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A new fluorescence retrieval method is proposed to support ESA's 8th Earth Explorer Fluorescence EXplorer (FLEX) candidate mission. Most hyperspectral fluorescence retrieval algorithms available in the literature are very sensitive to true reflectance modelization and/or they assume the atmospheric status as known. The proposed algorithm delivers the retrieval of full fluorescence spectrum at canopy level by using only Top Of Atmosphere (TOA) radiances as input. The proposed method starts with (1) the atmospheric correction of TOA radiances, characterizing the state of the atmosphere without assuming any a-priori classification on aerosols models, (2) performing a first estimation of fluorescence values in main oxygen absorption bands without any approximation of true reflectance spectrum, and (3) using this fluorescence estimation to initialize a Spectral Fitting Method (SFM) to finally retrieve a full fluorescence spectrum. All these aspects make the proposed fluorescence retrieval method robust and independent of external auxiliary data.

The recent advent of very high spectral resolution measurements by the Fourier Transform Spectrometer (FTS) on board the Greenhouse gases Observing SATellite (GOSAT) platform has made possible the retrieval of sun-induced terrestrial chlorophyll fluorescence (F s) on a global scale. The basis for this retrieval is the modeling of the in-filling of solar Fraunhofer lines by fluorescence. This contribution to the field of space-based carbon cycle science presents an alternative method for the retrieval of F s from the Fraunhofer lines resolved by GOSAT-FTS measurements. The method is based on a linear forward model derived by a singular vector decomposition technique, which enables a fast and robust inversion of top-of-atmosphere radiance spectra. Retrievals are performed in two spectral micro-windows (~2-3nm width) containing several strong Fraunhofer lines. The statistical nature of this approach allows to avoid potential retrieval errors associated with the modeling of the instrument line shape or with a given extraterrestrial solar irradiance data set. The method has been tested on 22 consecutive months of global GOSAT-FTS measurements. The fundamental basis of this F s retrieval approach and the results from the analysis of the global F s data set produced with it are described in this work. Among other findings, the data analysis has shown (i) a very good comparison of F s intensity levels and spatial patterns with the state-of-the-art physically-based F s retrieval approach described in Frankenberg et al. (2011a), (ii) the overall good agreement between F s annual and seasonal patterns and other space-based vegetation parameters, (iii) the need for a biome-dependent scaling from F s to gross primary production, and (iv) the apparent existence of strong directional effects in the F s emission from forest canopies. These results reinforce the confidence in the feasibility of F s retrievals with GOSAT-FTS and open several points for future research in this emerging field. © 2012 Elsevier Inc.