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We demonstrate the formation of the near field with non-trivial phase distribution using surface plasmon interference devices, and experimental quantitative imaging of that phase with near-field phase microscopy. The phase distribution formed with a single device can be controlled by the polarization of the external illumination and the area of the device assigned to the object wave. A comparison of the experimental data to a numerical electromagnetic model and an analytical model assigns the origin of the near-field phase to the out-of-plane electric component of surface plasmon polaritons, and also verifies the predictive power of the models. We demonstrate a formation of near-field plane waves with different propagation directions on a single device, or even simultaneously at distinct areas of a single device. Our findings open the way to the imaging and tomography of phase objects in the near field.

This thesis describes the development of active terahertz modulators based on arrays of coupled resonators loaded with monolayer graphene. The structures affect the amplitude, phase, and polarisation of the transmitted and reflected radiation. These devices were simulated using finite element modelling (FEM) software, fabricated using standard cleanroom lithographic techniques and characterised using terahertz (THz) time-domain spectroscopy (TDS). Devices designed to modulate the phase and frequency of the transmitted and reflected THz radiation were fabricated and characterised operating at ∼ 1.5 THz and 3 THz. Both the 3 THz and 1.5 THz devices were coupled with THz quantum cascade lasers (QCLs). The phase modulators were integrated with a partially suppressed QCL to form an external cavity. The devices acted as optoelectronic mirrors. By changing the bias on the device, the reflected phase changed the effective length of the cavity and affected the mode competition within the laser. The same experiment was also conducted with a gold mirror on a micrometre stage, and the position was changed to vary the external cavity length. They produced commensurate results. These results were compared with simulations of the external cavity and QCL set-up using reduced rate equations, which showed good agreement. Different devices that use coupled bright and dark resonators with capacitative coupling and some that use a double layer of resonators and magnetic coupling were simulated and fabricated. They were designed to change the polarisation of a linear THz beam, changing either the angle of rotation of the linear polarisation or converting from linear to elliptical polarisation, depending on the frequency. These devices were then coupled with THz QCLs to manipulate the linear polarisation output. For further improvement and optimisation of active metasurface devices, we need to understand the behaviour of the individual elements in response to THz incident illumination and their interaction with each other, which is not possible with FEM software. In response, metasurface devices were investigated with room temperature aperture and scattering scanning near-field optical microscopes (SNOM), which can provide subwavelength resolution. Furthermore, they showed the bonding and anti-bonding modes of the sub-wavelength features. For future direct integration of metasurfaces with the QCL facet inside the cryostat, the development of a scattering SNOM (s-SNOM) operating at cryogenic temperatures (∼10 K) was started. However, this proved to have multiple unforeseen difficulties, and much work was undertaken to reduce the vibration so that topography could be taken and so that it functioned as a cryogenic atomic force microscope (AFM)., EPSRC Studentship and EPSRC HyperTHz

We report thorough measurements of surface plasmon polaritons (SPPs) running along nearly perfect air-gold interfaces formed by atomically flat surfaces of chemically synthesized gold monocrystals. By means of amplitude-and phase-resolved near-field microscopy, we obtain their propagation length and effective mode index at visible wavelengths (532, 594, 632.8, 729, and 800 nm). The measured values are compared with the values obtained from the dielectric functions of gold that are reported in literature. Importantly, a reported dielectric function of monocrystalline gold implies similar to 1.5 times shorter propagation lengths than those observed in our experiments, whereas a dielectric function reported for properly fabricated polycrystalline gold leads to SPP propagation lengths matching our results. We argue that the SPP propagation lengths measured in our experiments signify the ultimate limit of optical losses in gold, encouraging further comprehensive characterization of optical material properties of pure gold as well as other plasmonic materials.

In this study, we theoretically and experimentally investigate the propagation of a second-order cylindrical vector beam through an aluminum lens which forms a tight focus at the distance of the wavelength. Simulation by the finite-difference time-domain method and the Richards–Wolf formulae produces light field distributions which coincide with experimental measurements provided with scanning near-field optical microscopy. We demonstrate that a pyramidal metallized cantilever with a hole is more sensitive to the transversal component of intensity than to the full intensity or to the Umov–Poynting vector in areas of reverse energy flow.

