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Start Over Descriptor "Trimethylsilyl" Language portuguese
1 results on '"Trimethylsilyl"'

1. O ressurgimento da química de benzino com sililaril triflatos no contexto das reações de inserção em ligações sigma

Author

Rafael D. C. Gallo, Rozanna Marques Muzzi, Hellenicy V. Rezende, and Cristiano Raminelli

Subjects
Trimethylsilyl, Stereochemistry, Aryl, silylaryl triflates, General Chemistry, Aryne, Medicinal chemistry, benzyne, chemistry.chemical_compound, chemistry, Nucleophile, Electrophile, insertion reactions, Sigma bond, Fluoride
Abstract

In this paper we gathered articles concerning insertion reactions of arynes, exclusively generated from 2-(trimethylsilyl)aryl triflates in the presence of fluoride ions, in substrates bearing nucleophilic and electrophilic portions separated by sigma bonds. Accordingly, we stand out the great importance and versatility of such transformations in the preparation of highly functionalized aromatic systems, which are hardly synthesized in just one step for other methods.

Published
2009

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