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Solubility trapping is crucial for permanent CO 2 sequestration in deep saline aquifers. For the first time, a pore-scale numerical method is developed to investigate coupled scCO 2 -water two-phase flow, multicomponent (CO 2 (aq), H + , HCO 3 − , CO 3 2− and OH − ) mass transport, heterogeneous interfacial dissolution reaction, and homogeneous dissociation reactions. Pore-scale details of evolutions of multiphase distributions and concentration fields are presented and discussed. Time evolutions of several variables including averaged CO 2 (aq) concentration, scCO 2 saturation, and pH value are analyzed. Specific interfacial length, an important variable which cannot be determined but is required by continuum models, is investigated in detail. Mass transport coefficient or efficient dissolution rate is also evaluated. The pore-scale results show strong non-equilibrium characteristics during solubility trapping due to non-uniform distributions of multiphase as well as slow mass transport process. Complicated coupling mechanisms between multiphase flow, mass transport and chemical reactions are also revealed. Finally, effects of wettability are also studied. The pore-scale studies provide deep understanding of non-linear non-equilibrium multiple physicochemical processes during CO 2 solubility trapping processes, and also allow to quantitatively predict some important empirical relationships, such as saturation-interfacial surface area, for continuum models. [ABSTRACT FROM AUTHOR]

Three immiscible fluids systems are often encountered in energy and environmental disciplines, especially in the oil exploration field. It is essential to enhance oil recovery (EOR) by identifying the three-phase fluid flow mechanism of oil-gas-water system in complex geological structures. In the present study, a lattice Boltzmann (LB) color gradient model for three immiscible fluid flow in three-dimensional porous media is employed and validated using five benchmarks (i.e., the multiphase spinodal decomposition; the multiphase Young-Laplace test; the liquid lens; contact angles and 3D channel layered three-phase fluid flow). The effects of wettability, viscosity ratio (M) and capillary number (Ca) on the relative permeability curves are analyzed in detail. When the wetting condition is enhanced, the results indicate that the relative permeability of non-wetting phase raises while that for the wetting phase exhibits a decline. When M is not equal 1, the relative permeability of high viscosity phase is significantly increased, while the other two phases are less affected. Meanwhile, the maximal value of relative permeability does not exceed unity because of the low porosity in the porous medium. For the influence of Ca , simulation results indicate the relative permeability shows weak sensitivity to Ca. • A lattice Boltzmann color gradient model for three-phase fluid flow is proposed. • Pore-scale three-phase fluid flow in porous media is studied. • Three-phase relative permeability is predicted. • Effects of wettability, viscosity ratio and capillary number are explored. [ABSTRACT FROM AUTHOR]