We study the effect of Coulomb correlation on the emission properties of the ground state exciton in zincblende CdSe/ZnS core–shell and in wurtzite ZnO quantum dots (QDs). We validate our theory model by comparing results of computed exciton energies of CdSe/ZnS QDs to photoluminescence and scanning near-field optical microscopy measurements. We use that to estimate the diameter of the QDs using a simple model based on infinitely deep quantum well and compare the results with the statistics of the atomic force microscopy scans of CdSe/ZnS dots, obtaining excellent agreement. Thereafter, we compute the energy fine structure of exciton, finding striking difference between properties of zincblende CdSe/ZnS and wurtzite ZnO dots. While in the former the fine structure is dominated by the dipole terms of the multipole expansion of the exchange interaction, in the latter system that is mostly influenced by Coulomb correlation. Furthermore, the correlation sizeably influences also the exciton binding energy and emission radiative rate in ZnO dots.

Metasurfaces based on gap surface-plasmon resonators allow one to arbitrarily control the phase, amplitude, and polarization of reflected light with high efficiency. However, the performance of densely packed metasurfaces is reduced, often quite significantly, in comparison with simple analytical predictions. We argue that this reduction is mainly because of the near-field coupling between metasurface elements, which results in response from each element being different from the one anticipated by design simulations, which are commonly conducted for each individual element being placed in an artificial periodic arrangement. In order to study the influence of near-field coupling, we fabricate meta-elements of varying sizes arranged in quasi-periodic arrays so that the immediate environment of same size elements is different for those located in the middle and at the border of the arrays. We study the near-field using a phase-resolved scattering-type scanning near-field optical microscopy (s-SNOM) and conducting numerical simulations. By comparing the near-field maps from elements of the same size but different placements we evaluate the near-field coupling strength, which is found to be significant for large and densely packed elements. This technique is quite generic and can be used practically for any metasurface type in order to precisely measure the near-field response from each individual element and identify malfunctioning ones, providing feedback to their design and fabrication, thereby allowing one to improve the efficiency of the whole metasurface.

We present a new methodology that enables studies of the molecular structure of graphene-liquid interfaces with nanoscale spatial resolution. It is based on Fourier transform infrared nanospectroscopy (nano-FTIR), where the infrared (IR) field is plasmonically enhanced near the tip apex of an atomic force microscope (AFM). The graphene seals a liquid electrolyte reservoir while acting also as a working electrode. The photon transparency of graphene enables IR spectroscopy studies of its interface with liquids, including water, propylene carbonate, and aqueous ammonium sulfate electrolyte solutions. We illustrate the method by comparing IR spectra obtained by nano-FTIR and attenuated total reflection (which has a detection depth of a few microns) demonstrating that the nano-FTIR method makes it possible to determine changes in speciation and ion concentration in the electric double and diffuse layers as a function of bias.

An overview of near-field optics is presented with a focus on the fundamental advances that have been made in the field since its inception 30 years ago. A focus is placed on the advancements that have been achieved in instrumentation. These advances have led to a greater generality of use with ultra-low mechanical and optical noise and the ultimate in force sensitivity with near-field optical probes. An emphasis is placed on the importance of fully integrating near-field optics with other imaging and spectroscopic modalities including Raman spectroscopy and electron/ion beam imaging. Important directions in probe design, force feedback methods and scanner flexibility are described. These developing avenues provide considerable optimism for an ever increasing incorporation of near-field optics to help resolve critical problems in fundamental and applied science.

In surface science, water adsorption on hydrophilic samples is usually invoked, addressing their nanoscale experimental effects in scanning probe microscopy, especially when water condensates between tip and sample. Here we study by means of a numerical hybrid method the effect of water bridge formation in near field imaging. We show how this nanometric water neck plays an important role not only in the optical image, producing a high contrast at hydrophilic patches, but also in the tip-sample distance control. This work contributes with a new methodology able to retrieve the original application of SNOM, using it as an instrument to study the optical properties of matter overcoming the diffraction limit. It extends the application of SNOM to study the hydrophilic character of polymeric and biological samples, taking advantage of ubiquitous effect of humidity when operating in ambient condition. © 2013 Elsevier B.V., This work has been funded through projects FIS2009-13403-C02-01(MICINN), S2009/MAT-1467(CAM) and CSD2010-00024(MICINN).

