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Within the critical zone, regolith plays a key role in the fundamental hydrological functions of water collection, storage, mixing and release. Electrical resistivity tomography (ERT) is recognized as a remarkable tool for characterizing the geometry and properties of the regolith, overcoming limitations inherent to conventional borehole-based investigations. For exploring shallow layers, a small electrode spacing (ES) will provide a denser set of apparent resistivity measurements of the subsurface. As this option is cumbersome and time-consuming, larger ES – albeit offering poorer shallow apparent resistivity data – is often preferred for large horizontal ERT surveys. To investigate the negative trade-off between larger ES and reduced accuracy of the inverted ERT images for shallow layers, we use a set of synthetic “conductive–resistive–conductive” three-layered soil–saprock/saprolite–bedrock models in combination with a reference field dataset. Our results suggest that an increase in ES causes a deterioration of the accuracy of the inverted ERT images in terms of both resistivity distribution and interface delineation and, most importantly, that this degradation increases sharply when the ES exceeds the thickness of the top subsurface layer. This finding, which is obvious for the characterization of shallow layers, is also relevant even when solely aiming for the characterization of deeper layers. We show that an oversized ES leads to overestimations of depth to bedrock and that this overestimation is even more important for subsurface structures with high resistivity contrast. To overcome this limitation, we propose adding interpolated levels of surficial apparent resistivity relying on a limited number of ERT profiles with a smaller ES. We demonstrate that our protocol significantly improves the accuracy of ERT profiles when using large ES, provided that the top layer has a rather constant thickness and resistivity. For the specific case of large-scale ERT surveys the proposed upgrading procedure is cost-effective in comparison to protocols based on small ES.

The Weierbach experimental catchment (0.45 km²) is the most instrumented and studied sub‐catchment in the Alzette River basin in Luxembourg. Within the last decade, it has matured towards an interdisciplinary critical zone observatory focusing on a better understanding of hydrological and hydro‐geochemical processes. The Weierbach catchment is embedded in an elevated sub‐horizontal plateau, characterized by slate bedrock and representative of the Ardennes Massif. Its climate is semi‐marine, with precipitation being rather evenly distributed throughout the year. Base flow is lowest from July to September, essentially due to higher losses through evapotranspiration in summer. The regolith is composed of Devonian slates, overlaid by Pleistocene slope deposits and entirely covered by forest with 70% deciduous and 30% coniferous trees. Since 2009, the Weierbach has been extensively equipped for continuously monitoring water fluxes and physico‐chemical parameters within different compartments of the critical zone. Additionally, these compartments are sampled fortnightly at several locations to analyze δ¹⁸O and δ²H isotopic composition of water including rainfall, throughfall, soil water, groundwater and streamwater. This ongoing monitoring and sampling programme is used for answering pressing questions related to fundamental catchment functions of water infiltration, storage, mixing and release in forest ecosystems. A recently started research line aims at investigating interactions between forest eco‐hydrosystems with the atmosphere and understanding how catchments will respond to a non‐stationary climate.

Fossil bioerosion traces at a new site of Les Bez (Jura Department) and those already known from Verrieres-de-Joux (Doubs Department) in the central French Jura record an ancient Miocene cliffed shoreline cut into Lower Cretaceous limestones. Both localities are at about 900 m above the present sea level. Caulostrepsis, Gastrochaenolites and Circolites are the ichnogenera identified at Les Bez, whereas only Gastrochaenolites is present at Verrieres-de-Joux. This ichnoassociation identifies the Entobia ichnofacies, which corresponds to the upper infralittoral marine environment, biologically associated with the biocenosis of photophilic algae. By means of digital analysis of high-resolution field images, the percentage of the surface affected by the erosive activity of polychaete worms, bivalves and echinoids has been calculated. This information permits a better evaluation of their biological activity, thus complementing the data on the number of specimens per surface area. The cliff preserved at Les Bez was more affected, showing Gastrochaenolites with diameters smaller than those at Verrieres. The Circolites–Caulostrepsis association is well developed at Les Bez, where polychaete borings are located within echinoid bowl-shaped pits with particular patterns, suggesting an ecological relationship between involved organisms. Moreover, the distribution of the borings along this outcrop is not uniform and digital analysis at three sections (A, B and C) suggests a lower and an upper zone developed on the outcrop under slightly different environmental conditions within the upper infralittoral. The exceptional preservation of the Les Bez fossil cliff-site demands protection in order to ensure its future existence and accessibility.

