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Abstract: In this paper a two-dimensional model of an annular cylindrical reactor filled with metal hydride suitable for hydrogen storage is presented. Comparison of the computed bed temperatures with published experimental data shows a reasonably good agreement except for the initial period. Effects of hydrogen pressure and external fluid temperatures on heat transfer and entropy generation are obtained. Results show that the time required for hydrogen charging and discharging is higher when the thermal capacity of the reactor wall is considered. The time required for absorption and desorption can be reduced significantly by varying the hydrogen gas pressure and external fluid temperatures. However, along with reduction in time the entropy generated during hydrogen storage and discharge increases significantly. Results also show that for the given input conditions, heat transfer between the external fluid and hydride bed is the main source of entropy generation. [Copyright &y& Elsevier]

Abstract: The present paper proposes a sub-model for two-layer zone models to describe heat and mass transfer across the interface between the upper and lower layers as a result of the temperature difference between the two layers. The sub-model is integrated into a two-layer zone fire growth and smoke movement model, which now can predict both pre- and post-flashover fires. The comparison of the numerical predictions of the improved model and experimental data shows that the improved model produces better temperature and heat release rate predictions for both pre- and post-flashover fires than the previous model. Compared with hybrid models consisting of a two-layer zone model and a single-layer zone model, the improved model has no transitional difficulties in switching from the pre- to the post-flashover state and it produces more reasonable temperature gradients for post-flashover fires. [Copyright &y& Elsevier]

Abstract: This paper presents a heat and mass transfer simulation of an adsorber, taking into consideration the geometry of the heat exchanger and the diffusion in the adsorbent medium. In this model, an increment in the direction of heating/cooling fluid containing one (or more) fin pitch was considered. In the domain of this increment, the distribution of the adsorbent temperature was evaluated in the radial and axial directions. The model is validated by experimental data of different adsorbents, volume flows and temperatures. All data were collected in an adsorber test-bench at Fraunhofer ISE. As a result it was found a coefficient of multiple determination of around 0.94 and an error of 20% during the transient. Finally, the model was run on typical operation for cooling application and compared with data from literature. A numerical energy balance was also evaluated. In summary, the results obtained by a independent group shows the same range of confidence of the model developed here, in terms of the tendency of the curves and even the absolute values. [Copyright &y& Elsevier]