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Waste-to-energy processes remain essential to ensure the safe and irreversible removal of materials and substances that are (or have become) unsuitable for reuse or recycling, and hence, to keep intended cycles of materials in the circular economy clean. In this paper, the behavior of inorganic compounds in waste-to-energy combustion processes are discussed from a multi-disciplinary perspective, against a background of ever tightening emission limits and targets of increasing energy efficiency and materials recovery. This leads to the observation that, due to the typical complexity of thermally treated waste, the intelligence of combustion control systems used in state-of-the-art waste-to-energy plants needs to be expanded to better control the behavior of inorganic compounds that typically end up in waste furnaces. This paper further explains how this goal can be achieved by developing (experimentally validated) predictive numerical models that are engineering-based and/or data-driven. Additionally, the significant economic potential of advanced thermochemical intelligence towards inorganic compounds in waste-to-energy combustion control systems is estimated on the basis of typical operational figures.

To support the ongoing energy transition and minimize the environmental footprint of combustion related technologies, the paper presents a novel approach for combustion control in gas turbines and burners. It relies on spatially targeted injection of inert components in the spray core where existent concepts fail to deliver the desired dilution rate and are unable to fully govern the spatial distribution of heat release rates. Combustion process control is thus possible by actively adjusting the composition and mass flow of spatially selective introduction of inert species in the spray, optionally combined with classic, external exhaust gas recirculation, leading to an ultimate fuel-flexible concept which is capable of adjustments to heterogeneous fuels, their reactivity and physical properties. The proof of concept is demonstrated in a gas turbine combustion chamber first by investigating the isolated effects of spatially selective injection of inert species, its comparison to external exhaust gas recirculation and a combination of both. The results confirm the superiority of the approach as spatially selective mixture inertization is capable of 7% reduction of NO emissions with merely 3% increase of CO emissions and even 9% reduction of PM emissions. Furthermore, the concept proved transferrable together with all its benefits to combustion cycles with external exhaust gas recirculation. In this case, the 63% reduction of NO emissions with no observed CO penalty is possible. Simultaneous exploitation of spatially selective inertization, as well as external exhaust gas recirculation forms a fully controllable concept - spatially selective dilution control (SSDC), which enables extensive adjustability of dilution rates throughout the spray core and primary zone of combustion chamber. Compared to baseline case, such approach was proved to simultaneously reduce CO, NO and PM emissions normalized to fuel thermal power for 39%, 63% and 91%, respectively. The confirmation of applicability of the novel approach and its potential to influence the local conditions is opening a series of possible uses, either as an original design feature for future fuel-flexible systems or as a retrofit approach in existent combustion systems.

The presented paper focuses on the combustion analysis of a highly oxygenated, viscous and economically viable fuel in an internal combustion micro gas turbine. Results suggest that environmental benefits in terms of NOx emissions and PM emissions are significant as concentrations of both species are reduced. Based on the analysis presented in the study, altered local air-fuel ratio suppresses NOx formation and PM formation resulting in 10-fold lower PM emission than same experimental apparatus with diesel fuel. The study further analyses and identifies three key mechanisms that are responsible for this reduction: altered oxygen profile during mixture preparation, prevention of soot precursors formation and promotion of soot oxidation reactions. The influence of tested fuel is also perceivable through higher CO and THC emissions. Parametric analysis within the selected experimental space suggests that operational parameters of the micro gas turbine can be adjusted to reduce concentrations of these two species without negatively affecting other pollutants. Significant benefits of the fuel in terms of environmental impact indicate that further investigation and development of this approach might provide a new alternative energy source for stationary use as well as for mobility in sectors where heavy duty gas turbines are used as prime movers.

The combustion of a viscous biofuel, liquefied wood (LW) produced via solvolysis of lignocellulosic biomass in acidified glycols, has been studied in a small gas turbine rig. The test rig includes a modified injection line which is compatible with acidic, viscous biofuels allowing fuel preheating and two pilot injectors, and a re-designed combustion chamber. The link between fuel properties and combustion performance of liquefied wood is investigated by burning the biofuel at different blending ratios with ethanol. Exhaust emissions have been compared to reference measurements with diesel fuel and ethanol. Combustion analysis is supported by the investigation of the engine operating parameters and the main emission species at different electrical loads. The experimental study reveals that it is possible to establish efficient operation of the micro gas turbine while utilizing liquefied wood-ethanol blends with high share of liquefied wood.

