1. Effects of Oxygen Contents on the Microstructures of High-Performance SmCo 2:17-Type Sintered Permanent Magnet
- Author
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Zhu Minggang, Hongsheng Chen, Kuikui Song, Sun Wei, Li Wei, Nengjun Yu, and Fang Yikun
- Subjects
Magnetization ,Materials science ,Magnet ,Demagnetizing field ,Analytical chemistry ,Coercivity ,Type (model theory) ,Magnetic hysteresis ,Temperature coefficient ,Intensity (heat transfer) - Abstract
Precipitation-hardened Sm 2 Co 17 based sintered permanent magnet has been attracting a great deal of attention due to its distinguished high temperature magnetic properties, extremely low temperature coefficient, excellent corrosion resistance and oxidation resistance [1]–[3]. In this study, magnetic properties and microstructures of Sm-Co 17 -based sintered permanent magnets with the nominal composition Sm(Co bal Fe 0.245 Cu 0.07 Zr 0.02 ) 7.8 have been investigated. The magnets were prepared using the conventional powder metallurgy method, in which the pulverizing of powder is jet-milling and ball-milling, respectively. The typical demagnetization curves of the sintered magnets obtained by jet-milled and ball-milled powders are shown in Fig. 1. The corresponding magnetic properties of the magnets made of ball-milled powders (the magnet is designated as $\mathrm{M}_{\mathrm{b}})$ , are: the remanent magnetic polarization intensity J r =1.157 T (11.57 kGs), the intrinsic coercivity $\mathrm{H}_{\mathrm{c}\mathrm{j}}=752$ kA/m (9.46 kOe), and the maximum magnetic energy product $(\text{BH})_{\max}=221$ kJ/m3(27.8 MGOe), while that of jet-milled powder (the magnet is designated as M j ) are: $\mathrm{J}_{\mathrm{r}}=1.146$ T (11.46 kGs), $\mathrm{H}_{\mathrm{c}\mathrm{j}}=2497$ kA/m (31.37 kOe), and $(\text{BH})_{\max}=251.7$ kJ/m3(31.64 MGOe). The cause of such a significant difference between the two kinds of samples is expected as the existed deviation in effective chemical compositions, due to the different oxygen contents introduced during fabrication for the two kinds of magnets: ∼2800 and ∼1300 ppm.
- Published
- 2016