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The efficiency roll-off in blue phosphorescent organic light emitting diodes (OLEDs) using different carbazole compounds as the host is systematically studied. While there is no significant difference in device efficiency, OLEDs using ter-carbazole as the host show a reduction in efficiency roll-off at high luminance. Data from transient photoluminescence and electroluminescence measurements show that the lower triplet–triplet annihilation (TTA) and triplet–polaron quenching (TPQ) rates in devices with the ter-carbazole host compared with other carbazole hosts are the reasons for this reduced efficiency roll-off. It is also found that the host materials with low glass transition temperatures are more susceptible to the efficiency roll-off problem.

Recent progress has been reported regarding high color gamut blue QDs development, improvement of QLEDs performance including efficiency and lifetime, and development of printable QD inks and ink-jet printing technique of QLEDs, in order to solve those key challenges towards QLED display technology commercialization.

Sub-bandgap electroluminescence in organic light emitting diodes is a phenomenon in which the electroluminescence turn-on voltage is lower than the bandgap voltage of the emitter. Based on the results of transient electroluminescence (EL) and photoluminescence and electroabsorption spectroscopy measurements, it is concluded that in rubrene/C60 devices, charge transfer excitons are generated at the rubrene/C60 interface under sub-bandgap driving conditions, leading to the formation of triplet excitons, and sub-bandgap EL is the result of the subsequent triplet-triplet annihilation process.

A new aqueous based polymer, Plexcore® OC AQ1200 (AQ1200) was used as a hole injection layer (HIL) in organic light emitting diodes (OLEDs) and the device results are compared with polyethylene dioxythiophene:polystyrene sulfonate (PEDOT:PSS) in terms of injection efficiency and stability. Dark injection transient measurements show a higher injection efficiency in hole-only devices using AQ1200 HIL compared with PEDOT:PSS. Using AQ1200 as an HIL, high efficiency phosphorescent OLEDs are demonstrated to have a long lifetime, with an estimated operational half lifetime (LT 50) of more than 8000 h from an initial luminance of 1000 cd/m 2 .

A cross-linkable hole transporting material PLEXCORE® HTL was incorporated in phosphorescent organic light emitting diodes. This hole transporting material is based on an arylamine derivate. The device performance in terms of efficiency and lifetime was compared to the same devices with a thermally evaporated 4,4′-bis[N-(1-naphthyl)-N-phenylamino]biphenyl (NPB)-based hole transporting layer. The resulting devices with the cross-linkable HTL gave higher efficiency, smaller roll-off and longer lifetime compared with devices with the NPB-based devices. This new hole transporting material paves the road toward solution processed multilayer light emitting devices.

We fabricated OLEDs on corrugated high-refractive-index substrates with an EQE of 63%. The high efficiency was achieved by suppressing the thin film guided modes and efficiently extracting the surface plasmon mode with the corrugated structure.

We fabricated OLEDs on corrugated high-refractive-index substrates. With a macro lens to extract the substrate mode, we were able to achieve an EQE of 63.2%. The high efficiency was achieved by suppressing the thin film guided modes and efficiently extracting the surface plasmon mode with the corrugated structure.

A systematic study has been conducted on microcavity organic light emitting diodes (OLEDs) based on green, red and blue phosphorescent emitters to elucidate the microcavity effects for different color emitters. We found that the luminance output is determined by the reflectivity of the semitransparent electrode and the photopic response of the green, red and blue emitters. While the luminance enhancements of blue and red phosphorescent microcavity devices are small, a current efficiency as high as 224 cd A−1 is obtained in the green phosphorescent microcavity OLEDs. The role that microcavities play in the output of an organic light-emitting device (OLED) has now been studied in detail. Chaoyu Xiang and co-workers from the University of Florida in the USA and Yamagata University in Japan investigated the efficiency and spectral characteristics of phosphorescent green, red and blue microcavity OLEDs. They concluded that the luminance output of a device is strongly affected by the reflectivity of its semitransparent electrode and its spectral match to the organic material’s electroluminescence. They fabricated device electrodes from indium-tin-oxide-coated distributed Bragg reflectors comprising two separated stacks of alternating layers of titanium oxide and silicon dioxide. They recorded a luminous efficiency of up 224 cd A–1 for an optimized green microcavity device, with smaller values achieved for blue and red devices.

We demonstrate blue/violet emitting devices based on cadmium-free zinc selenide/zinc sulfide core/shell quantum dots. Using poly(N-vinylcarbazole) with a low lying highest occupied molecular orbital energy for the hole transporting layer, enhanced hole injection was observed, resulting in efficient blue/violet emitting devices. The device charge balance was further enhanced by tuning the thicknesses of the hole transporting layer and quantum dot emitting layer.