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The current study highlights a sustainable fabrication of nanoscopic thermite (MnO2/Al) system, composed of MnO2 nanoparticles with an average particle size of about 20.8 nm prepared by a hydrothermal processing technique. In addition, it contains aluminium particles having a combustion heat of 32,000 J/g, which is very attractive for advanced energetic systems. Plate-like aluminium nanoparticles with an average particle size of 100 nm were developed by wet milling. Our results revealed aluminium optimum solid loading in tri-nitrotoulene (TNT), which was found to be 8.0 wt%. At this optimum solid loading level, aluminium nanoparticles increased the destructive effect of TNT by 25.0%. While, stoichiometric colloidal mixture of both MnO2 and Al nanoparticles exhibited a 65.0% increase in the destructive effect of TNT. Our work presents an intimate mixing between nano-thermite particles, where particle size and inter-particles' distance are at the nanoscale. To sum up, TNT detonation wave was supported with one of the most potent thermite reactions occurring with maximum rate. [ABSTRACT FROM AUTHOR]

Nanothermites (metal oxide/metal) can offer tremendously exothermic self sustained reactions. CuO is one of the most effective oxidizers for naonothermite applications. This study reports on two prospectives for the manufacture of CuO nanoparticles. Colloidal CuO particles of 15 nm particle size were developed using hydrothermal synthesis technique. Multiwalled carbon nanotubes (MWCNTs) with surface are 700m²/g was employed as a substrate for synthesis of CuO-coated MWCNTs using electroless plating. On the other hand, aluminium particles with combustion heat of 32000 J/g is of interest as high energy density material. The impact of stoichiometric nanothermite particles (CuO/Al & Cuo-coated MWCNTs/Al) on shock wave strength of Al/TNT nanocomposite was evaluated using ballistic mortar test. While CuO-coated MWCNTs decreased the shock wave strength by 15%; colloidal CuO enhanced the shock wave strength by 30%. The superior performance of colloidal CuO particles was correlated to their steric stabilization with employed organic solvent. This is the first time ever to report on fabrication, isolation, and integration of stablilized colloidal nanothermite particles into energetic matrix where intimate mixing between oxidizer and metal fuel could be achieved. [ABSTRACT FROM AUTHOR]

One of the great impetus of nanotechnology on energetic materials is the achievement of nanothermites (metal-oxide/metal) which are characterized by massive heat output. Yet, full exploitation of super-thermites in highly energetic systems has not been achieved. This manuscript reports on the sustainable fabrication of colloidal Fe 2 O 3 and CuO nanoparticles for thermite applications. TEM micrographs demonstrated mono-dispersed Fe 2 O 3 and CuO with an average particle size of 3 and 15 nm respectively. XRD diffractograms demonstrated highly crystalline materials. SEM micrographs demonstrated a great tendency of the developed oxides to aggregate over drying process. The effective integration and dispersion of mono-dispersed colloidal thermite particles into energetic systems are vital for enhanced performance. Aluminum is of interest as highly energetic metal fuel. In this paper, synthesized Fe 2 O 3 and CuO nanoparticles were re-dispersed in isopropyl alcohol (IPA) with aluminum nanoparticles using ultrasonic prope homogenizer. The colloidal thermite peraticles can be intgegrated into highly energetic system for subsequent nanocomposite development. Thanks to stabilization of colloidal CuO nanoparticles in IPA which could offer intimate mixing between oxidizer and metal fuel. The stabilization mechanism of CuO in IPA was correlated to steric stabilization with solvent molecules. This approach eliminated nanoparticle drying and the re-dispersion of dry aggregates into energetic materials. This manuscript shaded the light on the real development of colloidal thermite mixtures and their integration into highly energetic systems. [ABSTRACT FROM AUTHOR]