Power generation units based on the bio-syngas system face two main challenges due to (i) the possible temporary shortage of primary sources and (ii) the engine power derating associated with the use of low-energy density fuels in combustion engines. In both cases, an external input fuel is provided. Hence, complementing syngas with traditional fuels, like natural gas, becomes a necessity. In this work, an experimental methodology is proposed, aiming at the quantification of the impact of the use of both natural gas and syngas in spark ignition (SI) engines on performance and emissions. The main research questions focus on investigating brake thermal efficiency (BTE), power derating, and pollutant emission (NOx, CO, THC, CO2) formation, offering quantitative findings that present the basis for engine optimization procedures. Experimental measurements were performed on a Toyota 4Y-E engine (a 4-cylinders, 4-stroke spark ignition engine) at partial load (10 kW) under different syngas energy shares (SES) and at four different spark ignition timings (10°, 25°, 35° and 45° BTDC). Results reveal that the impact of the different fuel mixtures on BTE is negligible if compared to the influence of spark advance variation on BTE. On the other hand, power derating has proven to be a limiting factor and becomes more prominent with increasing SES. An increasing SES also resulted in an increase of CO and CO2 emissions, while NOx and THC emissions decreased with increasing SES.

On-road exhaust emissions of a Euro 5 factory bi-fuel CNG/gasoline light-duty vehicle equipped with the TWC were assessed considering the Real Driving Emissions (RDE) guidelines. The vehicle was equipped with a Portable Emission Measurement System (PEMS) that enabled the measurement of THC, CO, NOx, CO2, and CH4. With respect to the characteristics of the vehicle, the appropriate Worldwide Harmonized Light-Duty Vehicle Test Cycles (WLTC) were selected and based on the requirements of the RDE legislation a suitable route was conceived. In addition to the moderate RDE-based route, an extended RDE-based route was also determined. The vehicle was driven along each defined route twice, once with each individual fuel option and with a fully warm vehicle. RDE routes feature a multitude of new driving patterns that are significantly different to those encountered in the NEDC. However, as these driving patterns can greatly influence the cumulative emissions an insight in to local time trace phenomena is crucial to understand, reason and to possibly reduce the cumulative emissions. Original contributions of this paper comprise analyses of the RDE-LDV local time resolved driving emissions phenomena of a CNG-powered vehicle that are benchmarked against the ones measured under the use of gasoline in the same vehicle and under similar operating conditions to reason emission trends through driving patterns and powertrain parameters and exposing the strong cold-start independent interference of CO and N2O infrared absorption bands in the non-dispersive infrared (NDIR) analyzer. The paper provides experimental evidence on this interference, which significantly influences on the readings of CO emissions. The paper further provides hypotheses why CO and N2O interference is more pronounced when using CNG in LDVs and supports these hypotheses by PEMS tests. The study reveals that the vehicle's NOx real-world emission values of both conceived RDE-based routes when using both fuels are within Euro 5 and type-approval limits. Additionally, the THC and the NMHC emissions of both RDE-based routes using both fuels are within the Euro 5 limits indicating reasonable CH4 emissions. Notable increases above the type-approval and Euro 5 limits appeared in the CO emissions profile when using gasoline, while the CO2 emissions profile expectedly also exceeded the type-approval specifications.

Finding alternative value-added usage for glycerol is imperative as existing uses are inadequate due to the vast excesses of glycerol generated mainly as a result of increased biodiesel production. This paper explores a mid-term, cost-efficient, technically viable utilisation in power generation applications and exposes the nature of its combustion. Blended with methanol to avoid the heat loss and fuel coking problems associated with preheating, glycerol was combusted in a model swirl-stabilised gas turbine burner utilising a standard pressure-swirl injector for fuel atomisation. Stable flames resulting from the tested blends – 70/30 and 50/50 combinations of methanol/glycerol by volume – were achieved over an equivalence ratio (ER) range between 0.29 and 0.51. The upper and lower limits of stable operating ER for the 70/30 case were accompanied by significant flame lift-off from the nozzle exit orifice – a phenomenon that was not pronounced in the 50/50 case. Also, the temporal variation of CH* species integral intensity suggested a reduction in the fluctuation of heat release rate, hence better flame stability, as ER increased for both blends. Overall, the 50/50 case showed greater flame stability compared with the 70/30 case based on the CH* chemiluminescence data and spectral analysis by means of fast Fourier transform.

