1. Synergistic effect of highly porous microstructured support and co-solvent assisted interfacial polymerization on the performance of thin-film composite FO membranes.
- Author
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Lee, Jaewoo, Lim, Yu Jie, Low, Jiun Hui, Lee, So Min, Lee, Chung-Hak, Wang, Rong, and Bae, Tae-Hyun
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COMPOSITE membranes (Chemistry) , *POLYMERIZATION , *POROSITY , *OSMOSIS - Abstract
Internal concentration polarization (ICP) in a dense support layer is one of the main reasons holding back forward osmosis (FO) process. In this regard, a highly porous microstructured support (HPμS) featuring a quasi-sponge-free sublayer pore structure can be considered a suitable alternative to develop high-performance FO membranes. However, it has not been tested for its effects on FO. This study demonstrates that a TFC membrane prepared using the HPμS works out for FO by inducing 3.35 times higher water flux without compromising a reverse salt flux (J s) compared to a control TFC membrane prepared without support adjustment. The performance improvement could be achieved by HPμS's almost no sponge-like region and lateral walls, which were desirable to minimize ICP. Furthermore, we verified that it is possible to leverage co-solvent assisted interfacial polymerization (CAIP) to further improve FO membrane performances by creating a more permeable active layer. The in-house TFC membrane optimized by the HPμS and CAIP displayed 5.3 times higher FO water flux than the control membrane, while keeping comparable J s. We expect that this research could contribute to kicking the FO membrane performance up a notch by providing a practical example of simultaneous optimization of both support and active layers. [Display omitted] • A highly porous microstructured support (HPμS) successfully reduced ICP in FO. • Almost no sponge-like region and lateral walls of the HPμS were key in reducing ICP. • A sublayer structure of a support layer was examined by a non-destructive inspection. • Co-solvent assisted interfacial polymerization further improved FO performances. • The simultaneous optimizations of support and active layers maximized FO performances. [ABSTRACT FROM AUTHOR]
- Published
- 2022
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