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Shelf mud is an important sink for fluvial sediment, and it is sensitive to variations in river discharge and ocean circulation, which are significantly influenced by climate change. However, the evolution of shelf mud in response to climate change during the Holocene is poorly understood. Here, we present high‐resolution sedimentary records of heavy minerals and mass accumulation rates (MARs) from the East China Sea shelf to study the response mechanisms of the Holocene shelf mud supply, transport, and sedimentation to the climate‐driven variations in fluvial discharge and ocean currents. The results indicate that the shelf mud primarily originates from the Changjiang (Yangtze) River and has been mainly transported by wind‐driven longshore currents in suspension since approximately 8.0 ka. A comparison of the MARs with several shelf mud sedimentation‐rate records and climate changes during the Holocene on millennial timescales showed that strong (weak) precipitation in the river basin, which is positively linked with Asian summer monsoon and El Niño‐driven storms, could intensify (weaken) the fluvial sediment supply, thereby increasing (decreasing) the shelf mud deposition flux. On multicentennial timescales, changes in the relative intensities of different ocean currents due to climate oscillations during the Holocene could generate frequent migrations of the current shear front (a hydrodynamic barrier), which has trapped an abundance of suspended materials on the shoreward side and resulted in rapid mud sedimentation (~2.3 g/cm2/year) at different sites during different periods. Therefore, our study highlights that the Holocene shelf mud evolution responds sensitively to climate changes on different timescales. Key Points: The Changjiang River mud has been mainly carried southward by wind‐driven longshore currents since 8.0 kaHolocene shelf mud supply is modulated by precipitation from summer monsoons and El Niño‐related stormsHolocene rapid shelf mud sedimentation is directly linked with climate‐driven migrations of ocean currents [ABSTRACT FROM AUTHOR]

Human–environment interactions across historical periods in China have been well reconstructed over the past decade; however, few studies have focused on southern China, particularly Hainan Island. This study investigated two sediment cores (cores X1 and X2) collected from the continental shelf off Hainan Island in the northern South China Sea. Combined with geochemical compositions (Al, Ni, Cu, Zn, Cd, and Pb), Sr-Nd isotopes, grain size, and AMS 14C ages, our results showed that Cd and Cu in core X1 and Cd and Pb in core X2 have been mainly influenced by anthropogenic activities since ~4.0 kyr BP. The enrichment factors showed obvious increases starting at ~4.0 kyr BP and were in good accordance with the appearance of abundant archeological sites on Hainan Island. Significant climatic changes (i.e. decreases in the East Asian summer monsoon and increases in El Niño–Southern Oscillation activities) at ~4.0 kyr BP likely promoted more intense, localized human activities, which in turn enhanced heavy metal accumulation in the continental shelf sediments. These results provide new insights into the history of human activities on Hainan Island and indicate that the geochemical compositions of continental shelf sediments have the potential for broadening our knowledge of the human activities and cultural development in tropical areas. [ABSTRACT FROM AUTHOR]

The heavy metals in surface sediments of the continental shelf of the South Yellow Sea (SYS) and the East China Sea (ECS) collected in 2016 were analyzed to assess the heavy metal distributions, contamination status, and likely sources. The metal concentrations generally met the China Marine Sediment Quality criteria. However, the enrichment factor and geoaccumulation index values clearly showed elevated Cd and Pb concentrations in the region. Cd and Pb contamination occurred mostly to the southwest of the Changjiang River mouth and to the east of the Shandong Peninsula because of rapid economic and industrial development. The results are likely to be useful for authorities responsible for sustainable coastal zone management. [ABSTRACT FROM AUTHOR]

Selected trace elements (As, Cr, Zn, Cu, Cd, Co, Pb and Ni) in 76 surface sediment samples collected from the rivers and the intertidal zone of Jiaozhou Bay (JZB) were evaluated to assess their environmental background values in the JZB catchment. Overall, the sediment quality in the area meets the China Marine Sediment Quality criteria. The background values (ranges) of the elements As, Cr, Zn, Cu, Cd, Co, Pb and Ni were, respectively, 8.28 (4.10–12.46), 67.96 (38.40–97.52), 56.80 (16.42–196.51), 19.13 (5.71–64.06), 0.10 (0.02–0.42), 6.51 (2.08–20.40), 17.97 (12.26–55.84) and 20.69 (10.43–30.95) mg/kg. The background values of most of the trace elements were lower than those in Chinese soil, the upper continental crust, global shales and global preindustrial sediments. The results may assist in defining future coastal and river management measures specifically targeted at monitoring trace element contamination in the JZB catchment. [ABSTRACT FROM AUTHOR]

