1. Non-linear changes of performances caused by introduction of chloride ions into Er3+-doped fluorozirconate glass
- Author
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Yuan Xinqiang, Lin Wang, Haonan Li, Yiguang Jiang, Zaiyang Wang, Longfei Zhang, Sujie Cui, Qihua Zhu, Hao Chang, and Long Zhang
- Subjects
010302 applied physics ,Materials science ,Phonon ,Process Chemistry and Technology ,Doping ,02 engineering and technology ,021001 nanoscience & nanotechnology ,01 natural sciences ,Fluorescence ,Chloride ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Ion ,Electronegativity ,chemistry.chemical_compound ,chemistry ,0103 physical sciences ,Halogen ,Materials Chemistry ,Ceramics and Composites ,medicine ,Physical chemistry ,0210 nano-technology ,Fluoride ,medicine.drug - Abstract
The effect of chloride ions on the properties of Er3+-doped fluorozirconate glass is systematically studied. We first observed a nonlinear mutation of the glass-forming abilities and fluorescence properties of glass when 1 mol% fluoride ions were replaced by chloride ions. The results differed from previous reports. In order to explain this special phenomenon, we investigated the changes of the structure and the Judd-Ofelt theory of glass before and after halogen anion substitution. The results indicate that part of the fluorozirconium octahedral network was destroyed and transformed into a chain structure due to the bridging chlorine atoms, of which the electronegativity is lower than F-. With the increase of Cl-, the glass-forming abilities gradually recovered due to the decrease of the liquid's temperature. Therefore, a non-linear mutation of the glass-forming abilities was exhibited. Furthermore, the predictor χ, the ratio between the Judd–Ofelt parameters Ω 4 and Ω 6 , and the reduction in phonon density caused a mutation on the fluorescence properties of glass, such as the intensity and lifetime. This research could provide a new reference for the anion modification of fluoride glass.
- Published
- 2019