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2. Iron- and Cobalt-Catalyzed Synthesis of Carbene Phosphinidenes

Author

Pal, Kuntal, Hemming, Oliver B, Day, Benjamin M, Pugh, Thomas, Evans, David J, and Layfield, Richard

Subjects
010405 organic chemistry, QD, General Medicine, 010402 general chemistry, 01 natural sciences, 3. Good health, 0104 chemical sciences
Abstract

In the presence of stoichiometric or catalytic amounts of [M{N(SiMe3)2}2] (M=Fe, Co), N-heterocyclic carbenes (NHCs) react with primary phosphines to give a series of carbene phosphinidenes of the type (NHC)·PAr. The formation of (IMe4)·PMes (Mes=mesityl) is also catalysed by the phosphinidene-bridged complex [(IMe4)2Fe-(m-PMes)]2, which provides evidence for metal-catalysed phosphinidene \ud transfer.

Published
2015

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