The late Quaternary paleoceanography and paleoenvironment of the South China Sea (SCS) have been well reconstructed over the last decade. In contrast, the provenance of the terrigenous sediments that have accumulated in the northwestern continental shelf mud area remains enigmatic. This study investigated the provenance of these sediments and the paleoenvironmental changes archived in Core X2 via the analysis of geochemical elements, grain size, and accelerator mass spectrometry (AMS) 14 C ages. Based on the upper continental crust (UCC)-normalized REE patterns and REE fractionation parameters, southwestern and western Taiwanese rivers and the Pearl River were identified as the main sources of the fine-grained sediment deposited in the northwestern shelf mud area off Hainan Island. This finding further confirms the long-distance transport (> 1000 km) of fine-grained sediment from Taiwanese rivers to the northern SCS shelf and slope. Obvious changes in the grain size and Chemical Index of Alteration (CIA) record occurred at approximately 4.0 cal kyr BP and were likely caused by increased Hainan Island inputs due to sea level changes. [ABSTRACT FROM AUTHOR]

Selected heavy metals (Cu, Pb, Zn, Cr, Cd, and As) in 47 river sediment samples collected in the Jiaozhou Bay (JZB) catchment were evaluated to assess their spatial distributions and the potential ecological risks. The heavy metal concentrations in the sediments ranged from 4.5–178.7 mg kg − 1 for Cu, 8.2–65.8 mg kg − 1 for Pb, 8.2–325.7 mg kg − 1 for Zn, 12.2–185.5 mg kg − 1 for Cr, 0.013–1.486 mg kg − 1 for Cd, and 1.2–20.6 mg kg − 1 for As. The results showed that the overall sediment quality in the area generally met the China Marine Sediment Quality criteria. Based on the effect-range classification (the threshold effect level (TEL)/probable effect level (PEL) Sediment Quality Guidelines, Cu, Cr, and As were likely to have adverse biological impacts on local aquatic ecosystems. The geoaccumulation index (I geo ), enrichment factor (EF), contamination factor (CF), and pollution load index (PLI) values suggested that elevated levels of Cd, As, and Pb contamination occurred in the eastern JZB catchment (i.e., Hongjiang River, Moshui River, Baisha River, Loushan River, Licun River, and Haipo River). This study presents the current state of the sediment quality in the JZB catchment. The results may assist in the definition of future coastal and river management measures specifically targeted at monitoring heavy metal contamination. [ABSTRACT FROM AUTHOR]

The concentrations of seven heavy metals (Cr, Ni, Cu, Zn, As, Cd, and Pb) in the surface sediments of the northern portion of the South China Sea (SCS) shelf collected between 2012 and 2014 were measured to assess the potential contamination levels and determine the environmental risks that are associated with heavy metals in the area. The measured concentrations in the sediments were 12.4-72.5 mg kg for Cr, 4.4-29.2 mg kg for Ni, 7.1-38.1 mg kg for Cu, 19.3-92.5 mg kg for Zn, 1.3-12.1 mg kg for As, 0.03-0.24 mg kg for Cd, and 8.5-24.4 mg kg for Pb. These results indicate that the heavy metal concentrations in the sediments generally meet the China Marine Sediment Quality criteria and suggest that the overall sediment quality of the northern portion of the SCS shelf has not been significantly impacted by heavy metal pollution. However, the enrichment factor (EF) and geoaccumulation index ( I) clearly show that elevated concentrations of Cd occur in the region. A Pearson's correlation analysis was performed, and the results suggest that Cr, Ni, Cu, and Zn have a natural origin; Cd is primarily sourced from anthropogenic activities, with partial lithogenic components, and As and Pb may be affected by factors such as varying input sources or pathways (i.e., coal burning activities and aerosol precipitation). Heavy metal contamination mostly occurred to the east of Hainan Island, mainly because of the rapid economic and social developments in the Hainan Island. The results of this study will be useful for marine environment managers for the remediation of pollution sources. [ABSTRACT FROM AUTHOR]

The major (Al) and trace metal (Cu, Pb, Zn, Cr, Cd, and As) concentrations in 29 surface sediment samples from the intertidal Jiaozhou Bay (JZB) are evaluated to assess the contamination level. The results show that the overall sediment quality in the area has been obviously impacted by trace metal contamination. The geoaccumulation index and the enrichment factor values indicate that no Cr or Cu contamination has occurred on the whole, only a few stations have been polluted by As, and some areas have been polluted by Cd, Pb, and Zn. Principal component analysis suggests that the Cu, Pb, Zn, and Cd are derived from anthropogenic inputs and that Cr, As, Cu, and Zn are influenced by natural weathering processes. Cu and Zn may originate from both natural and anthropogenic sources. The contamination in the northeastern JZB is higher than that in other areas of the bay. [ABSTRACT FROM AUTHOR]

