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In order to evaluate the chemical composition of natural background environments of Pur-Taz interfluve (Western Siberia), the mineral components of soils, peats, lichens, and sphagnum mosses have been analyzed. The samples were tested using X-ray fluorescence technology. The average contents of hazardous metals in the soils of the Pur-Taz interfluve are either lower (for Cu, Pb, Zn, Ni, Sr) or equal to (for Hg, Co) the average values of these elements in the Earth's crust. This finding corresponds to the commonly held view that the contents of elements in the soils located in the north of Western Siberia are lower than the world averages. Additionally, in our samples low concentrations of copper and zinc have been observed. Since these microelements are important for soil physiology, this finding indicates unfavorable biochemical conditions in the research area. On the other hand, high concentrations are observed for inactive elements such as Mo, Sn and Zr. The significant differences have been identified in the composition of mineral and organic soil horizons. For instance, the average concentrations of P, Zn and S in organic horizons are 7.1, 8.1 and 18 times greater than in the illuvial mineral horizons, respectively. The intense accumulation of Zn, Cu, Cd, Hg has been recorded, all of them are chalcophiles in the ombrotrophic peat. This means that the chemical composition of soil is largely determined by biological accumulation of chalcophile elements. The content of lithophilic Al, Si, Ti and Zr, coming with dust precipitation from the atmosphere increases in the peat of dwarf shrub-moss-lichen tundras and larch woodlands. The revealed values of the elemental composition of soils can be recommended as background in the course of the environmental monitoring.