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1. Conversion of dechlorodauricumine into miharumine by a cell-free preparation from cultured roots of Menispermum dauricum

Author

Yasuo Yamauchi, Gen Sugimoto, Miharu Matsui, Hirosato Takikawa, Rieko Hori, and Yukihiro Sugimoto

Subjects
Menispermum, Magnetic Resonance Spectroscopy, Miharumine, Stereochemistry, Chemical structure, Applied Microbiology and Biotechnology, Biochemistry, Plant Roots, Analytical Chemistry, chemistry.chemical_compound, Tissue culture, Alkaloids, Biosynthesis, Spiro Compounds, Menispermaceae, Molecular Biology, Demethylation, Chromatography, biology, Cell-Free System, Organic Chemistry, General Medicine, biology.organism_classification, Dechlorodauricumine, chemistry, Biotechnology
Abstract

Dechlorodauricumine (5) and dechloroacutumine (6) were converted to miharumine (7) and dechloroacutumidine (8), respectively, by a cell-free preparation from cultured roots of Menispermum dauricum in the presence of FAD. The structures of 7 and 8 were elucidated on the basis of spectroscopic analyses and chemical conversion.

Published
2009

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