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Widening the working voltage of lithium-ion batteries is considered as an effective strategy to improve their energy density. However, the decomposition of conventional aprotic electrolytes at high voltage greatly impedes the success until the presence of high concentration electrolytes (HCEs) and the resultant localized HCEs (LHCEs). The unique solvated structure of HCEs/LHCEs endows the involved solvent with enhanced endurance toward high voltage while the LHCEs can simultaneously possess the decent viscosity for sufficient wettability to porous electrodes and separator. Nowadays, most LHCEs use LiFSI/LiTFSI as the salts and β-hydrofluoroethers as the counter solvents due to their good compatibility, yet the LHCE formula of cheap LiPF6 and high antioxidant α-hydrofluoroethers is seldom investigated. Here, we report a unique formula with 3 mol L−1 LiPF6 in mixed carbonate solvents and a counter solvent α-substituted fluorine compound (1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropylether). Compared to a conventional electrolyte, this formula enables dramatic improvement in the cycling performance of LiCoO2//graphite cells from approximately 150 cycles to 1000 cycles within the range of 2.9 to 4.5 V at 0.5 C. This work provides a new choice and scope to design functional LHCEs for high voltage systems.

In many applications, especially electrical submersible pump required remote operation of inverter via a long motor cable. The conventional control algorithm of induction motor (IM) didn’t operate effectively, which ignored the influence of the cable length, and didn’t consider the effect of long cable distribution parameters. A speed sensor technique was also difficult to achieve. In this paper, an improved speed sensorless vector control algorithm (ISSVCA) for IM based on long cable was proposed. Based on the analysis of long cable motor drive system of the inverter, the two-port π network model of the long cable was established. The functional relationship between the voltage/current parameters of the two ports of the long cable and the cable distribution parameters was deduced. The function expression was transformed to the α − β stationary reference frame, the accurate motor terminal voltage/current was calculated, so that the flux model was constructed to realize the observation of the flux, accurate velocity identification, and closed-loop control of the torque, flux and current. Simulation and experimental results showed that the proposed ISSVCA based on long cable increased the starting electromagnetic torque, decreased speed dip and speed recovery time caused by sudden loads, reduced the DC current harmonics, and had good dynamic and static characteristics.