This work reports the use of an infrared spectroscopic version of scanning near-field optical microscopy (IR-SNOM) and shows that it is possible to reveal subcellular entities via their chemical constituents in a label-free human oesophageal adenocarcinoma cell (OE33). This work presents the first high spatial resolution (similar to 0.15 mu m) study of features imaged at various wavelengths within a cancer cell. The clear illumination of sub-micron sized moieties within a cell is a major step forward and is a key requirement for understanding cancer and for the study of other diseases and healthy tissue. The stable and tuneable light source was provided by the infrared free electron laser on the ALICE accelerator at Daresbury. The images reveal a structure with a size and wavelength absorption that are consistent with a chromosome and open the possibility of observing other localized structures, such as microvesicles, that play an important role in the development and spread of cancers.

Amplitude and phase measurements of the near-field generated by isolated subwavelength apertures in a gold film are presented. The near-field distribution of such a structure is complex and the measured signal strongly depends on the electric field components effectively detected by the experimental setup. By comparing this signal with 3D vectorial calculations we are able to determine which electric field components are effectively measured. The sensitivity of the phase distribution is key to this measurement. The proposed characterization technique should prove extremely useful to calibrate a Scanning near-field optical microscopy (SNOM) beforehand in order to retrieve quantitative information on the polarization of the field distribution under study.

Human HaCaT cells, exposed for 24 h to a 1 mT (rms) 50 Hz sinusoidal magnetic field in a temperature-regulated solenoid, suffer detectable changes in their biochemical properties and shapes. By using infrared wavelength-selective scanning near-field optical microscopy, we observed changes in the distribution of the inner chemical functional groups and in the cell morphology with a resolution of 80-100 nm.

9 - Conference paper: 9th International Conference on Near-Field Optics, Nanophotonics and Related Techniques, SEP 10-15 2006, Lausanne (SWITZERLAND); In this paper, we study the performances of nanosensors based on Localized Surface Plasmon Resonance in the context of biological sensing. We demonstrate the sensitivity and the selectivity of our designed nanosensors by studying the influence of the concentration of Streptavidin on the shift of Localized Surface Plasmon Resonance wavelength. In addition, to study the detection of biomolecules on a single Au nanoparticle, we used a Scanning Near-field Optical Microscope. These results represent new steps for applications in biological research and medical diagnostics.

Topographic and optical contrasts formed by Ga+ ion irradiation of thin films of amorphous silicon carbide have been investigated with scanning near-field optical microscopy. The influence of ion-irradiation dose has been studied in a pattern of sub-micrometre stripes. While the film thickness decreases monotonically with ion dose, the optical contrast rapidly increases to a maximum value and then decreases gradually. The results are discussed in terms of the competition between the effects of ion implantation and surface milling by the ion beam. The observed effects are important for uses of amorphous silicon carbide thin films as permanent archives in optical data storage applications.

Graphene plasmons were predicted to possess simultaneous ultrastrong field confinement and very low damping, enabling new classes of devices for deep-subwavelength metamaterials, single-photon nonlinearities, extraordinarily strong light–matter interactions and nano-optoelectronic switches. Although all of these great prospects require low damping, thus far strong plasmon damping has been observed, with both impurity scattering and many-body effects in graphene proposed as possible explanations. With the advent of van der Waals heterostructures, new methods have been developed to integrate graphene with other atomically flat materials. In this Article we exploit near-field microscopy to image propagating plasmons in high-quality graphene encapsulated between two films of hexagonal ​boron nitride (h-BN). We determine the dispersion and plasmon damping in real space. We find unprecedentedly low plasmon damping combined with strong field confinement and confirm the high uniformity of this plasmonic medium. The main damping channels are attributed to intrinsic thermal phonons in the graphene and dielectric losses in the h-BN. The observation and in-depth understanding of low plasmon damping is the key to the development of graphene nanophotonic and nano-optoelectronic devices.

