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The preparation of ultra–small silver nanoparticles (average diameter ≤10 nm) is a technical problem because of their aggregation tendency. Therefore, the preparation conditions are usually harsh and complex. It is widely recognized that covalent organic frameworks (COFs) represent a novel class of porous crystalline compounds with broad applications in various fields. In this work, an environmentally and economically friendly new method has been developed for synthesizing ultra–small silver nanoparticles by reducing silver ions in ethanol solution with a covalent organic framework (TPB–DMTP–COF) as a template and reductant at room temperature. Interestingly, the TPB–DMTP–COF not only serves as a template and reductant but also functions as a stabilizer. Moreover, the TPB–DMTP–COF can be utilized repeatedly as a reductant. The morphology and structure of the silver nanoparticles were examined using transmission electron microscopy and showed that they were spherical with an average particle size of approximately 7.5 nm. Compared with the previously reported silver nanoparticles, the silver nanoparticles synthesized by this new method are not coated with Surfactant, such as Polyvinylpyrrolidone (PVP). As a result, they possess a larger exposed surface area, exhibit increased activity, and demonstrate excellent antimicrobial properties against both Gram–negative Escherichia coli and Gram–positive bacteria Staphylococcus aureus. [ABSTRACT FROM AUTHOR]

It is well known that hydrogen promotes catalyst activity in Cr/PNP‐catalyzed ethylene tetramerization, but the mechanism of this effect is unclear. A density functional theory (DFT) study was conducted to explore this effect, and conformation changes were carefully taken into consideration to build a clear reaction pathway. Three components in the ethylene tetramerization catalytic cycle were examined in detail: the production of 1‐hexene from metallacycloheptane, the production of 1‐octene from metallacyclononane, and the formation of an active centre on the Cr/PNP catalyst. This result indicates that the formation of an active centre on the catalyst becomes more favorable upon the imposition of hydrogen, where hydrogen functions as a second ligand. This easing effect could be the key factor leading to the outperformed Cr/PNP catalyst activity in ethylene tetramerization. [ABSTRACT FROM AUTHOR]

Schematic figure showing climate driving mechanisms on wetland hydrological and vegetational evolution. The relatively strong East Asian summer monsoon (EASM) with high precipitation tends to generate a higher water-level condition with more hygrophilous herbaceous plants while blocking the deposition of coarse grain-size fractions (a), and vise versa for weak EASM stages (b). [Display omitted] • The late-Holocene hydrological and vegetational regimes were reconstructed. • An ecological lake-to-wetland transition occurred at ~4.5 ka BP. • The wetlands evolution was largely controlled by monsoonal precipitation. The responding mechanism of wetland ecosystem to climate change is currently unclear due to a lack of long-term records incorporating multiple ecological factors. This paper presents a well-dated and multi-proxy cored record from a natural freshwater wetland developed in a paleo-pingo-related depression on the Sanjiang Plain. The study aims to reconstruct the wetland water-level and vegetational regimes during the past ~6.0 ka BP and discuss the wetland evolution response to the East Asian summer monsoon (EASM) circulation. The results show that a shallow-water lake with hygrophilous herbs developed in the depression with a strong EASM during ~6.0–4.5 ka BP. The paleolake was succeeded by a wetland with a lowered mean water level and an increase in tree cover controlled by the weakened EASM during the past 4.5 ka BP. Such an ecological lake-to-wetland transition corresponds well to the sharp decline of the EASM around 4.5 ka BP which has been well documented in various geological records across the EASM domain. During the wetland developing stage over the past 4.5 ka BP, the water-level and vegetational changes in the studied depression were also closely related to the EASM variations. The strengthened EASM usually generated higher water levels with more hygrophilous herbs around 4.0 ka BP, 3.5 ka BP, 3.0 ka BP, 2.0 ka BP, and 1.3 ka BP. Considering the prevalent EASM climate serving as the predominant water supply for the wetlands on the modern Sanjiang Plain, we suggest the EASM circulation has played a critical role in driving the wetland ecological evolution during the mid-to-late Holocene Epoch. The past 0.4 ka BP is an exception as the local Trees/Herbs ratio visibly increased with the declined water level, while the monsoonal precipitation shows no equivalent shift. The wetland evolution at this stage was attributed to human interference. [ABSTRACT FROM AUTHOR]