics. This article tells the story of the history of ceramic and glass-ceramic waste forms for the immobilization of HLW and their latest developments. It also highlights some of the essential contributions of professor Rod Ewing (1946–2024) in the areas of radiation damage, natural analogues, and nuclear waste forms. [ABSTRACT FROM AUTHOR]

Multi-principal component transition metal (TM) diborides represent a class of high-entropy ceramics (HECs) that have received considerable interest in recent years owing to their promising properties for extreme environment applications that include thermal/ environmental barriers, hypersonic vehicles, turbine engines, and next-generation nuclear reactors. While the addition of chemical disorder through the random distribution of TM elements on the cation sublattice has offered opportunities to tailor elastic stiffness and hardness, the effects of irradiation-induced structural damage on the physical properties of these complex materials have remained largely unexplored. To this end, changes in the hardness and elastic moduli of a high-entropy TM diboride (Hf0.2Nb0.2Ta0.2Ti0.2Zr0.2)B2 and three of its quaternary subsets following irradiation with 10 MeV gold (Au) ions to fluences of up to 6 × 1015 Au cm−2 are investigated at the micrometer and sub-micrometer length-scales via the dispersion of laser-generated surface acoustic waves (SAW) and nanoindentation, respectively. The nanoindentation measurements show that the TM diborides exhibit an initial increase in hardness following irradiation with energetic Au ions, with a subsequent decrease in hardness following further irradiation. One quaternary composition, (Hf1/3Ta1/3Ti1/3)B2, exhibits a notable exception to the trend and continues to exhibit an increase in hardness with ion irradiation fluence. Although differences in the absolute values of the effective elastic moduli obtained from the measured SAW dispersion and nanoindentation are observed (and attributed to microstructural variations at the measurement length-scale), both techniques yield similar trends in the form of an initial reduction and subsequent saturation in the elastic modulus with increasing ion irradiation fluence. The quaternary TM diboride (Hf1/3Ta1/3Ti1/3)B2 again exhibits a departure from this trend. The high-entropy TM diboride (Hf0.2Nb0.2Ta0.2Ti0.2Zr0.2)B2 exhibits the greatest recovery in hardness and modulus when irradiated to high ion fluences following initial changes at low fluence, indicating superior resistance to radiation-induced damage over its quaternary counterparts. Opportunities for designing HECs with superior hardness and modulus for enhanced radiation resistance (compared to their single constituent counterparts) by tailoring chemical disorder and bond character in the lattice are discussed. [ABSTRACT FROM AUTHOR]