Within the Critical Zone, regolith plays a key role in the fundamental hydrological functions of water collection, storage, mixing and release. Electrical Resistivity Tomography (ERT) is recognized as a remarkable tool for characterizing the geometry and properties of the regolith, overcoming limitations inherent to conventional borehole-based investigations. For exploring shallow layers, a small electrode spacing (ES) will provide a denser set of apparent resistivity measurements of the subsurface. As this option is cumbersome and time-consuming, smaller ES – albeit offering poorer shallow apparent resistivity data – are often preferred for large horizontal ERT surveys. To investigate the negative trade-off between larger ES and reduced accuracy of the inverted ERT images for shallow layers, we use a set of synthetic conductive/resistive/conductive three-layered soil–saprock/saprolite–bedrock models in combination with a reference field dataset. Our results suggest that an increase in ES causes a deterioration of the accuracy of the inverted ERT images in terms of both resistivity distribution and interface delineation and, most importantly, that this degradation increases sharply when the ES exceeds the thickness of the top subsurface layer. This finding, which is obvious for the characterization of shallow layers, is also relevant even when solely aiming for the characterization of deeper layers. We show that an oversized ES leads to overestimations of depth to bedrock and that this overestimation is even more important for subsurface structures with high resistivity contrast. To overcome this limitation, we propose adding interpolated levels of surficial apparent resistivity relying on a limited number of ERT profiles with a smaller ES. We demonstrate that our protocol significantly improves the accuracy of ERT profiles when using large ES, provided that the top layer has a rather constant thickness and resistivity. For the specific case of large-scale ERT surveys the proposed upgrading procedure is cost-effective in comparison to protocols based on small ES.

Weakening of the rock texture in a saprolite by weathering and further pedoplasmation results in the formation of a porous network and neoformed clays, which are the initial stages of pedogenesis, but the saprolite is likely the least studied compartment of the regolith. In this paper, the genesis of clays and their associated pore system was studied in gneiss saprolites. We investigated the saprolites of three regoliths in the Atlantic Forest Biome in northeast Brazil and used optical and electron microscopy to depict the clay–pore morphology. To assess the mobility of clays, we also determined the amounts of water–dispersible and total clay. The total chemical composition (SiO2, Al2O3, Fe2O3, CaO, MgO, Na2O, K2O, TiO2 and P2O5), exchangeable cations (Al+ 3, Ca+ 2, Mg+ 2, K+ and Na+), available P, capacity for saprolites to exchange cations and secondary forms of iron (Fed and Feo) were also measured. Micromorphological analyses showed that the most frequent pore types were channels and fissures. Channels occurred in the more weathered saprolite layers, which were identified according to the weathering indexes, and the clay–sized minerals found in the saprolite were illite, kaolinite, iron oxides, feldspar and quartz. The weathering of biotite and green hornblende formed an Fe–rich clay, and the weathering of feldspars formed an Al–rich clay. Secondary clays were accumulated at the mineral surfaces, pseudomorphs, clay infillings and clay coatings. The clay coatings are formed by two layers, i.e., the first clay layer was formed by an Fe–rich clay, and the second layer was formed by an Al–rich clay. Peculiar features named “doughnut–shaped holdfasts” were described in the clay cutans. The capacity for saprolites to exchange cations was similar to that in the shallower soils, which was environmentally relevant to the adsorption of plant nutrients, e.g., Ca+ 2, Mg+ 2 and K+, and potentially toxic elements, e.g., Al+ 3.

