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In this work, the new compound [HNC5H4B(OH)2–3]2[Pt(CN)4] was synthesized and its crystal structure was characterized by the single crystal X-ray diffraction method. Crystal structure analysis showed in the orthorhombic crystal system of the compound, in the Cmca space group and a= 6.4372(13) Å, b = 14.769(3) Å, c = 19.045(4) Å, α = β = γ = 90°, V = 1810.6(6) ų, Z = 4 crystallization. In the crystalline structure of the compound, [Pt(CN)4]2– anion and [HNC5H4B(OH)2–3]2+ cation interact with N–H⋯NCPt– and strong B(OH)⋯NCPt– hydrogen bonds. Thus, the structure grows in a one-dimension chain structure. A two-dimensional network is formed in the bc plane with the cation molecules directed alternately above and below the glide plane. In addition, hydrogen bond interactions O–H⋯N, C–H⋯O, C–H⋯N and N–H⋯N also hold molecules together. Thus, a three-dimensional packed structure is formed. These hydrogen bond interactions provide the formation of a threedimensional crystal structure and the stability of the lattice structure. [ABSTRACT FROM AUTHOR]

In this study, the new 2D organic compound [PSA2][BPP2] (psa=phenol-4-sulfonic acid, bpp=1,3-Bis(4-pyridyl)propane was hydrothermally synthesized and characterized by single-crystal Xray diffraction, powder X-ray diffraction (PXRD), elemental analysis, and solid-state UV-vis absorption spectra. The crystal structure analysis of the compound indicates that complex crystallizes in the orthorhombic crystal system Pca21 space group and its asymmetric unit consists of two discrete psa and bpp ligand. The ring of phenol and pyridyl groups is almost planar. Additionally, crystal structure of the compound is linked via intermolecular O - H...O and C - H...O hydrogen bonds as well as intramolecular C-H...π and between the bpp molecules π - π interactions, which form two-dimensional structure and provide structural stability. [ABSTRACT FROM AUTHOR]