Search

AbstractThe wet desulfurization yields slurry with a moderate temperature and stable supply and thus holds promise for waste heat utilization. However, the corrosive nature and solid particle content of desulfurization slurry from the wet desulfurization process pose potential erosion challenges in waste heat utilization heat exchangers, which is an aspect scarcely explored in the existing literature. The present study aimed to investigate the erosion characteristics in desulfurization slurry heat exchangers using numerical simulation approaches, which can offer crucial insights for practical application in low-grade energy recovery. The result identified slurry mass flow rate and composition as essential factors of erosion distribution. Higher mass flow rates enhance heat transfer efficiency. Still, paradoxically, lower flow rates lead to more pronounced erosion, with a slurry mass flow rate of 35 kg/s resulting in nearly double the erosion compared to the benchmark condition of 56 kg/s. This phenomenon is ascribed to lower fluid velocities in the heat tubes, where the influence of changed velocity diminishes, but slurry exhibits more stable flow at higher mass flow rates. Furthermore, it is also observed that both elevated solids content and particle size lead to an increase in erosion rates. The difference in erosion caused by solid particles with particle sizes in the range of 200–350 µm is marginal. The heat exchanger structure and arrangement also impact fluid flow and erosion. While the difference in fluid flow between vertically and horizontally arranged heat exchangers is negligible, the erosion was significantly reduced to 1/10 in the vertical arrangement. The no-tube-in-window heat exchangers, designed to minimize vibration, exhibit reduced heat transfer capacity alongside diminished and more uniform erosion. The augmentation of tube passes reduces overall erosion but focalizes severe erosion at the slurry inlet, which presents a potential design solution. [ABSTRACT FROM AUTHOR]

The multi-beam echo sounder system can not only obtain high-precision seabed bathymetry data, but also obtain high-resolution seabed backscatter strength data. A number of studies have applied acoustic remote sensing method to classify seabed sediment type with multi-beam backscatter strength data, and obtained better classification results than the traditional sediment sampling method. However, these studies mainly focus on the single type sediment classification or seabed mixed sediment classification using single beam data, not multi-beam echo sounder data. Based on backscatter strength data by a high-frequency (300 kHz) Simrad EM3000 multi-beam echo sounder and seabed sediment sampling data of Jiaozhou Bay in Qingdao, China, we establish the relation model between seabed backscatter strength and sediment type characteristics after data processing and corrections. The purpose of data processing is to diminish or weaken the influence of local bottom slope and near nadir reflection on backscatter strength data. Processed backscatter strength data through corrections and compensations can better characterize the features of the seabed sediments. Applying the back propagation neural network method based on genetic algorithm, we present a fast and accurate seabed classification method in this paper which could identify not just a single type of sediment-like rock, sand but also mixed types of sediment like sand gravel, clayey silt and sand-silt-clay. [ABSTRACT FROM PUBLISHER]

Colloidal gas aphrons (CGAs) are applied in pollutant removal due to their large specific surface area and high surface activity. The structure and properties of the prepared CGAs were investigated in the process of oil removal from oily sludge. The prepared CGAs had a liquid film thickness was 5-10 μm with high stability. CGA interfacial tension was as low as 3.157 mN/m. Then it was found that the oil removal rate of CGAs was higher than that of chemical treatments, showing that CGAs could increase the mass transfer surface area and provide additional attachment sites for pollutants, enhancing the oil removal. The treatment conditions of the oil removal were optimized through response surfaces, showing that under optimal treatment conditions, the oil removal rate of oily sludge reached 96.07%. Additionally, the interaction between surfactant concentration and temperature was the most significant of all of the influencing factors. The behavior and mechanism of CGAs in the cleaning process of oily sludge were further investigated using an inverted fluorescence microscope, SEM, FTIR, and two-dimensional fluorescence spectrometer, showing that pollutants transferred from the liquid film surface of CGAs to the inside the film, and CGAs could specifically adsorb negatively charged organic compounds and aromatic hydrocarbons. The results show that CGAs achieved liquid membrane solubilization. Many negatively charged organic compounds and aromatic hydrocarbons are adsorbed onto the CGAs liquid membrane surface via electrostatic and hydrophobic interactions and then migrated to the hydrophobic layer of the CGAs liquid membrane due to the distribution effect, thus enabling rapid pollutant migration between solid and liquid phases.

A Ag 3 PO 4 /GO/UiO-66-NH 2 (AGU) composite photocatalyst was prepared by an ultrasonic-assisted in situ precipitation method. The optical property, structure, composition, and morphology of photocatalysts were investigated using UV-vis diffuse reflectance spectroscopy, photoluminescence spectroscopy, electrochemical impedance spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, energy-dispersive spectrometry, transmission electron microscopy, Fourier transform infrared spectroscopy, and charge flow tracking by photodeposition of Pt and PbO 2 nanoparticles. In comparison with Ag 3 PO 4 and Ag 3 PO 4 /UiO-66-NH 2 (AU), the AGU composite photocatalyst showed heightened photocatalytic performance for the degradation of levofloxacin hydrochloride (LVF). The AGU photocatalyst (dosage: 0.8 g/L) with 1% mass content of graphene oxide (GO), the mass ratio of Ag 3 PO 4 and UiO-66-NH 2 (U66N) reached 2:1, showed the highest photodegradation rate of 94.97% for 25 mg/L LVF after 60 min of visible light irradiation at pH = 6. The formation of a heterojunction and the addition of GO synergistically promote faster separation of electron-hole pairs, retain more active substances, and enhance the performance of the photocatalyst. Furthermore, the mechanism of the Z-scheme of the AGU composite photocatalytic is proposed.