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There are extensive range of applications related to nuclear industry, industrial manufacturing, science and engineering processing, in which the boundary layer hydromagnetic motion of Casson liquids perform vital role. Casson liquid is a useful liquid in the nuclear industry for optimizing the design and operation of nuclear reactors. Researchers have investigated transfer of heat in liquid motions with linear stratification, which is a phenomenon where the temperature varies linearly with height, affecting various fields such as medical equipment, glass fiber production, electronic devices, polymer sheets, paper production, filaments, and medicine. However, the most discussion of heat transfer problems is to get numerical solutions of a comprehensive Casson liquid model with heat generation described by the BVP4 via shooting method. In this study, a new velocity slip boundary condition is applied at the stretching or shrinking surface. These conditions are grounded in the previously established Buongiorno model, providing a more practical and realistic approach compared to previous study. The time independent Gov. Eqs. changed into a set of couple non-linear ODEs with help of suitable similarity conversions. The equations are evaluating via R-K-F by help of MATLAB software programming.