Double peak hydrographs are widespread phenomena but poorly understood mechanistically. In many cases, saturation-excess overland flow in the near-stream areas is assumed to control the initial peak, while the delayed peak is explained by subsurface flow in the soil or sediment cover or groundwater flow on fractured bedrock. Here we explore the mechanisms that control the generation of double peak hydrographs in a forested headwater catchment. We made use of the extensive high-resolution hydrometric time series collected in the catchment to estimate catchment storage and causal linkages. We found that double peak hydrographs occurred only after a certain amount of catchment storage was exceeded. The amount of this storage threshold was consistent over a 3-year period. The non-linear relationship between storage and discharge led to hysteretic relationships between both variables, and these hysteretic relationships were different for the different hydrograph types (single or double peak hydrographs). Discharge peaked before catchment storage during single peak hydrographs suggesting that single peaks were mainly generated by water quickly reaching the stream during precipitation pulses. It was catchment storage that peaked first during double peak hydrographs and consequently generated the delayed peak in the hydrograph. Our results also showed that double peak hydrographs were controlled in different proportions by contrasting landscape units (defined along a hillslope sequence). Hillslopes were connected to the stream at low discharge values, whereas the plateau dominated discharge generation when storage reached a certain threshold value.

In the history of alluvium and colluvium, the definitions have been shifted and rearranged several times, and this evolution is ongoing. Although field books, textbooks, and dictionaries provide standardized references, the authors of those definitions must wrestle with a wide variety of previous definitions, especially for colluvium. Contributing to this challenge is the need for Earth scientists to match available terminology to fit specific cases, which has resulting in the stretching of definitions to the point of overlap and sometimes contradiction. Alluvium was first used to describe gradual and imperceptible deposition of new earth material along rivers by floods. In the 19th century, as coarse, alluvium-like sediment in higher landscape positions was unlikely deposited by annual flooding, geologists explained those “older alluvium” deposits by the biblical deluge and named such materials diluvium. Although not the original definition, cases where alluvium and diluvium could not be distinguished, were named colluvium. Later, colluvial soils replaced ‘overplacement soils’ to describe regolith that had been transported down slope by mass-gravity processes. Concurrently other scientists used colluvium to describe deposits from slope wash. Modern definitions tend to connect to one, or more frequently both, of those concepts. The resulting spectrum of definitions presents the potential for confusion and miscommunication. This pattern was observed in a survey of 376 Earth scientists who generally agreed with defining colluvium as produced by mass-gravity-driven transport on steep slopes and alluvium as produced by water-driven transport on floodplains. However, diverse perspectives were evident for the spectrum between those two end members. This paper synthesizes the history, the logic, current perspectives, and potential strategies going forward.

As soil surveys were traditionally conducted in support of agriculture, soil classification tended to focus on upper soil horizons and their characteristics. However, when dealing with environmental issues – such as vegetation ecology or water quality – an integrated knowledge of the soil, soil-to-substratum, and deeper substratum continuum is required. In both World Reference Base for soil resources (WRB) and Soil Taxonomy (ST), the lower boundary for soil classification is arbitrarily set at 2 m, including weathered and continuous rock. However, as soil classification hinges on diagnostic horizons and characteristics, which often occur within the first 100 cm, collecting data on the subsolum is often neglected. We propose a classification system of the subsolum , the structure of which is inspired by WRB. We define Regolite , Saprolite , Saprock and Bedrock as four subsolum reference groups corresponding to different weathering stages. Intergrades of these reference groups can be qualified with principal qualifiers, while morphologic and lithologic characteristics can be presented with supplementary qualifiers. The proposed subsolum classification system is not intended to substitute geological surveys, but rather to complement existing soil classification systems such that at least the whole 2 m can be categorized. Still, whenever desired the system can also be used for deeper materials.

Diatoms are unicellular eukaryotic algae that are widely distributed in aquatic environments. In particular, their presence is abundant in stream flows, whereas the instance and transport of cells through subsurface flow is controversial. In this work, we study the transport of diatoms through soils by designing laboratory percolation experiments on undisturbed loamy and sandy soil cores. To label diatom tracers and enhance their detectability, we develop protocols to functionalize frustules of purified diatomite and Conticribra weissflogii cultures with rhodamine 123 and 2-(4-pyridyl)-5[4-dimethylaminoethyl-aminocarbamoyl)-methoxy]phenyloxazole, respectively. Labelled diatoms demonstrate good detectability and resilience under weathering agents. We execute percolation experiments for maximum time domains of approximately 600 min where volumes of water up to 3600 ml are deployed on the soil core surface. Under such experimental conditions, fluorescent diatoms are not recovered in samples of percolated material as per microscopy and spectrofluorometry. While further field studies are needed to fully investigate diatom transport, our findings shed new light on the potential of using biotic tracers for surface hydrological processes. Copyright © 2015 John Wiley & Sons, Ltd.

