1. Magneto-dielectric effect in relaxor superparaelectric Tb2CoMnO6 film
- Author
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R. Mandal, Rajni Rawat, Roshan Choudhary, Mohit Chandra, Malvika Tripathi, Vladimir Roddatis, Vasily Moshnyaga, and P. Ksoll
- Subjects
Materials science ,Electron energy loss spectroscopy ,02 engineering and technology ,Dielectric ,021001 nanoscience & nanotechnology ,Epitaxy ,01 natural sciences ,Ion ,Condensed Matter::Materials Science ,Crystallography ,Ferromagnetism ,0103 physical sciences ,Curie temperature ,Thin film ,010306 general physics ,0210 nano-technology ,Monoclinic crystal system - Abstract
We report magneto-dielectric properties of partially B-site ordered monoclinic ${\mathrm{Tb}}_{2}\mathrm{CoMn}{\mathrm{O}}_{6}$ double perovskite thin film epitaxially grown on $\mathrm{Nb}:\mathrm{SrTi}{\mathrm{O}}_{3}$(100) substrates by metalorganic aerosol deposition technique. Transmission electron microscopy and electron energy loss spectroscopy mapping shows the presence and distribution of both $\mathrm{C}{\mathrm{o}}^{2+}$ and $\mathrm{C}{\mathrm{o}}^{3+}$ ions in the film, evidencing a partial $B$-site disorder, which was further confirmed by the observation of reduced saturation magnetization at low temperatures. The ferromagnetic Curie temperature, ${T}_{C}=110\phantom{\rule{0.16em}{0ex}}\mathrm{K}$, is slightly higher as compared to the bulk value (100 K) probably due to an in plane epitaxy tensile strain. Temperature dependent dielectric study reveals an unexpected high temperature dipolar relaxor-glass-like transition at a temperature ${T}^{*}\ensuremath{\sim}190\phantom{\rule{0.16em}{0ex}}\mathrm{K}g{T}_{\mathrm{C}}$, which depends on the applied frequency and indicates a superparaelectric behavior. Two different dielectric relaxation peaks have been observed; they merge at ${T}^{*}$ where likely a coupling to the disorder-induced short range charge-spin correlations results in a 4% magneto-dielectric coupling.
- Published
- 2020
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