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1. Selectfluor-mediated regioselective nucleophilic functionalization of N-heterocycles under metal- and base-free conditions

Author

Zheng Wang, Jie Qu, Sha Peng, Zhong Cao, Long-Yong Xie, Kai-Jian Liu, Yi Wang, He Weimin, and Man-Hua Ding

Subjects
010405 organic chemistry, Base free, Regioselectivity, 010402 general chemistry, 01 natural sciences, Pollution, Combinatorial chemistry, 0104 chemical sciences, Metal, chemistry.chemical_compound, Transition metal, chemistry, Nucleophile, Reagent, visual_art, visual_art.visual_art_medium, Environmental Chemistry, Surface modification, Selectfluor
Abstract

A practical and environmentally attractive methodology for the direct diversification of N-heterocycles at ambient temperature under open-air conditions was developed. The obvious advantage of the process is that no toxic reagent, transition metal, base or other additive is employed, thus greatly reducing costs, facilitating post-reaction neutralization and purification and minimizing the environmental impact.

Published
2018
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