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The paper presents the results of the study of rock samples from Bazhenov deposits before and after laboratory modelling of hydrothermal processes in autoclaves. To evaluate the influence of hydrothermal influence on rocks of different degrees of transformation, 3 samples from the well, the rocks in which are located at the very beginning of the main zone of oil formation (PK3–MK1), and 4 samples from the well, the rocks in which are located in the middle of generation (MK2–MK3) were studied. Comparison of samples before and after heating was carried out by means of pyrolytic, coal petrography studies and analyses of polished section under scanning electron microscope. It is shown that at 350 °C there is a change in pyrolytic characteristics of the rock, which depends on the nature of organic matter and the degree of catagenetic transformation of kerogen at the time of exposure. It was found that as a result of exposure the initial macerals decrease in size and change their luminescence in ultraviolet light, secondary (kerogenic) porosity appears in onychite fragments. New minerals, in particular barium zeolites, are formed in the rocks. Identification of such formations in natural objects may indicate the occurrence of local temperature processes, which may lead to heterogeneity of organic matter transformation in Bazhenov sediments and should be taken into account to identify local zones of increased catagenesis.

Сatagenetic transformations of asphaltenes of organic matter (OM) from recent sediments and fossil rocks were studied on rocks sampled from different sedimentary basins (Timan-Pechora, Mezen, West Siberian, Kuznetsk, Aldan-Maya and Middle Amur) of Russia. Changes in the elemental composition of asphaltenes were analyzed with the Veselovsky’s model of the formation of major groups of fossil fuels using cO parameter (cO = (O/8 – N)/(C/3)) as compared with the total carbon based on elemental analysis. Just as the Van-Krevelen diagram, the plot built in C–cO coordinates for OM of various genetic forms demonstrates a significant difference in the asphaltenes composition evolution during catagenesis. At the same time, the cO parameter has notably increased in asphaltenes of both types of OM. Structural transformations of asphaltenes during catagenesis were identified in the course of high-resolution NMR (nuclear magnetic resonance) spectroscopy. The research results comprise data on carbon distributions in the aromatic and aliphatic groups in the investigated asphaltenes of different type OM of sediments and rocks at different stages of lithogenesis. A correlation between the asphaltene composition and structural parameters depending on thermocatalytic transformations is revealed. The asphaltenes of terrestrial organic matter are distinguished by higher cO values and different carbon yields of aromatics (higher) and aliphatics (lower) throughout the catagenesis phase. The highly transformed marine OM is marked by surge condensation of aromatic rings in asphaltenes, which makes them similar to asphaltenes of the terrestrial type OM.

The evolution of the elemental composition of dispersed organic matter (DOM) heterocyclic components during catagenesis was traced via studying samples from the Tyumen (SG-6) and Srednevylyuy-27 (SV-27) super-deep wells of Siberia. During mesocatagenesis, the composition of terrigenous DOM asphaltenes and resins undergoes directed changes: a decrease in hydrogen and oxygen content, enrichment with carbon, and graphitization of the structure. During apocatagenesis, due to high-temperature destruction, on the one hand, there is a condensation of individual blocks of asphaltenes and their transition to an insoluble form (formation of epiasphaltenic kerogens – EPAK). On the other hand, the lighter part of the asphaltenes goes into the formation of hydrocarbons and gas formation – a relative increase in the concentration of the former in % by mass of residual bitumoids is noted, as well as structural redistributions within benzene and spirit-benzene resins. In all studied parameters of the elemental composition, a symmetrical (unidirectional) transformation of resinous and asphaltene components of bitumoids from the SG-6 and SV-27 wells under harsh thermobaric conditions is noted. The obtained results should be taken into account when predicting new oil and gas accumulation zones in deep-laid horizons.

The article considers the elements of organic geochemistry in the regional aspect, which aims to separate quantitative prediction of oil and gas content of regions. The principles and results of balance calculations of generation and emission of liquid and gaseous hydrocarbons for different faciesgenetic types of organic matter and methods for calculating the scale of hydrocarbon emission are considered. Finally, a list of the main regularities of organic geochemistry is given.

A model of the activity of hydrothermal-metasomatic systems confined to certain structural elements is proposed in the present article. The model is based on the analysis of a large volume of traditional studies: measurements of porosity coefficients, permeability, pyrolytic measurements - together with specific measurements: isotopic composition of carbonate rocks, temperature of homogenization of gas-liquid inclusions, studies of the composition of rocks with a scanning electron microscope, a description of petrographic thin sections. The model allows to generalize the results of the impact of hydrothermal-metasomatic systems on the reservoir properties of the rocks of the BazhenovAbalak complex: constructive – leaching processes and increasing reservoir properties, and destructive – massive mineral formation that fills the pore space, up to the formation of secondary seals.