Although various modelling approaches exist for the simulation of solid fuel combustion, no specific model has been developed for the accurate description of gas-phase combustion in small-scale combustion devices. This is particularly limiting in scenarios when volatile-rich, complex and incompletely described solid fuels such as sewage sludge are used. To address this issue, an accurate description of combustion from the fuel bed onwards is required as well as an improved description of emitted volatiles. This paper introduces an innovative surrogate-based combustion model that combines data on sludge devolatilisation and measured combustion characteristics to offer a new surrogate composition. The composition includes heavy hydrocarbon species to accurately describe combustion evolution. A sensitivity analysis revealed that H2 contributes significantly to combustion evolution, while the most robust surrogate composition is obtained when ethanol is used as a leading representative of heavier hydrocarbons. The model can be used to produce suitable surrogates for the main sludge combustion interval, offering the required improvement in fuel descriptions and accuracy of simulations in the vicinity of the fuel bed. Hence, this model is particularly suitable for the optimisation of temperature, heat release rate, and concentration field in combustion chambers with limited volumes.

To further expand the knowledge base on the use of innovative fuels in the micro gas turbines, this paper provides insight into interrelation between specific fuel properties and their impact on combustion and emission formation phenomena in micro gas turbines for stationary power generation as well as their impact on material corrosion and deposit formation. The objective of this study is to identify potential issues that can be related to specific fuel properties and to propose counter measures for achieving stable, durable, efficient and low emission operation of the micro gas turbine while utilizing advanced/innovative fuels. This is done by coupling combustion and emission formation analyses to analyses of material degradation and degradation of component functionality while interpreting them through fuel-specific properties. To ensure sufficiently broad range of fuel properties to demonstrate the applicability of the method, two different fuels with significantly different properties are analysed, i.e. tire pyrolysis oil and liquefied wood. It is shown that extent of required micro gas turbine adaptations strongly correlates with deviations of the fuel properties from those of the baseline fuel. Through the study, these adaptations are supported by in-depth analyses of impacts of fuel properties on different components, parameters and subsystems and their quantification. This holistic approach is further used to propose methodologies and innovative approaches for constraining a design space of micro gas turbine to successfully utilize wide spectra of alternative/innovative fuels.

Presented paper deals with adaptation procedure of a microturbine (MGT) for exploitation of refuse derived fuels (RDF). RDF often possess significantly different properties than conventional fuels and usually require at least some adaptations of internal combustion systems to obtain full functionality. With the methodology, developed in the paper it is possible to evaluate the extent of required adaptations by performing a thorough analysis of fuel combustion properties in a dedicated experimental rig suitable for testing of wide-variety of waste and biomass derived fuels. In the first part key turbine components are analyzed followed by cause and effect analysis of interaction between different fuel properties and design parameters of the components. The data are then used to build a dedicated test system where two fuels with diametric physical and chemical properties are tested – liquefied biomass waste (LW) and waste tire pyrolysis oil (TPO). The analysis suggests that exploitation of LW requires higher complexity of target MGT system as stable combustion can be achieved only with regenerative thermodynamic cycle, high fuel preheat temperatures and optimized fuel injection nozzle. Contrary, TPO requires less complex MGT design and sufficient operational stability is achieved already with simple cycle MGT and conventional fuel system. The presented approach of testing can significantly reduce the extent and cost of required adaptations of commercial system as pre-selection procedure of suitable MGT is done in developed test system. The obtained data can at the same time serve as an input for fine-tuning the processes for RDF production.