Carbonate weathering mantles, like terra fusca , are common in Europe but their formation and evolution is still badly understood. We propose to combine geological, mineralogical and pedological knowledge with trace element and isotope data of a weathering mantle as a novel approach to understand the evolution of terra fuscas . Sr–Nd–Pb isotopes and rare earth element (REE) contents were analyzed in a cambisol developing on a typical terra fusca on top of a condensed Bajocian limestone-marl succession from the eastern side of the Paris Basin. The isotope data, REE distribution patterns and mass balance calculations suggest that the cambisol mirrors the trace element enrichments present in this carbonate lithology, which are exceptionally high compared to global average carbonate. The deeper soil horizons are strongly enriched not only in REE (ΣREE: 2640 ppm) but also in redox-sensitive elements such as Fe (44 wt.%), V (1000 ppm), Cr (700 ppm), Zn (550 ppm), As (260 ppm), Co (45 ppm) and Cd (2.4 ppm). The trace element distribution patterns of the carbonate bedrock are similar to those of the soil suggesting their close genetic relationships. Sr–Nd–Pb isotope data allow to identify four principal components in the soil: a silicate-rich pool close to the surface, a leachable REE enriched pool at the bottom of the soil profile, the limestone on which the weathering profile developed and an anthropogenic, atmosphere-derived component detected in the soil leachates of the uppermost soil horizon. The leachable phases are mainly secondary carbonate-bearing REE phases such as bastnaesite ((X) Ca(CO 3 ) 2 F) (for X: Ce, La and Nd). The isotope data and trace element distribution patterns indicate that at least four geological and environmental events impacted the chemical and isotopical compositions of the soil system: 1. An oxygen-deficient diagenetic or hydrothermal event caused trace metal enrichments in the Bajocian limestone-marls. 2. Carbonate dissolution caused the enrichment of detrital silicate phases and authigenic REE-bearing residual phases – e.g. marine authigenic fluorapatites and bastnaesite – in the newly formed condensed horizons. 3. Dissolution/precipitation of metastable bastnaesite phases and downward migration of the REE during soil formation. 4. Overprinting of the chemical and isotopical compositions of the uppermost soil horizon by recent atmospheric depositions.

An integrated knowledge of the soil and its deeper substratum is required when dealing with environmental issues and Critical Zone research. Though the lower boundary for classifying soils is set a...

The synthesis of experimental understanding of catchment behaviour and its translation into qualitative perceptual models is an important objective of hydrological sciences. We explore this challenge by examining the cumulative understanding of the hydrology of three experimental catchments and how it evolves through the application of different investigation techniques. The case study considers the Huewelerbach, Weierbach and Wollefsbach headwater catchments of the Attert basin in Luxembourg. Subsurface investigations including bore holes and pits, analysis of soil samples and Electrical Resistivity Tomography measurements are presented and discussed. Streamflow and tracer data are used to gain further insights into the streamflow dynamics of the catchments, using end-member mixing analysis and hydrograph separation based on dissolved silica and electrical conductivity. We show that the streamflow generating processes in all three catchments are controlled primarily by the subsolum and underlying bedrock. In the Huewelerbach, the permeable sandstone formation supports a stable groundwater component with little seasonality, which reaches the stream through a series of sources at the contact zone with the impermeable marls formation. In the Weierbach, the schist formation is relatively impermeable and supports a ‘fill and spill’-type of flow mechanism; during wet conditions, it produces a delayed response dominated by pre-event water. In the Wollefsbach, the impermeable marls formation is responsible for a saturation-excess runoff generating process, producing a fast and highly seasonal response dominated by event water. The distinct streamflow generating processes of the three catchments are represented qualitatively using perceptual models. The perceptual models are in turn translated into quantitative conceptual models, which simulate the hydrological processes using networks of connected reservoirs and transfer functions. More generally, the paper illustrates the evolution of perceptual models based on experimental fieldwork data, the translation of perceptual models into conceptual models and the value of different types of data for processes understanding and model representation. Copyright © 2014 John Wiley & Sons, Ltd.

