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Bose-Einstein condensation happens as a gas of bosons is cooled below its transition temperature, and the ground state becomes macroscopically occupied. The phase transition occurs in the thermodynamic limit of many particles. However, recent experimental progress has made it possible to assemble quantum many-body systems from the bottom up, for example, by adding single atoms to an optical lattice one at a time. Here, we show how one can predict the condensation temperature of a Bose gas from the energy fluctuations of a small number of bosons. To this end, we make use of recent advances in Lee-Yang theories of phase transitions, which allow us to determine the zeros and the poles of the partition function in the complex plane of the inverse temperature from the high cumulants of the energy fluctuations. By increasing the number of bosons in the trapping potential, we can predict the convergence point of the partition function zeros in the thermodynamic limit, where they reach the inverse critical temperature on the real axis. Using less than 100 bosons, we can estimate the condensation temperature for a Bose gas in a harmonic potential in two and three dimensions, and we also find that there is no phase transition in one dimension as one would expect., Comment: 11 pages, 6 figures

The standard approach to quantum engines is based on equilibrium systems and on thermodynamic transformations between Gibbs states. However, non-equilibrium quantum systems offer enhanced experimental flexibility in the control of their parameters and, if used as engines, a more direct interpretation of the type of work they deliver. Here we introduce an out-of-equilibrium quantum engine inspired by recent experiments with cold atoms. Our system is connected to a single environment and produces mechanical work from many-body interparticle interactions arising between atoms in highly excited Rydberg states. As such, it is not a heat engine but an isothermal one. We perform many-body simulations to show that this system can produce work. The setup we introduce and investigate represents a promising platform for devising new types of microscopic machines and for exploring quantum effects in thermodynamic processes., 10 pages, 5 figures

Scattering theory is a standard tool for the description of transport phenomena in mesoscopic systems. Here, we provide a detailed derivation of this method for nano-scale conductors that are driven by oscillating electric or magnetic fields. Our approach is based on an extension of the conventional Lippmann-Schwinger formalism to systems with a periodically time dependent Hamiltonian. As a key result, we obtain a systematic perturbation scheme for the Floquet scattering amplitudes that describe the transition of a transport carrier through a periodically driven sample. Within a general multi-terminal setup, we derive microscopic expressions for the mean values and time-integrated correlation functions, or zero-frequency noise, of matter and energy currents, thus unifying the results of earlier studies. We show that this framework is inherently consistent with the first and the second law of thermodynamics and prove that the mean rate of entropy production vanishes only if all currents in the system are zero. As an application, we derive a generalized Green-Kubo relation, which makes it possible to express the response of any mean currents to small variations of temperature and chemical potential gradients in terms of time integrated correlation functions between properly chosen currents. Finally, we discuss potential topics for future studies and further reaching applications of the Floquet scattering approach to quantum transport in stochastic and quantum thermodynamics., Comment: 17 pages, 3 figures

We develop a geometric framework to describe the thermodynamics of microscopic heat engines driven by slow periodic temperature variations and modulations of a mechanical control parameter. Covering both the classical and the quantum regime, our approach reveals a universal trade-off relation between efficiency and power that follows solely from geometric arguments and holds for any thermodynamically consistent microdynamics. Focusing on Lindblad dynamics, we derive a second bound showing that coherence as a genuine quantum effect inevitably reduces the performance of slow engine cycles regardless of the driving amplitudes. To demonstrate the practical applicability of our results, we work out the example of a single-qubit heat engine, which lies within the range of current solid-state technologies., 6+3 pages, 2 figures

We optimize the operation of single-electron charge pumps using full counting statistics techniques. To this end, we evaluate the statistics of pumped charge on a wide range of driving frequencies using Floquet theory, focusing here on the current and the noise. For charge pumps controlled by one or two gate voltages, we demonstrate that our theoretical framework may lead to enhanced device performance. Specifically, by optimizing the driving parameters, we predict a significant increase in the frequencies for which a quantized current can be produced. For adiabatic two-parameter pumps, we exploit that the pumped charge and the noise can be expressed as surface integrals over Berry curvatures in parameter space. Our findings are important for the efforts to realize high-frequency charge pumping, and our predictions may be verified using current technology., 7 pages, 3 figures, final version as published in Phys. Rev. B

For classical ballistic transport in a multi-terminal geometry, we derive a universal trade-off relation between total dissipation and the precision, at which particles are extracted from individual reservoirs. Remarkably, this bound becomes significantly weaker in presence of a magnetic field breaking time-reversal symmetry. By working out an explicit model for chiral transport enforced by a strong magnetic field, we show that our bounds are tight. Beyond the classical regime, we find that, in quantum systems far from equilibrium, correlated exchange of particles makes it possible to exponentially reduce the thermodynamic cost of precision., Comment: 5+3 pages, 2 figures

We investigate the long-time behavior of quantum N-level systems that are coupled to a Markovian environment and subject to periodic driving. As our main result, we obtain a general algebraic condition ensuring that all solutions of a periodic quantum master equation with Lindblad form approach a unique limit cycle. Quite intuitively, this criterion requires that the dissipative terms of the master equation connect all subspaces of the system Hilbert space during an arbitrarily small fraction of the cycle time. Our results provide a natural extension of Spohn's algebraic condition for the approach to equilibrium to systems with external driving., 9 pages, 1 figure