To achieve a near zero emission footprint of combustion in power generation, introduction of fuels with low global warming potential, namely low-carbon or carbon neutral fuels and simultaneous reduction of harmful emissions through implementation of advanced combustion concepts is necessary. The study addresses this challenge experimentally by proposing a new approach which combines the benefits of highly oxygenated waste derived fuels, here represented by glycerol, and an introduction of external exhaust gasses recirculation (EGR) aimed for further reduction of NOx emissions. Thus, the recognized role of the high oxygen content in glycerol can positively influence the well-known penalties of EGR, which are commonly perceivable through elevated CO and soot emissions. The measurements were performed with an experimental gas turbine equipped with an exhaust heat regeneration system and feedback loop for 8% and 13% EGR content in compressor intake air. The proposed system layout represents a technically viable and cost-efficient approach for upgrading existent gas turbine setups with a goal to improve their emission footprint. Results confirm that with 8% and 13% EGR rate, NO [sub] x, CO and soot can be reduced simultaneously, thus improving the CO- NO [sub] x and soot- NO [sub] x trade off approximately 2-fold for each species. Additionally, underlying phenomena responsible for observed improvements while increasing EGR rate are identified as an increased soot reactivity, a competing effect of EGR related dilution and an increased primary air temperature together with spray related parameters linked to low stoichiometric ratio of glycerol.

The current work investigates the impact of a paraffinic fuel on combustion and emissions of a diesel engine, examining alternative injection strategies for the full exploitation of the fuel characteristics. The paraffinic fuel used was the HVO (Hydrotreated Vegetable Oil) produced by Neste Oil with the brand name NEXBTL. The study was conducted on a light-duty turbocharged and aftercooled common-rail diesel engine, with both HVO and a conventional diesel fuel. Four steady-state operating points were examined, at low and medium engine speeds (1500 and 3000 rpm) and loads (35 and 100 Nm), typical of daily driving of a passenger car. The key contribution of the study is a comprehensive analysis of the phenomena influencing the crank angle resolved in-cylinder parameters, as well as interlinking the effects of different variations of injection pressure (default and 300 bar higher), pilot injection timing (default and ± 5°CA) and main injection timing (default and ± 2°CA) on gaseous emissions and particulate matter (PM). The findings have shown that at default engine settings the use of HVO results in up to 40% reduction of engine-out PM and HC emissions without appreciable changes in NOx emissions. The significant reduction of engine-out PM levels, facilitates the adoption of measures for NOx emissions limitation. The latter are reduced by up to 20% when the main injection timing is retarded (by 2° CA in the present study), while PM emissions are still kept well below the respective diesel fuel levels.

The paper focuses on the implementation of a comprehensive and robust optimization procedure for a synthesis gas fired four-cylinder, spark ignited, 2.2 L industrial engine used in combined heat and power applications. Innovatively designed workflow is for the first time incorporating also a thorough operational stability analysis for evaluation of the engine operation durability while using off-design fuels. Design constraints of the engine operational space are set after in depth investigation of knock phenomena, cycle to cycle variations, emission formation phenomena and engine performance parameters. These are derived from experimental data, obtained from the engine, equipped with newly designed components. Throughout the paper, results obtained with synthesis gas are benchmarked to natural gas. With significant emphasis laid on analysis of lean operation conditions, as a measure to reduce environmental footprint of energy generation, a newly proposed optimum operation points reveal a possibility to obtain TA-Luft and EPA emission limits already with stoichiometric mixture. This allows to achieve a remarkably low power de-rating factor of only 16.5% and omission of any aftertreatment system. Therefore, findings of this study represent a significant improvement of current control strategies and enable further increase in specific power and thus economic attractiveness of distributed power generation techniques at enhanced durability while using low-carbon and renewable fuels.

A tire pyrolysis oil (TPO) produced from waste tires was tested in a 6-cylinder, compression ignition, turbocharged, 6.9 L heavy-duty engine. The thermodynamic parameters, engine performance and exhaust emissions of the engine fuelled with TPO were benchmarked against results of the engine fuelled with commercial diesel fuel (D2). Experiments were conducted in two operating modes, with and without intercooler, at two different engine speeds and at various loads. Impact of thermodynamic and engine performance parameters on combustion process were systematically analyzed in terms of cause and effect phenomena through mechanisms initiated by the fuel properties. The original contribution of this analysis arises from holistic assessment of combustion phenomena, engine performance and emission characterization of a modern turbocharged CI engine fuelled by the pure TPO. Results indicate that TPO can be efficiently used in turbocharged non-intercooled CI engines at high loads, which opens its use in power generation.