We derived a simple method to fabricate STM-SNOM hybrid probes obtained from commercial cheap communication optical fibers. The tips are fabricated by a methodology that combines two well-known techniques: the selective attack by a buffered solution and the protected layer chemical etching, in a single new one-step technique. The tailored probes are then sputtered by metal and mounted on a STM setup. The usual difficulties of integrating the optical fiber in the STM head are solved originally with a particular home made mount described in details. We will show that the resulting probes reach atomic resolution on both vertical and horizontal scale, and that the optical imaging is free of artifacts and satisfactory with a lateral resolution in the order of λ/20, as far as we know the finest resolution obtained with a system based on a hybrid fiber probe. We believe that our methodology is very interesting for its simplicity of realization and for the good resolving power in both SNOM and STM modes.

We report about the polarization properties of light transmitted by hollow pyramidal SNOM tips. The use of a thin polymeric dichroic film allowed us to clearly distinguish between the behavior in the near-field and in the far-field regime and to emphasize strong differences between them: while in the far-field region a pinning of the polarization can take place, in the near-field region the in-plane polarization always follows linearly that of the light incident on the tip, for all the measured tips. These original findings stress the very peculiar nature of the evanescent field in the near-field regime, and have important consequences for all the applications of polarized light in near-field microscopy. (© 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)

High-resolution analysis of activities of live cells is limited by the use of non-invasive methods. Apparatuses such as SEM, STM or AFM are not practicable because the necessary treatment or the harsh contact with system probe will disturb or destroy the cell. Optical methods are purely non-invasive, but they are usually diffraction limited and then their resolution is limited to approximately 1 μm. To overcome these restrictions, we introduce here the study of membrane activity of a live cell sample using a Scanning Near-field Optical Microscope (SNOM). A near field optical microscope is able to detect tiny vertical movement on the cell membrane in the range of only 1 nm or less, about 3 orders of magnitude better than conventional optical microscopes. It is a purely non-invasive, non-contact method, so the natural life activity of the sample is unperturbed. In this report, we demonstrated the nanometer-level resolving ability of our SNOM system analyzing cardiomyocytes samples of which membrane movement is known, and then we present new intriguing data of sharp 40 nm cell membrane sudden events on rat pheochromocytoma cell line PC12. All the measurements are carried out in culture medium with alive and unperturbed samples. We believe that this methodology will open a new approach to investigate live samples. The extreme sensitivity of SNOM allows measurements that are not possible with any other method on live biomaterial paving the way for a broad range of novel studies and applications.

Scanning near-field optical microscopy (SNOM or NSOM) is the technique with the highest lateral optical resolution available today, while infrared (IR) spectroscopy has a high chemical specificity. Combining SNOM with a tunable IR source produces a unique tool, IR-SNOM, capable of imaging distributions of chemical species with a 100 nm spatial resolution. We present in this paper boron nitride (BN) thin film images, where IR-SNOM shows the distribution of hexagonal and cubic phases within the sample. Exciting potential applications in biophysics and medical sciences are illustrated with SNOM images of the distribution of different chemical species within cells. We present in this article images with resolutions of the order of λ/60 with SNOM working with infrared light. With our SNOM setup, we routinely get optical resolutions between 50 and 150 nm, regardless of the wavelength of the light used to illuminate the sample.

The advent of scanning near-field optical microscopy (SNOM) has augmented at a microscopic level the usefulness of optical spectroscopy in the region between 300 nm and 10 mum. Two-dimensional imaging of chemical constituents makes this a very attractive and powerful new approach. In this paper we show SNOM results obtained in several geometrical configurations on boron clusters in silicon, Li clusters embedded in a LiF sample and BN growth on silicon. We also show some results on the wavelength dependence of the reflectivity (R) in the near infrared (IR) of biological cells in liquid environment with the observation of the local fluorescence. The SNOM images revealed features that were not present in the corresponding shear-force (SF) images and which were due to localized changes in the bulk properties of the sample. The size of the smallest detected features clearly demonstrated that near-field conditions were reached both in the visible and infrared region. (C) 2004 Elsevier B.V. All rights reserved.

