1. Facile microwave synthesis, structural diversity and herbicidal activity of six novel alkaline-earth metal complexes (AECs) based on skeletal isomerization chlorophenoxyacetic acids.
- Author
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Xu, Xiuling, Hu, Fan, Ma, Yuwei, Gao, Jinming, and Shuai, Qi
- Subjects
METAL complexes ,MICROWAVES ,ISOMERIZATION - Abstract
Six novel AECs of [Sr(o-CPA)
2 (H2 O)4 ]·(o-CPA) 1, [Ba(o-CPA)2 (H2 O)]·H2 O 2, [Sr(m-CPA)2 (H2 O)4 ]·(m-CPA) 3, [Ba(m-CPA)2 (H2 O)4 ]2 ·2(m-CPA)·H2 O 4, [Sr(p-CPA)2 (H2 O)] 5 and [Ba(p-CPA)2 (H2 O)] 6 (o-CPA = 2-chlorophenoxyacetic acid, m-CPA = 3-chlorophenoxyacetic acid and p-CPA = 4-chlorophenoxyacetic acid) were synthesized by a facile microwave-assistant reaction. The solid-state structures were well established by X-ray crystallography and routine analyses of Fourier transform infrared, elemental analysis, field emission scanning electron microscope (FESEM) and thermogravimetric analysis. The structure data reveal that complexes of 1, 3 and 4 are one-dimensional chains with a zigzag arrangement, while 2, 5 and 6 are (4, 4) rhomboid two-dimensional grid structures. It is noticed that the carboxyl group in these complexes displays multiple coordination modes of μ2 -η1 :η1 (1, 2, 3, 4, 5 and 6), μ3 -η1 :η2 (1, 2, 3 and 4), μ2 -η1 :η2 (2), μ3 -η2 :η2 (5 and 6). Interestingly, the oxygen atoms of flexible –OCH2 – in phenoxy groups take part in coordination behavior with metal centers through the rotation of the C–O and C–C bonds in complexes 2, 5 and 6, while only carboxyl group coordination can be found in complexes 1, 3 and 4. FESEM images indicate that the surface appearances of complexes are totally different from ligands after coordination. All ligands and complexes were evaluated for activity as plant-growth inhibitors against Amaranth (Amaranthus spp.) and barnyard grass. Compared with ligands, complexes 1, 3 and 4 exhibited better response index (RI) values of Shoot elongation against barnyard grass. Moreover, complexes 1, 3 and 4 demonstrated a higher inhibitory activity than 2, 5 and 6. It is significant to develop a new kind of environmentally-friendly herbicide based on these kinds of complexes for their low toxicity and high efficiency. [ABSTRACT FROM AUTHOR]- Published
- 2018
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