The work presented here characterises the influences of different waste-derived fuels on the combustion process in a microturbine. The two most common types of solid waste are converted into liquids by liquefaction in polyhydric alcohols and by pyrolysis to produce the novel fuels LW (liquefied wood) and TPO (tire pyrolysis oil). Baseline results were obtained with diesel fuel and with raw polyhydric alcohols otherwise used in wood liquefaction process. The original contribution of this analysis is the in-depth comparison of the combustion and emission phenomena of LW and TPO under different operating conditions. The results revealed significantly higher CO (carbon monoxide) and THC (total hydrocarbons) emissions for LW due to its reduced atomisation ability and increased spray penetration in line with the physical and chemical properties of the fuel. The combustion properties of TPO resembled those of diesel fuel in terms of CO and THC. NO x (nitrous oxides) emissions reflected the elemental composition of the fuels. In addition, pronounced soot formation is observed when utilizing TPO, whereas for LW, the opacity measurements are surprisingly low. These results indicate that TPO can be exploited directly in gas turbines, whereas LW requires adaptations in the fuel supply system and a narrower range of operating conditions.

The paper reports foremost the results of a successful combustion of an innovative lignocellulosic biofuel in a gas turbine. The fuel was processed through liquefaction of lignocellulosic materials with polyhydroxy alcohols in an acid catalyzed reaction. The liquefaction process features: high efficiency, high liquid yields and inexpensive, easily available process equipment. For the purpose of this analysis the following were developed: an experimental gas turbine with internal combustion chamber, a preheated pressurized fuel supply system with swirl-air fuel injector and a heat exchanger to obtain high primary air temperatures. The paper gives results on the emissions of CO, THC, NOx and soot. For the purpose of benchmarking the turbine was also run on diesel fuel. The paper presents analyses of the underlying phenomena with which it aims to provide guidelines for improvements in the fuel processing and in the experimental equipment. It has been shown that direct utilization of this innovative lignocellulosic biofuel gives promising results. Although the CO and THC emissions are higher compared to the benchmark diesel results it has been shown that both emissions decrease with increased turbine inlet temperature and with the increased fuel preheat temperature, due to a very high viscosity of the fuel. It is additionally shown that NOx emissions are low and comparable to those of the diesel fuel, whereas soot emissions are very low for both fuels.

This paper examines the influence of compressed natural gas, liquefied petroleum gas and gasoline fuel on the exhaust emissions and the fuel consumption of a spark-ignition engine powered passenger car. The vehicle was driven according to the urban driving cycle and extra urban driving cycle speed profiles with the warmed-up engine. Cause and effect based analysis reveals potential for using different fuels to reduce vehicle emission and deficiencies associated with particular fuels. The highest tank to wheel efficiency and the lowest CO2 emission are observed with the natural gas fuelled vehicle, that also featured the highest total hydrocarbon emissions and high NOx emissions because of fast three way catalytic converter aging due the use of the compressed natural gas. Retrofitted liquefied petroleum gas fuel supply systems feature the greatest air–fuel ratio variations that result in the lowest TtW efficiency and in the highest NOx emissions of the liquefied gas fuelled vehicle.

Tire pyrolysis oil (TPO) represents a promising waste-derived fuel for Diesel engines with its main deficiency being lower cetane number compared to Diesel fuel. Until now, successful utilization of the TPO in Diesel engines was possible only by increasing its cetane number, increasing compression ratio of the engine or preheating intake air or operation. This study shows the foremost results of utilizing the pure TPO in a modern turbocharged and intercooled Diesel engine without any of the aforementioned aids, which significantly facilitates its use and boosts its conversion efficiency to mechanical work. This was achieved by the tailored injection strategy that includes pilot injection, which was previously not utilized in combination with the TPO. The study reveals that with additional tailoring of the pilot injection, further optimization of thermodynamic parameters can be achieved while operating the turbocharged and intercooled Diesel engine in a wide operating range under the use of pure TPO. Discovered phenomena are supported by interpretation of interactions between the injection parameters and combustion as well as emission formation phenomena of the pure TPO.