Spatial distribution of InGaN photoluminescence (PL) at room temperature has been examined by observation through an illumination-transmission mode scanning near-field optical microscope (SNOM). The near-field PL mapping revealed a disuniform pattern of sharp or blunt emission peaks from few hundreds of nanometer extension to the micrometer scale range. The peaks’ average amplitude size and distances from neighboring peaks have been measured in a large number of experiments for three different samples at dissimilar indium doses, and their results compared. A general trend has been found and the influence of indium concentration is shown in a final plot. We describe the experimental approach adopted and present full details on the results obtained. Data were gathered from more than 100 different measurements; low-cost optical SNOM nanoprobes were originally fabricated and we briefly explain the fabrication procedure.

We demonstrated a novel application of a microfabricated force-sensing cantilever with a lead zirconate titanate (PZT) thin film as an integrated deflection sensor for a dynamic-mode atomic force microscope (AFM) combined with a scanning near-field optical microscope (SNOM). This experimental setup was also applied to a Kelvin-probe force microscope (KFM) for the investigation of local electrical properties. A frequency modulation (FM) detection method was used for enhancing the detection sensitivity of electrostatic forces between a probe tip and a sample. Local optical properties of a PbTiO3 single crystal were investigated using the conductive PZT cantilever as an AFM/SNOM probe. Furthermore, studies on local optical and electrical properties of ferroelectric copolymer films were also presented.

Optical writing and subsequent optical reading of sub-micron size features has been obtained at room temperature on a spin-coated film of polymethecrylate added with azobenzene mesogenic side groups (PMA4), by means of scanning near-field optical microscopy (SNOM). Illumination with blue or UV light through the SNOM aperture induces conformational transitions in the side units, obtaining their orientation in a localized region. Optical writing and topographic reading with subwavelength resolution have been demonstrated. The pure optical readback is obtained by laser light at 690nm through the aperture, in the polarization-modulation mode that provides sensitivity to dichroism and birefringence. Equally spaced lines have been written and subsequently imaged, presenting about one micron width in the birefringence image and about 600nm width in the scattering optical image. Local erasure of optical information can be obtained by using green light at 543nm with modulated polarization through the SNOM tip, in order to destroy the molecular alignment.

We demonstrated applications of a microfabricated cantilever with a lead zirconate titanate (PZT) piezoelectric thin film as an integrated deflection sensor to dynamic-mode atomic force microscopy (AFM) and to the related techniques including scanning near-field optical microscopy (SNOM) and Kelvin force microscopy (KFM). In the SNOM measurement, the evanescent light scattered by the tip apex was transmitted through the pyramidal hollow tip of the cantilever and it was detected by a photodetector placed in a confocal arrangement. Furthermore, local surface potential of a ferroelectric film was mapped by KFM using the frequency modulation (FM) detection method. Local poled ferroelectric domains made by the AFM tip were imaged by both SNOM and KFM.

Polymer liquid crystals with a photosensitive azobenzene side chain (azo-scPLC) are interesting materials because of their potential in optical switching and high density optical data storage applications. By illumination with blue linearly polarized light, the azobenzene chromophores undergo repeated trans-cis-trans isomerization cycles, resulting in reorientation of the side chains perpendicular to the electric field direction. We investigate the structural effects due to molecular reorientation in azo-scPLC on the scale of 10-100 nm by using a scanning near-field optical microscope (SNOM). We have selected a SNOM contrast mechanism suitable for domain discrimination by modulating the polarization at the input of the SNOM fiber probe and measuring the sample response with a lock-in technique, since the SNOM optical signal is polarization dependent. We image topographic and optical spontaneous structures of a Langmuir-Schaeffer multilayer of azo-scPLC and photoinduced micron-size patterns previously crea...