Studies have been carried out to assess the qualitative features of fluids, aimed at identifying the regularities in the differentiation of the properties of naphthides during the formation of hydrocarbon deposits outside anticlinal structures. Due to the exhaustion of hydrocarbon reserves associated with anticlinal traps, the main attention is paid to the composition of fluids confined specifically to non-anticlinal structures – to traps of a combined structure. Physicochemical properties, trace element (TE) composition, phase states of naphthides in deposits affected by hypergenetic or catagenetic processes have been analyzed using specific examples; in regions with a possible additional inflow of hydrocarbons (Romashkino group of fields in the Republic of Tatarstan); in the crystalline basement of sedimentary basins. The results of the analysis make it possible to predict the characteristic features of fluids in traps of various types at certain levels of the processes of oil formation, secondary transformation and destruction of accumulations, mainly due to the tectonic regime of the sedimentary basin. With prolonged lateral migration, at great depths with good isolation from surface weathering agents, light oils, depleted in TE, more often of nickel specialization, are found in lithologically and stratigraphically screened traps, and gas condensate accumulations are possible. At shallow depths with poor regional or local seals, heavy, highly viscous hypergene-transformed oils, natural bitumens with high concentrations of industrially significant metals V, Ni, Co, Mo Cd, U were found in traps of pinch-out zones and various types of trap screening. tectonically-screened traps) with a multiphase filling of traps and, at the same time, the influence and inflow of deep ones, i.e. more catagenically transformed fluids, it is possible to detect light oils of the nickel type or gas condensates enriched with elements of “magmatic emanations” – As, Hg, Al, B, rare earth elements. Oils filling combined traps in the crystalline basement within platform oil and gas basins, as a rule, do not differ in their compositional peculiarities in comparison with oils in overlying or adjacent parts of the sedimentary section.

Silurian source rocks are among the least studied in the Timan-Pechora basin. This is mainly due to their occurrence at great depths (3.0–4.5 km) and the limited penetration of this stratigraphic interval by wells. Another source of information is the outcrops of the Silurian, which are known in the eastern and northeastern parts of the Timan-Pechora basin. The studied section of the Silurian deposits is exposed on the Padimeityvis River, located on the Chernov swell in the northeastern part of the basin. This article is devoted to the study of Silurian source rocks based on the results of lithological, coal petrographic studies and geochemistry of organic matter. The studied section is composed of carbonate and clay-carbonate deposits formed in shallow-water shelf conditions. Most of the section, composed of microcrystalline and microcrystalline with bioclasts limestones, is characterized by low concentrations of organic matter (Corg is generally less than 0.3 %). Elevated Corg contents (up to 1.16 %) are characteristic of clay-carbonate rock varieties, which make up about 20 % of the section. Sediments with increased concentrations of organic matter were formed in isolated and deepened areas of the bottom of the shallow-water basin as a whole. Assessment of the catagenetic transformation based on Rock-Eval pyrolysis data, coal petrographic studies, and conodont color indices showed that organic matter reached the conditions of the middle-end of the main oil generation zone (gradation MC2‑MC3). The obtained geochemical characteristics (Corg, S2, HI), taking into account a certain level of organic matter maturity, indicate that the Silurian source rocks had an average hydrocarbon potential.

The relevance of the research is caused by the need to expand the resource base in the fields of the Baykit anteclise. Occurrence of two types of oils may be caused by additional source, which increases the prospects of the area. However, variations in the composition of oils may also be associated with high catagenesis and migration effects; therefore, an assessment of the influence of these factors on composition of oils is necessary. The aim of research is to determine the influence of genetic, catagenetic and migration factors on biomarker hydrocarbons in the oils of the Baykit anteclise, to identify areas of preferential influence of each of them. Objects of the research are the oils of the Baykit anteclise. Methods: comparison of the characteristics of biomarker hydrocarbons obtained using gas chromarography-mass spectrometry in saturated and aromatic fractions of oils, assessment of the impact on their composition of the contribution from different source formations, catagenesis and migration, grouping of oils by the predominance of the influence of these factors. Results. The author has characterized biomarker hydrocarbons of saturated and aromatic fractions of the oils from Riphean and Vendian collectors of the Baykit anteclise. Based on the characteristics, which differ from the previously obtained characteristics of the most common and typical ancient oils of the Siberian platform, the author made a conclusion on the impact of the contribution from the Upper Riphean Iremekensky stratum in two oils in the east of the Kuyumbinskoye field, as well as the contribution of probably Vendian oil source formations in oils from Vendian collectors. The main factor in the formation of the composition of most oils of the Kuyumbinskoe field was high catagenesis, enhanced by migration effects towards the enrichment of low molecular weight compounds. Probably, several oils are a mixture of two components with different catagenesis, moreover, more transformed component is enriched with saturated, including cyclic compounds, and less transformed – with aromatic compounds.