We introduce a universal scheme to divide the power output of a periodically driven quantum heat engine into a classical contribution and one stemming solely from quantum coherence. Specializing to Lindblad-dynamics and small driving amplitudes, we derive general upper bounds on both, the coherent and the total power. These constraints imply that, in the linear-response regime, coherence inevitably leads to power losses. To illustrate our general analysis, we explicitly work out the experimentally relevant example of a single-qubit engine., Comment: 7+4 pages, 2 figures

The thermodynamics of quantum systems coupled to periodically modulated heat baths and work reservoirs is developed. By identifying affinities and fluxes, the first and second law are formulated consistently. In the linear response regime, entropy production becomes a quadratic form in the affinities. Specializing to Lindblad-dynamics, we identify the corresponding kinetic coefficients in terms of correlation functions of the unperturbed dynamics. Reciprocity relations follow from symmetries with respect to time reversal. The kinetic coefficients can be split into a classical and a quantum contribution subject to a new constraint, which follows from a natural detailed balance condition. This constraint implies universal bounds on efficiency and power of quantum heat engines. In particular, we show that Carnot efficiency can not be reached whenever quantum coherence effects are present, i.e., when the Hamiltonian used for work extraction does not commute with the bare system Hamiltonian. For illustration, we specialize our universal results to a driven two-level system in contact with a heat bath of sinusoidally modulated temperature., 21 pages, 5 figures

We consider the performance of periodically driven stochastic heat engines in the linear response regime. Reaching the theoretical bounds for efficiency and efficiency at maximum power typically requires full control over the design and the driving of the system. We develop a framework which allows to quantify the role that limited control over the system has on the performance. Specifically, we show that optimizing the driving entering the work extraction for a given temperature protocol leads to a universal, one-parameter dependence for both maximum efficiency and maximum power as a function of efficiency. In particular, we show that reaching Carnot efficiency (and, hence, Curzon-Ahlborn efficiency at maximum power) requires to have control over the amplitude of the full Hamiltonian of the system. Since the kinetic energy cannot be controlled by an external parameter, heat engines based on underdamped dynamics can typically not reach Carnot efficiency. We illustrate our general theory with a paradigmatic case study of a heat engine consisting of an underdamped charged particle in a modulated two-dimensional harmonic trap in the presence of a magnetic field., Comment: 15 pages, 6 figures

For thermoelectric power generation in a multi-terminal geometry, strong numerical evidence for a universal bound as a function of the magnetic-field induced asymmetry of the non-diagonal Onsager coefficients is presented. This bound implies, inter alia, that the power vanishes at least linearly when the maximal efficiency is approached. In particular, this result rules out that Carnot efficiency can be reached at finite power, which an analysis based on the second law only, would, in principle, allow., Comment: 9 pages, 6 figures, Phys. Rev. E, in press

A genuine feature of projective quantum measurements is that they inevitably alter the mean energy of the observed system if the measured quantity does not commute with the Hamiltonian. Compared to the classical case, Jacobs proved that this additional energetic cost leads to a stronger bound on the work extractable after a single measurement from a system initially in thermal equilibrium [Phys. Rev. A 80, 012322 (2009)]. Here, we extend this bound to a large class of feedback-driven quantum engines operating periodically and in finite time. The bound thus implies a natural definition for the efficiency of information to work conversion in such devices. For a simple model consisting of a laser-driven two-level system, we maximize the efficiency with respect to the observable whose measurement is used to control the feedback operations. We find that the optimal observable typically does not commute with the Hamiltonian and hence would not be available in a classical two level system. This result reveals that periodic feedback engines operating in the quantum realm can exploit quantum coherences to enhance efficiency., Comment: 14 pages, 3 figures

We introduce a simple model for an engine based on the Nernst effect. In the presence of a magnetic field, a vertical heat current can drive a horizontal particle current against a chemical potential. For a microscopic model invoking classical particle trajectories subject to the Lorentz force, we prove a universal bound 3-2*sqrt(2) simeq 0.172 for the ratio between maximum efficiency and Carnot efficiency. This bound, as the slightly lower one 1/6 for efficiency at maximum power, can indeed be saturated for large magnetic field and small fugacity irrespective of the aspect ratio., 5+6 pages, 2 figures

For thermoelectric transport in the presence of a magnetic field that breaks time-reversal symmetry, a strong bound on the Onsager coefficients is derived within a general set-up using three terminals. Asymmetric Onsager coefficients lead to a maximum efficiency substantially smaller than the Carnot efficiency reaching only \eta_C/4 in the limit of strong asymmetry. Related bounds are derived for efficiency at maximum power, which can become larger than the Curzon-Ahlborn value \eta_C/2, and for a cooling device. Our approach reveals that in the presence of reversible currents the standard analysis based on the positivity of entropy production is incomplete without considering the role of current conservation explicitly., Comment: 6 pages including supplemental information, 3 figures, to appear in Phys. Rev. Lett

Thermoelectric transport involving an arbitrary number of terminals is discussed in the presence of a magnetic field breaking time-reversal symmetry within the linear response regime using the Landauer-B\"uttiker formalism. We derive a universal bound on the Onsager coefficients that depends only on the number of terminals. This bound implies bounds on the efficiency and on efficiency at maximum power for heat engines and refrigerators. For isothermal engines pumping particles and for absorption refrigerators these bounds become independent even of the number of terminals. On a technical level, these results follow from an original algebraic analysis of the asymmetry index of doubly substochastic matrices and their Schur complements., Comment: 31 pages, 9 figures, New J. Phys., in press