Three different statistical models were used to regionalize the winter stormflow coefficient for mesoscale basins of the Grand Duchy of Luxembourg and the neighbouring Rhineland Palatinate (Germany). The methodology is derived from a previous study, in which winter stormflow coefficients were regionalized for the Grand Duchy of Luxembourg only. The models are based on regression analysis and it is shown that model performances do not differ considerably between parsimoniously and heavily parameterized models. Next, a regionalization procedure based on a raster grid was performed, producing a qualitative grid-based analysis of runoff-producing areas for the mesoscale. The winter runoff coefficient turned out to be highly correlated with the permeability of the lithology, yet not with basin area. The grid appeared to be useful in merging basin characteristics, which were used in a statistical model to describe the winter stormflow coefficients.

The dominant processes concept was used to develop a regionally applicable rainfall—runoff model. The first-order runoff processes are identified through a combination of field investigations, physico-geographical analysis of the research area, the Alzette River basin in the Grand-Duchy of Luxembourg, and discharge data series analysis. Lithology appeared to be the major source of discrepancy in hydrological behaviour over the total area. As a result, the hydrological behaviour of each lithological substratum was characterized and conceptualized into a parsimonious model structure. The runoff signals were calibrated against the hourly-recorded discharge series of eight sub-basins, with parameter sensitivity and correlation analysis outlining the need for minor corrections to the model structure. Validation against another set of 10 sub-basins showed good results for the regional parameter set, with an average loss in efficiency (R eff) of 0.04, compared to the reference model, with a mean R eff o...

The formation, functioning and emergent properties of patterned landscapes have recently drawn increased attention, notably in semi-arid ecosystems. We describe and analyze a set of similarly spectacular landforms in seasonal tropical wetlands. Surales landscapes, comprised of densely packed, regularly spaced mounds, cover large areas of the Orinoco Llanos. Although descriptions of surales date back to the 1940's, their ecology is virtually unknown. From data on soil physical and chemical properties, soil macrofauna, vegetation and aerial imagery, we provide evidence of the spatial extent of surales and how they form and develop. Mounds are largely comprised of earthworm casts. Recognizable, recently produced casts account for up to one-half of total soil mass. Locally, mounds are relatively constant in size, but vary greatly across sites in diameter (0.5-5 m) and height (from 0.3 m to over 2 m). This variation appears to reflect a chronosequence of surales formation and growth. Mound shape (round to labyrinth) varies across elevational gradients. Mounds are initiated when large earthworms feed in shallowly flooded soils, depositing casts that form 'towers' above water level. Using permanent galleries, each earthworm returns repeatedly to the same spot to deposit casts and to respire. Over time, the tower becomes a mound. Because each earthworm has a restricted foraging radius, there is net movement of soil to the mound from the surrounding area. As the mound grows, its basin thus becomes deeper, making initiation of a new mound nearby more difficult. When mounds already initiated are situated close together, the basin between them is filled and mounds coalesce to form larger composite mounds. Over time, this process produces mounds up to 5 m in diameter and 2 m tall. Our results suggest that one earthworm species drives self-organizing processes that produce keystone structures determining ecosystem functioning and development.

Legacy soil data have been produced over 70 years in nearly all countries of the world. Unfortunately, data, information and knowledge are still currently fragmented and at risk of getting lost if they remain in a paper format. To process this legacy data into consistent, spatially explicit and continuous global soil information, data are being rescued and compiled into databases. Thousands of soil survey reports and maps have been scanned and made available online. The soil profile data reported by these data sources have been captured and compiled into databases. The total number of soil profiles rescued in the selected countries is about 800,000. Currently, data for 117, 000 profiles are compiled and harmonized according to GlobalSoilMap specifications in a world level database (WoSIS). The results presented at the country level are likely to be an underestimate. The majority of soil data is still not rescued and this effort should be pursued. The data have been used to produce soil property maps. We discuss the pro and cons of top-down and bottom-up approaches to produce such maps and we stress their complementarity. We give examples of success stories. The first global soil property maps using rescued data were produced by a top-down approach and were released at a limited resolution of 1 km in 2014, followed by an update at a resolution of 250 m in 2017. By the end of 2020, we aim to deliver the first worldwide product that fully meets the GlobalSoilMap specifications.