Major (Al) and trace metal (Cu, Pb, Zn, Cr, Ni, Cd, and As) concentrations in 29 surface sediment samples from the eastern continental shelf of Hainan Island were evaluated to determine the level of contamination. A multivariate analysis indicated that the sources of Cd, As, and Pb were primarily anthropogenic, whereas the sources of Cu, Zn, Cr, and Ni were primarily natural and/or partially anthropogenic. Enrichment factor (EF) and geoaccumulation index ( I geo ) values were calculated to assess the anthropogenic contamination in the region. Both the EF and I geo values indicated relatively elevated Cd and As concentrations. This study provides a useful aid for sustainable marine management in the region. [ABSTRACT FROM AUTHOR]

To obtain the historical changes of pyrogenic sources, integrated source apportionment methods, which include PAH compositions, diagnostic ratios (DRs), Pb isotopic ratios, and positive matrix factorization (PMF) model, were developed and applied in sediments of the northern South China Sea. These methods provided a gradually clear picture of energy structural change. Spatially, Σ 15 PAH (11.3 to 95.5 ng/g) and Pb (10.2 to 74.6 μg/g) generally exhibited decreasing concentration gradient offshore; while the highest levels of PAHs and Pb were observed near the southern Taiwan Strait, which may be induced by accumulation of different fluvial input. Historical records of pollutants followed closely with the economic development of China, with fast growth of Σ 15 PAH and Pb occurring since the 1980s and 1990s, respectively. The phasing-out of leaded gasoline in China was captured with a sharp decrease of Pb after the mid-1990s. PAHs and Pb correlated well with TOC and clay content for core sediments, which was not observed for surface sediments. There was an up-core increase of high molecular PAH proportions. Coal and biomass burning were then qualitatively identified as the major sources of PAHs with DRs. Furthermore, shift toward less radiogenic signatures of Pb isotopic ratios after 1900 revealed the start and growing importance of industrial sources. Finally, a greater separation and quantification of various input was achieved by a three-factor PMF model, which made it clear that biomass burning, coal combustion, and vehicle emissions accounted for 40 ± 20%, 41 ± 13%, and 19 ± 12% of PAHs through the core. Biomass and coal combustion acted as major sources before 2000, while contributions from vehicle emission soared thereafter. The integrated multi-methodologies here improved the source apportionment by reducing biases with a step-down and cross-validation perspective, which could be similarly applied to other aquatic systems. [ABSTRACT FROM AUTHOR]

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Riverine sediment samples from Hainan Island were collected in 2013 to assess the heavy metal pollution levels, sources, and associated environmental risks. The concentrations of Cr, Ni, Cu, Zn, As, Cd, and Pb measured in this study were 31.6-128.8 mg kg -1 , 9.8-70.3 mg kg -1 , 18.3-210.8 mg kg -1 , 49.3-314.2 mg kg -1 , 2.3-69.2 mg kg -1 , 0.3-1.5 mg kg -1 , and 23.2-113.4 mg kg -1 , respectively. The results indicate that the sediment quality of Hainan Island has been obviously influenced by heavy metals. Based on the effect range classification, the heavy metals in Hainan riverine sediments likely have adverse biological effects on local ecosystems. The enrichment factor (EF), geoaccumulation index (I geo ), contamination factor (CF), and pollution load index (PLI) clearly reflect significant metal pollution in this region. The most significant pollution was observed in the northern and eastern parts of Hainan Island. The pollution levels of the three largest rivers on Hainan Island (i.e., the Nandu, Changhua, and Wanquan Rivers) were notably high. The results of this research will be useful in assessing and managing environmental pollution in this region. In the future, greater attention and further investigation should focus on the metal sources linked to further economic development on Hainan Island.

Selected trace elements (As, Cr, Zn, Cu, Cd, Co, Pb and Ni) in 76 surface sediment samples collected from the rivers and the intertidal zone of Jiaozhou Bay (JZB) were evaluated to assess their environmental background values in the JZB catchment. Overall, the sediment quality in the area meets the China Marine Sediment Quality criteria. The background values (ranges) of the elements As, Cr, Zn, Cu, Cd, Co, Pb and Ni were, respectively, 8.28 (4.10-12.46), 67.96 (38.40-97.52), 56.80 (16.42-196.51), 19.13 (5.71-64.06), 0.10 (0.02-0.42), 6.51 (2.08-20.40), 17.97 (12.26-55.84) and 20.69 (10.43-30.95)mg/kg. The background values of most of the trace elements were lower than those in Chinese soil, the upper continental crust, global shales and global preindustrial sediments. The results may assist in defining future coastal and river management measures specifically targeted at monitoring trace element contamination in the JZB catchment., (Copyright © 2017 Elsevier Ltd. All rights reserved.)