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International audience; Solid oxide electrolysis cells (SOEC) are a promising energy conversion technology for the production of green hydrogen via steam electrolysis. However, performance loss remains a bottleneck for large-scale commercialization. Here, we investigate the different types of degradation occurring in a state-of-the-art cell composed of La0.6Sr0.4Co0.2Fe0.8O3-Ce0.8Gd0.2O2 (LSCF-GDC) composite for the oxygen electrode, GDC for the barrier layer, Y0.16Zr0.84O1.92 (8YSZ) for the electrolyte and Ni-YSZ for the fuel electrode. Electrochemical impedance spectra measured before and after operation at 750 °C for 2000 hours at -1 A cm-2 in SOEC mode revealed no significant evolution for the oxygen electrode contribution. To investigate potential degradation of this electrode, we performed multi-modal chemical imaging based on synchrotron X-ray diffraction (µ-XRD) with a resolution at the micrometer-scale. In addition, we monitored the evolution of the chemical composition and chemical environment before and after ageing using laboratory X-ray photoelectron spectroscopy (XPS). All these analyses revealed a slight evolution of the crystal lattice parameter in the oxygen electrode and the inter-diffusion layer. It was also found that Sr segregation accelerates with ageing. However, more severe ageing conditions and/or longer ageing durations are required in order to observe an effect on the performance.

This presentation described the modelling activities of the SWITCH system, conducted at EPFL. A morphological-based model is developed to simulate Ni agglomeration in Ni-YSZ fuel electrodes. A large range of microstructures are generated by the model simulating different degrees of Ni evolution. The model showed a goodagreement with the experimental data acquired from real reconstructions.

Hydrodynamic interactions are crucial for determining the cooperative behavior of microswimmers at low Reynolds numbers. Here we provide a comprehensive analysis of the scaling and strength of the interactions in the case of a pair of three-sphere swimmers with intrinsic elasticity. Both stroke-based and force-based microswimmers are analyzed using an analytic perturbative approach. Following a detailed analysis of the passive interactions, as well as active translations and rotations, we find that the mapping between the stroke-based and force-based swimmers is only possible in a low driving frequency regime where the characteristic time scale is smaller than the viscous one. Furthermore, we find that for swimmers separated by up to hundreds of swimmer lengths, swimming in pairs speeds up the self propulsion, due to the dominant quadrupolar hydrodynamic interactions. Finally, we find that the long term behavior of the swimmers, while sensitive to initial relative positioning, does not depend on the pusher or puller nature of the swimmer., Comment: 29 pages, 6 figures

A walking droplet possesses fascinating properties due to its peculiar wave/particle interaction. The self-propelling motion of such a droplet is driven by the Faraday instability triggered around the droplet at each impact. We studied in this article how such a droplet behaves in an annular cavity where a periodic pattern is placed underneath the liquid-air interface, altering the Faraday instability. We show that, while the annulus ensures a circular motion of the droplet, the periodic pattern affects the global droplet motion. Similarly to electromagnetic waves in photonic crystals, the average droplet speed nearly vanishes when the pattern has a characteristic length close to half the Faraday wavelength. This effect opens ways to design guides, reflectors, lattices and metamaterials for such macroscopic particles., Comment: 6 pages, 5 figures, 1 movie. arXiv admin note: text overlap with arXiv:1504.00484

The scattering of a wave obeying Helmholtz equation by an elliptic obstacle can be described exactly using series of Mathieu functions. This situation is relevant in optics, quantum mechanics and fluid dynamics. We focus on the case when the wavelength is comparable to the obstacle size, when the most standard approximations fail. The approximations of the radial (or modified) Mathieu functions using WKB method are shown to be especially efficient, in order to precisely evaluate series of such functions. It is illustrated with the numerical computation of the Green function when the wave is scattered by a single slit or a strip (ribbon)., Comment: 41 pages, 15 figures

When gently placing a droplet onto a vertically vibrated bath, a drop can bounce without coalescing. Upon increasing the forcing acceleration, the droplet is propelled by the wave it generates and becomes a walker with a well defined speed. We investigate the confinement of a walker in different rectangular cavities, used as waveguides for the Faraday waves emitted by successive droplet bounces. By studying the walker velocities, we discover that 1d confinement is optimal for narrow channels of width of $D \simeq 1.5 \lambda_F $. We also propose an analogy with waveguide models based on the observation of the Faraday instability within the channels., Comment: 8 pages, 6 figures

We present an experiment where three mesoscopic soft ferromagnetic beads are placed onto a liquid surface and submitted to the influence of magnetic fields. A vertical magnetic field creates a repulsion which counterbalances the capillary attraction. We show that the competition with a second, oscillating field, deforms the structure in a non reciprocal way. As a consequence, the structure is able to swim. This experiment is fully described in a fluid dynamics video attached to this submission., Comment: 5 pages, 6 figures and 2 videos for the gallery of fluid motion (The same ones but at different qualities.)