1. Symmetries and criticality of generalised van der Waals models
- Author
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Antônio Renato Pereira Moro, Francesco Giglio, Luigi Martina, G. Landolfi, Giglio, Francesco, Landolfi, Giulio, Martina, Luigi, and Moro, Antonio
- Subjects
Statistics and Probability ,Physics ,G100 ,Scale (ratio) ,Fundamental thermodynamic relation ,Statistical Mechanics (cond-mat.stat-mech) ,General Physics and Astronomy ,FOS: Physical sciences ,Statistical and Nonlinear Physics ,Space (mathematics) ,Symmetry (physics) ,symbols.namesake ,Criticality ,Modeling and Simulation ,Homogeneous space ,symbols ,Statistical physics ,van der Waals force ,Asymptotic expansion ,Mathematical Physics ,Condensed Matter - Statistical Mechanics - Abstract
We consider a family of thermodynamic models such that the energy density can be expressed as an asymptotic expansion in the scale formal parameter and whose terms are suitable functions of the volume density. We examine the possibility to construct solutions for the Maxwell thermodynamic relations relying on their symmetry properties and deduce the critical properties implied in terms of the the dynamics of coexistence curves in the space of thermodynamic variables., Comment: 10 pages, 6 plots
- Published
- 2021
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