A combination of geochemical methods were used to study organic matter from Permian rocks in the central part of the Vilyui syneclise (East Siberia) penetrated by the Srednevilyuiskaya-27 ultra-deep well in the depth range of 3370-6458 m. This study discusses variations in the pyrolysis indices (HI, Tmax), hydrocarbon type content (hydrocarbons-resins-asphaltenes), vitrinite reflectance (R0vt, %), organic carbon content (Corg), as well as some trends in the saturated and aromatic hydrocarbon compositions of bitumen extracts from the Upper Paleozoic rocks. Below a depth of about 4.5 km (late mesocatagenesis), the hydrocarbon type composition is characterized by a sharp decrease in the content of asphaltenes from < 30 % (at 4.5-5.0 km) to < 15 % (at 5.0-5.5 km), which are not detected at greater depth. In turn, the resins became the dominant constituent (~ 50-70 %), whereas hydrocarbons account for < 20 % at depths down to 5 km and < 40 % at greater depth. These depths are also characterized by a predominance of saturated hydrocarbons over aromatic compounds with a decrease in the relative contents of high molecular weight compounds in both fractions, as indicated by mass chromatograms. The hydrocarbon index (HI) of organic matter decreases to the first tens from the depth of 4.9 km and to the bottomhole (6519 m); the temperature of the maximum hydrocarbon yield (Tmax) varies between 570-580 °C, showing a slightly increasing trend. Our results show that the generative potential of organic matter from the rocks within the studied depth range (4.9-6.5 km) has been exhausted and that the terrestrial organic matter undergoes significant changes under severe temperature and pressure conditions at great depths.

Оbject. The article presents the results of studies of secondary mineral formation in the lower Cretaceous sediments of the Bolshekhetskaya depression, which contain highly promising oil and gas deposits, with established industrial performance at Pyakyakhinskoye, Khalmerpayutinskoye and South-Messoyakhskoye fields. The objects under consideration are located in the most submerged part of the Nadym-Taz syneclise in the zone, where the Taz and Urengoy facies regions meet.Materials and methods. Main types of postsedimentary changes of reservoir rocks selected on the basis of study of core material Pokurskaya, Angelovskaya, Sortymskaya and Megionskaya fms. Petrography and Mineralogy of the rocks under consideration were studied on the basis of stage analysis using optical and electron microscopy, and X-ray diffraction study at the Center of core and reservoir fluids research of “LUKOIL-Engineering’s KogalymNIPIneft branch In Tyumen” (Kogalym). Determination of the mineral type of zeolite was performed by X-ray phase analysis at the Institute of Geology and Geochemistry UrO RAS (Ekaterinburg).Resuts. It was found that for rocks Pokurskaya, Angelovskaya, Sortymskaya and Megionskaya fms characteristic a diverse range of secondary minerals and structures, evidence of the background stage catagenesis and the superimposed processes. The most important among them is the regeneration of quartz, the transformation of feldspar, violation of the crystal structure of biotite, the formation of various clay minerals, crystallization of zeolites and calcite.Conclusions. Studies show that the upper part of the section of the lower Cretaceous deposits of Bolshekhetskaya depression corresponds to the area of the middle catagenesis (gradation MK2), the bottom – changed to the stage of deep catagenesis (gradation MK3). In this case, the epigenetic process proceeded unevenly, pulsation, due to changing tectonic conditions. Particular attention is paid to the origin of zeolites, which is still debatable. It is assumed that their formation is associated with the transformation of “camouflage pyroclastic” in particular, feldspar clastics.