Bloch surface waves (BSWs) are electromagnetic surface waves excited in the band gap of a one dimensional dielectric photonic crystal. They are confined at the interface of two media. Due to the use of dielectric material, the losses are very low, which allows the propagation of BSWs over long distances. Another advantage is the possibility of operating within a broad range of wavelengths. In this paper, we study and demonstrate the propagation of light in ultra-thin curved polymer waveguides having different radii fabricated on a BSWs sustaining multilayer. A phase-sensitive multi-parameter near-field optical measurement system (MH-SNOM), which combines heterodyne interferometry and SNOM, is used for the experimental characterization. Propagating properties, bending loss, mode conversion and admixture are investigated. We experimentally show that when light goes through the curved part of the waveguide, energy can be converted into different modes. The superposition and interference of different modes lead to a periodically alternating bright and dark beat phenomenon along the propagation direction. Experimental optical phase and amplitude distributions in the curved waveguide show a very good agreement with simulation results.

This paper presents the design of a Scanning Near-field Optical Microscopy (SNOM) probe for the use with specimen in liquid environment. The approach is based on a first electro-mechanical characterization of existing SNOM probes. A modeling stage has permitted to identify and optimize critical probe parameters in order to improve SNOM sensitivity: development and implementation of SNOM probes for air and in liquid environments have been verified with imaging of both standard and soft samples.

A tapered dielectric waveguide that scans, at constant height, a sample containing a viral capsid is studied by combining a lattice gas model to simulate water meniscus formation and a finite difference time domain algorithm for light propagation through the media involved. Our results show different contrasts related to different water contents and different meniscus orientations. We propose this method as a way to study water content and evaporation process in nanocavities being either biological, like viral capsides, or nonbiological, like photonic crystals, This work has been funded through projects FIS2009-13403-C02-01 (MINECO), S2009-MAT-1467 (CAM), and CSD2010-00024 (MINECO)

Our aim is to transpose the polarization control by mechanical stress, usually applied to single-mode fibers, to the(TM01,TE01,HEev21,HEod21) annular mode family. Nevertheless, the quasi-degeneracy of these four modes makes the situation more complex than with the fundamental mode HE11 . We propose a simple device based on periodic perturbation and mode coupling to produce the radially polarized TM01 mode or at least one of the four modes at the extremity of an arbitrarily long fiber, the conversion to TM01 mode being achievable by classical crystalline plates. OPTICS LETTERS, ISSN : 0146-9592, DOI : 10.1364/OL.36.000205, Issue : 2, Volume : 36, pp. 205-207, 15 January 2011.

We investigate the performance of a simple corrugated aperture scanning near-field optical microscope (SNOM) probe with various cladding metals. The probes have only one corrugation, however, they offer increased transmission over both uncorrugated probes and those with many grooves. Enhancement of light throughput results from excitation of surface plasmons at the corrugation at the core–cladding interface. We show how the choice of metal influences radiation properties of grooved probes.

We report the first use of polymethylmethacrylate (PMMA) optical fiber-made probes for scanning near-field optical microscopy (SNOM). The sharp tips were prepared by chemical etching of the fibers in ethyl acetate, and the probes were prepared by proper gluing of sharpened fibers onto the tuning fork in the conditions of the double resonance (working frequency of a tuning fork coincides with the resonance frequency of dithering of the free-standing part of the fiber) reported earlier for the case of glass fibers. Quality factors of the probes in the range 2000–6000 were obtained, which enables the realization of an excellent topographical resolution including state-of-art imaging of single DNA molecules. Near-field optical performance of the microscope is illustrated by the Photon Scanning Tunneling Microscope images of fluorescent beads with a diameter of 100 nm. The preparation of these plastic fiber probes proved to be easy, needs no hazardous material and/or procedures, and typical lifetime of a probe essentially exceeds that characteristic for the glass fiber probe.

Newborn rat oligodendrocyte cultures were investigated by scanning near-field optical microscope (SNOM), a versatile new tool able to map cell membranes in 3D and simultaneously obtain images of the cytoplasm. Topography, error, transmission and reflection signals were acquired to describe cell morphology with nanometer-scale resolution. Oligodendrocytes were studied as a model because their extensive membrane processes (typical of their physiological role in myelination) made them particularly suitable to test the sensitivity of the new method. Furthermore, we combined a classical histochemical method with SNOM, to identify specific intracellular proteins at high definition. In particular, with this technique, cytoskeleton elements of oligodendrocytes, such as microtubules, were observed with tubulin antibodies. Images obtained with SNOM were also compared with those from conventional scanning electron microscopy (SEM) and optical microscopy. Our results showed that SNOM allowed to observe cell nanostructures otherwise undetectable all together with other microscopies. In conclusion, SNOM, combined with rapid and non-invasive methods of specimen preparation, appears to be a powerful tool that can offer new possibilities in the field of neuroscience imaging at nano-scale level.

