Search

Your search keyword '"Zhu, Shou‐Fei"' showing total 1 results
Start Over Author "Zhu, Shou‐Fei" Language undetermined
1 results on '"Zhu, Shou‐Fei"'

1. Nickel-catalyzed enantioselective hydrovinylation of silyl-protected allylic alcohols: An efficient access to homoallylic alcohols with a chiral quaternary center

Author

Zhu Shou-Fei, Zhou Qi-Lin, Cai Yan, Zhang Qi, and Wang Li-Xin

Subjects
Phosphoramidite, Allylic rearrangement, Silylation, Chemistry, General Chemical Engineering, Enantioselective synthesis, chemistry.chemical_element, General Chemistry, Biochemistry, Catalysis, chemistry.chemical_compound, Nickel, Materials Chemistry, Organic chemistry, Bifunctional, Quaternary carbon
Abstract

An asymmetric hydrovinylation of silyl-protected allylic alcohols catalyzed by nickel complexes of chiral spiro phosphoramidite ligands was developed. A series homoallylic alchols with a chiral quaternary center were produced in high yields (up to 97%) and high enantioselectivities (up to 95% ee). The reaction provided an efficient method for preparing bifunctional compounds with a chiral quaternary carbon center.

Published
2010

Catalog

Books, media, physical & digital resources
See catalog results