The petrographic, lithogeochemical and U-Pb (LA-ICP-MS) geochronological studies were carried out to investigate the terrigenous rocks sampled from the lower part of the Ipsit suite of the Karagass series (Sayan segment of the Sayan-Baikal-Patom belt). These rocks include sandstones, aleurite sandstones and aleurolites, and their mineral compositions are close to that of arkose. Most of the studied rock samples show petrographic features typical of the epigenetic changes at the stage of catagenesis: regeneration of quartz clastic grains, pelitization of potassium-feldspar clastic grains, occurrence of clay-hydromica aggregate, sericitization of plagioclase, chloritization of biotite, and silicification of dolomite pieces, and occurrence of authigenous tourmaline. The above was confirmed by the analysis of the concentrations of petrogenic elements in the studied rocks from the lower part of the Ipsit suite. The analysis results show that the concentrations of K2O are elevated, while the concentrations of Na2O are relatively very low, which may be due to the redistribution of these elements during epigenetic transformations. According to the classification by genetic types on the basis of the system of petrochemical modules, the rocks of the lower part of the Ipsa suite are of the petrogenic nature. The acidic igneous rocks are dominant in the source area, as evidenced by the presence of granitoid and quartzite fragments in the clastogenic component, as well as the set of accessory minerals typical of the igneous rocks of the acidic composition, and the distribution pattern of rare and trace elements. According to the U-Pb (LA-ICP-MS) dating of detrital zircons from the aleurite sandstone sampled from the lower part of the Ipsit suite, the zircons are exclusively of the Archean-Early Proterozoic ages. Such ages correlate with the age of the granitoids of the Sayan complex and the felsic volcanites from the Maltsev layer of the Elash series (Biryusa block). Furthermore, the detrital-zircon age spectra of the aleurite sandstone of the lower part of the Ipsit suite are identical to the detrital-zircon age spectra of the terrigenous rocks from the underlying strata of the Shangulezh and Tagul suites of the Karagass series. This study suggests that sedimentation of the Ipsit suite of the Karagass series took place due to the influx of detrital material from the southern part of the Siberian craton into the sedimentation basin, and the acidic igneous rocks of the Biryusa block were one of the main sources of detrital material.

The paper is devoted to modeling of the processes of oil and gas deposits formation of the Vuktyl thrust development area, to which the largest in the Timan-Pechora oil and gas province is associated with the same oil and gas condensate deposit. Oil and gas of deeply buried formations of the autochthon of the overthrust region remains poorly studied. Therefore, application of modern methods of basin modeling is relevant for oil and gas content estimation. In order to simulate the section, Schlumberger PetroMod software package was used. The package allows to determine the history of generation of hydrocarbons on the geological time scale, migration paths, amount and type of oil and gas accumulations in both surface and reservoir conditions. Using the 1D and 2D modeling of the Vuktylskaya-58 parametric well and the overthrust region models were obtained. The models reflect the modern geological section, its evolution during the geological time. The processes of formation of oil and gas were studied. As a result, it was shown that the parent rocks of the allochthonous section part could not participate in the formation of the main gas-condensate deposit of the Vuktyl deposit because they entered only the main oil formation zone. In deeply buried deposits of the autochthon starting from the Permian and Triassic formation of the Vuktylsky gas-condensate field and possibly the deposits in poorly studied deep formations could be caused by processes of generation of gases and gas condensates. That is proved by the discovery of a large number of gas emergences beyond the 4-5 km in a section of the only well drilled beyond the 6 km such as Vuktylskaya-58. Generation and accumulation of gas hydrocarbons occurred mainly after the appearance of thrust dislocations, when the main traps were formed both at ordinary and high depths.

Fossil resins and amber are a product of lithogenesis of resinous substances of higher plants – resinite. These components of plants, like other lipoid ingredients (suberins, coutines, sporinins, natural rubbers) are resistant to microbial action, so they are well preserved in bacterial processing of organic matter in the stages of sedimento- and diagenesis, and are well diagnosed in microscopic studies. They occur in a rather wide age range of sedimentary rocks. The amber of the Baltic region of the Eocene age is most fully studied. The article presents the results of a study of the collection of fossil resins and amber from various regions of the world. Samples were studied microscopically; carbon isotope analysis, infrared spectroscopy (IR spectroscopy) were performed. The most informative analysis of high-molecular polymeric compounds is IR spectroscopy. It was found that in the analyzed samples of fossil resins of different ages, aromatic compounds are not observed, most of which are first volatilized in fossilization processes. The possibility of influencing the group composition of amber and amber-like resins for sedimentation, diagenesis and catagenesis is discussed. The IR spectra of fossil and modern resin conifers are compared. Using the IR spectroscopy method, an attempt was made to identify the botanical origin of fossil resins.

New results of research of sulfur from rocks and organic matter (OM) for the Kuonamka complex of the Lower and Middle Cambrian in the eastern Siberian platform have been demonstrated. It has been shown that in the rocks enriched in organic matter the amount of organic carbon controls not only the total content of sulfur and sulfide sulfur, but also the content of sulphate sulfur. It has been revealed that the sulfur content in bitumen extracts of Cambrian black shales in the northeastern Siberian platform decreases with increasing carbon and hydrogen. It was hypothesized that during diagenesis the introduction of sulfur in the OM structure led to dehydrogenation and decarboxylation. The intensity of these processes is associated neither with the mineral composition of the sediment nor with its enrichment in OM. The paper discusses the structure and patterns of distribution of OM sulfur compounds in the rocks of the Kuonamka complex in the sections of the northern and southeastern Siberian platform.