Summary We demonstrate that tapered optical fibre probes can be easily modified in the taper cone to realize an electric dipole producing a well-defined near-field polarized light. This novel structure is made of a Short-cut Double C–shaped probe design combined to the usual full metal coating near the tapered end of the fibre. Hence, the cone at the apex of the probe is excited by an equivalent dipole whose spatial orientation is dictated by the probe geometry, regardless the polarization state of the incoming light. Properties and performances of such a configuration are first predicted by a finite-difference time domain simulation, showing that the near field coming out from the probe is linearly polarized. Following this novel design, a probe prototype is manufactured and tested. Its measured polar diagram confirms the polarization maintenance property in the near field.

We present a simple modification of the tube etching process for the fabrication of fiber probes for near-field optical microscopy. It increases the taper angle of the probe by a factor of two. The novelty is that the fiber is immersed in hydrofluoric acid and chemically etched in an upside-down geometry. The tip formation occurs inside the micrometer tube cavity formed by the polymeric jacket. By applying this approach, called reverse tube etching, to multimode fibers with 200/250 microm core/cladding diameter, we have fabricated tapered regions featuring high surface smoothness and average cone angles of approximately 30 degrees . A simple model based on the crucial role of the gravity in removing the etching products, explains the tip formation process.

International audience; This report presents the Apertureless Scanning Optical Near‐Field Microscope as a powerful tool for the characterization of modern optoelectronic and photonic components with sub‐wavelength resolution. We present an overview of the results we obtained in our laboratory over the past few years. By significant examples, it is shown that this specific probe microscopy allows for in situ local quantitative study of semiconductor lasers in operation, integrated optical waveguides produced by ion exchange (single channel or Y junction), and photonic structures.

In a recent letter Chicanne {\em et al.} [1] reported the experimental observation of the electromagnetic local density of states LDOS established by gold nanostructures. The obtained images have been compared with combinations of partial LDOSs defined in terms of the imaginary part of the Green-tensor ${\bf G}^I = [{\bf G}-{\bf G}^\dag]/(2i)$ calculated at the tip position. Moreover just this comparison was the criterion for the choice of the optimum tip design. These results support the point of view that ${\cal G}_{\bf u} =-({2 \omega}/{\pi c^2}) {\bf u} \cdot {\bf G}^I({\bf r}, {\bf r}, \omega) \cdot {\bf u}$ (${\bf u}$ is the unit vector used to define the effective dipole associated to the illuminating tip) is the key quantity to interpret SNOM images in analogy with the electronic LDOS measured by the scanning tunneling microscope (STM). Rigorous Green-tensor analysis shows that ${\cal G}_{\bf u}$ (that is also the key quantity determining spontaneous decay rates of molecular transitions) is not the correct key quantity, and that measurements in Ref. [1] should have been compared with a different quantity. Moreover the identification of ${\cal G}_{\bf u}$ with the detected SNOM signal can lead to unphysical results.

Using scanning near-field optical microscopy for probing surface plasmon fields, we show that energy can be transferred from the plasmon propagating on one interface to the mode bound to the other interface of a thin metal film. This coupling is mediated by a narrow groove interrupting the silver film. Excitation of the second plasmon mode is detected by mapping the spatial intensity modulation induced by the interfering fields of the two plasmons. A quantitative analysis provides detailed knowledge about the degree of coupling. Our inter-pretation of the experimental results is confirmed by a numerical simulation of the field distribution.

The infrared (IR) absorption of a biological system can potentially report on fundamentally important microchemical properties. For example, molecular IR profiles are known to change during increases in metabolic flux, protein phosphorylation, or proteolytic cleavage. However, practical implementation of intracellular IR imaging has been problematic because the diffraction limit of conventional infrared microscopy results in low spatial resolution. We have overcome this limitation by using an IR spectroscopic version of scanning near-field optical microscopy (SNOM), in conjunction with a tunable free-electron laser (FEL) source. The results presented here clearly reveal different chemical constituents in thin films and biological cells. The space distribution of specific chemical species was obtained by taking SNOM images at IR wavelengths (l) corresponding to stretch absorption bands of common biochemical bonds, such as the amide bond. In our SNOM implementation, this chemical sensitivity is combined with a lateral resolution of 0.1 mm (Hl/70), well below the diffraction limit of standard infrared microscopy. The potential applications of this approach touch virtually every aspect of the life sciences and medical research, as well as problems in materials science, chemistry, physics and environmental research.

In apertureless near-field optical microscopy the vertical dithering of the tip, associated with demodulation at higher harmonics (n > 1), allows us to suppress the far-field background, providing artifact free elastic scattering images. This paper analyzes, both theoretically and experimentally, the physical origin of the background signal at the different harmonics and the mechanisms underlying its rejection for the general case of propagative-field illumination. We show that Fourier components of the background must be expected at every harmonic, evidencing why demodulation at higher harmonics is not an inherently background-free technique, and assessing the experimental conditions in which it becomes like that. In particular, we put forward the fundamental roles of both the harmonic order and the tip oscillation amplitude in the background suppression mechanisms. Furthermore, we outline how the lock-in detection of the signals amplitude can enhance the nonlinear dependence of the background on the tip-sample distance. Such effect provides a more subtle source of topography artifacts since the optical maps become qualitatively uncorrelated from the topographic counterpart, requiring an upgrade of the criteria to assess the absence of artifacts from the optical maps.

Infrared scanning near-field optical microscopy (IR-SNOM) is an extremely powerful analytical instrument since it combines IR spectroscopy's high chemical specificity with SNOM's high spatial resolution. In order to do this in the infrared, specialty chalcogenide glass fibers were fabricated and their ends tapered to generate SNOM probes. The fiber tips were installed in a modified near-field microscope and both inorganic and biological samples illuminated with the tunable output from a free-electron laser located at Vanderbilt University. Both topographical and IR spectral images were simultaneously recorded with a resolution of similar to 50 and similar to 100 nm, respectively. Unique spectroscopic features were identified in all samples, with spectral images exhibiting resolutions of up to lambda/60, or at least 30 times better than the diffraction limited lens-based microscopes. We believe that IR-SNOM can provide a very powerful insight into some of the most important biomedical research topics.

We used a combination of internal photoemission and of near-field optical microscopy (SNOM) to study the lateral Variations in solid interface properties such as energy barriers and electron-hole recombination. Ln particular we investigated the fully formed Pt-GaP, Au-GaAs, Au-SiNx-GaAs and PtSi-Si Schottky barriers. Our approach enabled us to measure large lateral variations in the photocurrent with spatial resolution on the nanometric scale. Due to the ability of SNOM to supply parallel topographic information, we observed photocurrent variations from zone to zone that only correlated in a few cases with local variations in surface morphology. We assigned the uncorrelated fluctuations to local variations in the interface stoichiometry, the presence of interface states induced by the metallic overlayer and to defect states at the junction. Furthermore, by tuning the photon energy and applied bias we were able to measure the surface distribution of the diffusion length.

International audience; In this paper, we present near-field optical images of nanostructures exhibiting an extraordinary transmission. These structures consist of annular aperture arrays engraved in a metallic film: they are quite promising structures for nanophotonics because of their high transmission directly linked to a guided mode mediated by each annular aperture. We first briefly explain our fabrication process (focused ion beam milling), then we expose the experimental setup of the near-field optical microscope working both in reflection and transmission modes. For the reflection mode, the ‘coffee-bean' structure of the electromagnetic field predicted by the theory has been quite well reproduced. For the transmission mode, we present preliminary experimental results concerning the influence of the wavelength and the polarization of the incident beam on the obtained near-field images.